Non-steady-state model for kinetics of free radical polymerization, 4. Direct thermal initiation

This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided.     

稀土混合物水溶液中囊泡的形成

依据柠檬酸的螯合作用和乙二醇的空间位阻效应，获得了稀土混合物囊泡。并利用ＩＣＰ、ＴＥＭ、ＦＳ等仪器对囊泡的性能进行了研究，最后对囊泡的形成机理进行了讨论。     

1，2─双（二乙基膦基）乙烷的合成

以二乙基氯化膦为原料，经乙炔化及加氢两步合成了１，２－双（二乙基膦基）乙烷，产率超过文献值。用红外光谱和核磁共振波谱分别测定了结构。     

Preparation of nanosized titania powder via the controlled hydrolysis of titanium alkoxide

By controlling the hydrolysis of titanium butoxide, followed with or without an ethanol washing process, the preparation of nanoscale titania powder was studied in detail. The characteristics of different powders produced by the direct precipitation (without an ethanol wash) and ethanol wash processes were studied by X-ray diffraction, transmission electron microscopy, BET, thermogravimetry and differential thermal analysis techniques. By comparison, it was found that both the direct precipitation and ethanol wash methods can obtain slightly agglomerated nanoscale titania powders of less than 15 nm, but the ethanol wash can further reduce the agglomeration. The particle sizes of titania powders can be modified while still retaining the anatase structure.     

Behaviour of Hydrogen in Nano-transition Metals

Nanocrystalline transition metals were prepared with Ar+H2 arc plasma method. The hydrogenmust be used during preparation to get a special nanrvparticles. The hydrogen plays an importantrole in the structure and state of nanocrystalline transition metals. The state of hydrogen andthe change of the nanocrystalline metal structure caused by hydrogen are called the behaviour ofhydrogen in nano-transition metals which includes the ability and function of storing hydrogenin the metals.     

B—ISDN宽带UNI信令点到多点配置的实现

本文根据ＩＴＵ－Ｔ最新的Ｑ．２９７１协议，以及笔者所从事的实际课题，提出一整套Ｂ－ＩＳＤＮ第三层ＵＮＩ信令的软件实现策略，其特点是能同时满足用户对点到点以及点到多点广播这两种通信方式的要求，而且可以动态配置。