Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO₄ were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Epoxidation of high trans‐1,4‐polyisoprene and its properties

A new organic‐solvent‐free water‐phase suspension method was used to synthesize partially epoxidized high trans‐1,4‐polyisoprene (TPI) to improve its properties, including oil resistance and wet‐skid resistance. The epoxidation was conducted in an aqueous peracetic acid solution and on the TPI granules prepared by a bulk precipitation method with supported titanium catalyst. The effects of the synthesis conditions, including reaction temperature, reaction time, and pH value, on the epoxy content were investigated. Epoxidized trans‐1,4‐polyisoprene (ETPI) with epoxy contents between 10 and 80% were obtained within 4 h. Both the amorphous and crystalline regions of TPI were epoxidized. The crystallization properties decreased with increasing epoxy content. ETPIs possessed lower mechanical properties than TPI but could be enhanced by vulcanization. The oil resistance and wet‐skid resistance were significantly improved after epoxidation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Dual band-notched ultra-wideband microstrip antenna using asymmetrical spurlines

A simple and novel ultra-wideband microstrip-fed antenna with dual band-notched characteristic is presented. By etching a pair of asymmetrical spurlines on the feedline, two notched bands of 600 MHz (3.95? 4.55 GHz) and 650 MHz (5.35?6.0 GHz) are achieved. Measured results show that this antenna operates from 2.5 to 12.0 GHz for voltage standing wave ratio less than 2, except two frequency notched bands of 3.95?4.55 GHz and 5.35?6.0 GHz. Moreover, this antenna has good omnidirectional radiation patterns in the H-plane.     

Low-Temperature Annealing Effect of RF Inductor With FeNi-SiO2 Granular Film

A low-temperature annealing process in vacuum is proposed to enhance the inductance of RF inductors with FeNi-SiO₂ magnetic granular films. Due to the great improvement of soft magnetic property in the 200degC and 350degC annealed film, the inductance is enhanced by 9.6% (200degC) and 8.3% (350degC), respectively, compared with the case of as-deposited film inductor. The peak value of quality factor, which is 9.18 for the as-deposited film inductor, is also increased to 9.27 (200degC ) and 12.27 (350degC), respectively.     

Bile acids as constituents for dental composites: in vitro cytotoxicity of (meth)acrylate and other ester derivatives of bile acids.

Methacrylic derivatives of bile acids have been synthesized for use as monomers in dental composites. Polymeric dental materials are known to leach cytotoxic unreacted monomers and degradation products. In this study, the in vitro cytotoxicity of bile acids and their derivatives towards 3T3 fibroblasts has been evaluated by colorimetric MTT assay and compared with that of the common dental monomers BisGMA, UDMA and TEGDMA. In general, the bile acids and their derivatives induced mitochondrial dysfunction at similar or higher concentrations than the commercial dental monomers. Certain monomers did not influence MTT response over their entire range of solubility.     

转炉冶炼20CrMo钢的生产实践

介绍了石家庄钢铁有限公司转炉生产20CrMo钢的工艺技术及其产品质量状况和这一新工艺所带来的显著效益。     

五年来我国有色金属工业结构调整状况及对策建议

本文总结了近5年来我国有色金属工业结构调整和产业升级的基本情况,即中国有色金属工业集约化程度、技装备水平提高,生产成本下降,行业整体实力增强。而这些成绩的取得都有赖于国家积极的财政政策及“债转股”政策的推动,有赖于深化企业改革及发挥市场资源配置的作用等等。同时,针对对当前及今后有色金属工业结构调整和产业结构升级所面临的问题,提出了有关对策建议     

A fast evolutionary pursuit algorithm based on linearly combining vectors

In this paper, we propose a fast Evolutionary pursuit algorithm. It searches for optimal discriminant vectors through linearly combining standard bases. Experiments on the Yale and ORL databases verify its effectiveness and enhanced efficiency.