Oxidation behavior of in-situ Al2O3/TiAl composites at 900℃ in static air

In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate that the composite samples present a much lower oxidation mass gain. Under long-time intensive oxidation exposure, the formed oxide scale is multi-layer. The formation of the outer TiO2 layer is fine and dense, the internal Al2O3 scale has good adhesiveness with the outer TiO2 scale, and the TiO2+Al2O3 mixed layer forming the protective oxide scale is favorable for the improvement of oxidation resistance. It is believed that the incorporation of Al2O3 particulates into the metal matrix decreases the coefficient of thermal expansion of the substrate, and forms a local three-dimensional network structure that can hold the oxide scale. The formation of the oxide scale with fmer particle size, stronger adherence, less micro-defects and slower growth rate can contribute to the improvement of oxidation resistance. Nb element plays an important role in reducing the internal oxidation action of the materials, restraining the growth of TiO2 crystals andpromoting thc stable formation of the Al 2O3-riched layer,which is benfeicial to improve the oxidation properties.     

合金元素对TRIP钢连续冷却固态相变和硬度的影响

为了研究Al和P合金元素在TRIP钢固态相变过程中的重要作用,利用热膨胀实验、金相观察、显微硬度测量等方法绘制了4种不同Al和P含量的C-Mn-Al-P TRIP钢的CCT图.结果表明,Al元素强烈缩小奥氏体相区,提高Ac3与Ms,促使CCT图左移和上移.P元素能够阻碍碳化物的生成,当钢中w(P)达到0.14%时,能显著将CCT曲线图中的珠光体区与贝氏体区右移.P元素对先共析铁素体相变和马氏体相变没有显著影响.随着冷却速率的增加,材料的显微硬度增加.对于每一种成分超过其临界冷却速率时将得到完全的马氏体组织.添加固溶强化元素可以强化铁素体基体,增加铁素体基体的硬度,P元素固溶强化能力最强,Mn元素稍弱,Al元素很弱.     

活性炭负载硅钨酸催化α-蒎烯的异构化研究

以活性炭负载硅钨酸为催化剂 ,研究了 α-蒎烯的异构化反应 ;考察了反应温度、反应时间、配料比和溶剂等因素对异构化反应的转化率和选择性的影响。实验结果表明 ,反应温度升高 ,反应时间增加 ,配料比减小 ,蒎烯的转化率增大。在乙醇介质中 ,α-蒎烯能发生异构化和乙氧基化反应。主要产物是莰烯、苎烯和 α-松油基乙醚 ,总醚选择性约 5 0 %     

常温高效除油清洗剂的制备与应用研究

研制出了一种去油污能力强，可室温使用，综合效果较好的新型高效常温除油清洗剂     

Application of hindered piperidine amine and/or tertiary amine in the modification of polyamide 6

PA 6 resin was produced in a hydrolytic‐polymeric process in which ε‐caprolactam was polymerized in the presence of water as initiator, isophthalic acid and benzoic acid as chain regulators, by polymerizing caprolactam in the presence of 7.5% by weight of water, 0.2% by weight of isophthalic acid, 0.1% by weight of benzoic acid, each percentage being based on caprolactam. By adding hindered piperidine amine and/or tertiary amine to the polymeric system, the effects of additives on the polymer were studied. The results showed that: the addition of 0.1 ～ 0.2% additives can improve the melt stability of polyamide 6; the addition of 0.2% additives can protect mechanical properties of polyamide 6 fibers after exposure to high temperature; and the addition of 0.05 ～ 0.25% additives can increase the amino end group content of polyamide 6 and thereby increase the dyeability of polyamide fibers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2489–2493, 2004     

乙烯环氧化反应的动态特性与反应器的动态操作(Ⅰ)——基元过程序列结构与动力学

利用动态响应方法,对乙烯在银催化剂上环氧化反应的基元过程序列结构和动力学进行了系统的实验和模型化研究,为从理论上考察这一反应体系在浓度强制振荡条件下的时间平均性能与基元过程动力学的相互关系,为建立适当的模型来描述浓度强制振荡过程提供了必要的条件.     

具有“强积分小”系数的二阶泛函微分方程解的振动性质

本文研究下列二阶泛函微分方程解的振动性质: (r(t)x′(t))′+q(t)x′(t)+M(t,x(g(t)))=0给出了方程(*)存在非振动解的必要条件以及存在振动解的充分判据。     

椭圆形钢铅耗能器性能及振动台试验

针对工字型钢铅组合耗能器直角区域容易应力集中、过早屈服断裂退出工作的问题,提出一种由钢和铅两种材料组成的椭圆形钢铅耗能器,这种耗能器加工简便且水平两个方向都具有良好耗能性能.首先,对椭圆形钢铅耗能器中钢板的平面应力进行分析.其次,对椭圆形钢铅耗能器进行力学性能试验;利用有限元分析软件ANSYS建立椭圆形钢铅耗能器的非线性计算模型进行数值分析并与性能试验结果进行对比.最后,对一个安装和不安装椭圆形钢铅耗能器的六层钢框架结构模型进行振动台对比试验.研究结果表明:数值分析结果与性能试验结果吻合良好,本文建立椭圆形钢铅耗能器数值计算模型的方法正确;椭圆形钢铅耗能器滞回曲线饱满,具有良好耗能能力;椭圆形钢铅耗能器对多层结构的地震反应具有较好减震效果.     

地面高精度磁测在龙首山新水井-火石岭地区铀矿勘查中的应用

龙首山地区是以碱交代型为主的铀成矿带,新水井-火石岭地区处于龙首山成矿带中段。通过地面高精度磁测工作,并结合地质情况,对该地段马路沟断裂及岩体分布特征进行了研究。共推断断裂构造5条,圈定侵入岩体8片,其中东南部2片闪长岩主要发育于浅部,而其他地段岩体深部延伸较深,并大致查明了区内构造格架、岩体的发育特征,为本区铀矿勘查提供了找矿信息。     

退火态5083铝合金焊接接头组织与性能分析

采用连续挤压—拉拔—刮削光亮化技术制备的ER5356铝合金焊丝对退火态5083铝合金板材进行MIG焊接,并通过金相、扫描、硬度、拉伸等观察与测试手段对其焊接接头进行试验分析。结果表明:该技术制备的焊丝焊接效果良好,焊缝无裂纹、夹杂等缺陷;焊接接头各区域组织分布均匀,焊缝中心硬度最低,为68 HV,焊接接头抗拉强度为277 MPa,强度系数为92.3%,力学性能较好,完全达到了实际焊接要求和船舶使用需求。