Molecular Adsorption-Induced Interfacial Solvation Regulation to Stabilize Graphite Anode in Ethylene Carbonate-Free Electrolytes

Many organic solvents have excellent solution properties, but fail to serve as lithium-ion batteries (LIBs) electrolyte solvents, due to their electrochemical incompatibility with graphite anodes. Herein, a new strategy is proposed to address this issue by introducing a surface-adsorbed molecular layer to regulate the interfacial solvation structure without the alteration of electrolyte composition and properties. As a proof-of-concept study, it is demonstrated for the first time that the intrinsically incompatible propylene carbonate (PC)-based electrolyte becomes completely compatible with graphite anodes by introducing a layer of adsorbed hexafluorobenzene (HFB) molecules to weaken the Li⁺-PC coordination strength and facilitate the interfacial desolvation process. As a consequence, the graphite/ NCM811 pouch cells using the PC-based electrolyte containing only 1 vol.% HFB demonstrate excellent long-term cycling stabilities over 1150 cycles. This strategy is also proved to be applicable to other ethylene carbonate (EC)–free electrolytes, thus providing a new avenue for developing advanced LIB electrolytes.     

光电跟踪系统力矩波动干扰抑制的研究

光电跟踪系统的力矩波动是影响其跟踪精度的噪声的角度一个关键问题.基于某光电跟踪控制系统动态模型,从抑制噪声的角度分析了加入电流环对抑制力矩波动的影响,同时还分析了系统速度、电流两环闭环带宽与力矩波动抑制之间的关系.分析表明,加入电流环后的光电跟踪系统抑制力矩波动的能力明显增强,同时较高的速度回路带宽有利于抑制力矩波动引起的干扰,且在速度带宽一定的情况下增加电流用环带宽对抑制力矩波动也有一定作用.因此,在设计光电跟踪系统时,在不影响系统稳定性的前提下应选用尽可能大的速度及电流闭环带宽.     

SDL的静态语义定义框架

Ｓ Ｄ Ｌ 语言自身的形式化描述对于该语言的不断发展、完善将发挥重要的核心作用。 Ｓ Ｄ Ｌ－ ９２的形式语义已无法充分满足应用需要,本文对 Ｓ Ｄ Ｌ 现有的静态语义定义方法进行了深入的分析,提出了一种基于抽象语法树和谓词演算的 Ｓ Ｄ Ｌ 静态语义定义方法。     

Current transport studies of amorphous n/p junctions and its application in a‐Si:H/HIT‐type tandem cells

This paper presents an understanding of the fundamental carrier transport mechanism in hydrogenated amorphous silicon (a‐Si:H)‐based n/p junctions. These n/p junctions are, then, used as tunneling and recombination junctions (TRJ) in tandem solar cells, which were constructed by stacking the a‐Si:H‐based solar cell on the heterojunction with intrinsic thin layer (HIT) cell. First, the effect of activation energy (E_a) and Urbach parameter (E_u) of n‐type hydrogenated amorphous silicon (a‐Si:H(n)) on current transport in an a‐Si:H‐based n/p TRJ has been investigated. The photoluminescence spectra and temperature‐dependent current–voltage characteristics in dark condition indicates that the tunneling is the dominant carrier transport mechanism in our a‐Si:H‐based n/p‐type TRJ. The fabrication of a tandem cell structure consists of an a‐Si:H‐based top cell and an HIT‐type bottom cell with the a‐Si:H‐based n/p junction developed as a TRJ in between. The development of a‐Si:H‐based n/p junction as a TRJ leads to an improved a‐Si:H/HIT‐type tandem cell with a better open circuit voltage (V_oc), fill factor (FF), and efficiency. The improvements in the cell performance was attributed to the wider band‐tail states in the a‐Si:H(n) layer that helps to an enhanced tunneling and recombination process in the TRJ. The best photovoltage parameters of the tandem cell were found to be V_oc = 1430 mV, short circuit current density = 10.51 mA/cm², FF = 0.65, and efficiency = 9.75%. Copyright © 2015 John Wiley & Sons, Ltd.     

一种基于多模板的超宽带信道估计算法

该文针对码片率抽头间隔的脉冲超宽带(IR-UWB)系统离散信道,提出一种基于帧(frame)级采样速率的多模板信道估计算法。在该算法中引入了若干个复合信道参数,每个复合信道参数都是几个独立信道参数的线性组合。利用极大似然准则和从多个模板中获得的帧级采样数据,可以先获得所有复合信道参数的极大似然估计值。然后联合由不同模板得到的复合信道参数估计值,得到每个独立的信道参数的极大似然估计。通过仿真,验证了该方法的可行性。     

电力系统短期负荷预测中非线性模型的研究与应用

介绍了时间序列分析中的一类非线性模型-SETAR模型的特点及其建 模，将这一模型应用于电力系统的短期日负荷预报。这种模型可以描述一些非 线性的时间序列，在负荷序列波动较大时仍能进行很好的预测，实例计算结果 表明预测精度满足要求，证实了将这一模型应用于电力系统短期负荷预测是可 行的。     

谈饭店行业冷凝水的回收

介绍了回收冷凝水的技术基础及在饭店行业如何具体应用等方面的基本知识。     

新型冷拌冷铺沥青混合料路用性能研究

为了提高普通乳化沥青混合料的路用性能,将乳化沥青与水性环氧树脂有机结合,得到一种新型复合材料——水性环氧乳化沥青。通过试验研究水性环氧树脂用量对混合料的力学强度、水稳定性以及温度稳定性的影响。结果表明：混合料的初期强度、后期强度以及高温稳定性随着水性环氧树脂用量的增加而提高,但其水稳定性和低温稳定性随着水性环氧树脂用量的增加先增大后减小,分别在水性环氧树脂用量为10%和15%时达到最佳提升效果。在实际工程应用中将水性环氧树脂用量控制在10%~15%之间。     

Efficient visible light driven photocatalytic removal of NO with aerosol flow synthesized B, N-codoped TiO2 hollow spheres

In this study, we demonstrate that aerosol assisted flow synthesized B, N-codoped TiO(2) photocatalyst possesses superior photocatalytic activity to pure and single element doped counterparts on the degradation of NO in a flow system under both simulated solar light and visible light irradiation. Characterization results revealed that B, N-codoped TiO(2) photocatalyst was composed of hollow microspheres. Boron and nitrogen were in the form of Ti-O-B and N-Ti-O structures, respectively. The introduction of B and N into the TiO(2) lattice could effectively tune the band gap of TiO(2) and extend its optical response to the visible-light region. The synergistic effect of B and N codoping on visible light driven photocatalytic activity enhancement of TiO(2) was discussed on the basis of experimental results.     

Synthesis and characterization of Fe-Co binary ferrospinel nanospheres via one-step nonaqueous solution pathway

Fe-Co binary ferrospinel (CoFe₂O₄) nanospheres were synthesized by a facile nonaqueous solution route. X-ray diffraction (XRD) and electron diffraction (ED) showed that the obtained nanospheres had the cubic spinel structure. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the samples consisted of abundant uniform CoFe₂O₄ nanospheres with the particle size in the range of 35-40 nm. The magnetic properties of the sample were measured by using a vibrating sample magnetometer (VSM) at room temperature, which showed that the nanospheres exhibited a typical ferromagnetic behavior.