支持多种访问控制方法和策略继承的授权系统

分布式计算环境下访问控制技术的一种发展趋势是采用集中式的身份与权限管理,即由一专门的系统为企业、机构的各类计算机系统、应用服务系统提供集中的身份与授权策略管理,但这种集中式的授权管理系统在实际应用中也面临一些技术问题,论文提出了一种集中式的授权系统,它通过Manager-Provider（管理者-提供者）架构支持、扩展多种不同的访问控制方法,基于资源策略树定义可继承的授权策略,并提供面向不同访问控制方法的在线授权决策服务。     

Electrically Reconfigurable 3D Spin-Orbitronics

The explosive demands of storage capacity and the von Neumann bottleneck of modern computer architectures trigger many innovations in information technology. Amongst them, nonvolatile spintronics attract considerable attentions for which can embed the computation capability into memory, enable neuromorphic, and probabilistic computing. These exciting progresses typically rely on the manipulation of the relative magnetization orientations of two magnetic layers. By extending to 3D spintronic architectures made of multiple magnetic layers (n), the exponentially increased 2ⁿ magnetic states can provide ample opportunities for implementing novel spintronic functionalities. Here, through building perpendicularly magnetized 3D spin-orbitronic architectures – [Pt/Fe_1−xTb_x/Si₃N₄]_n multilayers, it is demonstrated the electrical programing of 2ⁿ memory states via current-induced spin–orbit torques (SOTs), and the accompanied reconfigurable multifunction in-memory logic features in a single four-terminal Hall device. Further, an electrical readout of these 2ⁿ states, together with the implementation of Boolean logic gates and digital circuitry such as 2–4 and 3–8 decoders, are successfully conducted. More complex logic circuits are also envisioned. The experiments thus substantiate 3D spin-orbitronic structures as a promising platform for exponentially boosting the storage capacity and accommodating in-memory computing that can be important for promoting the emerging 3D nanospintronics.     

Single Small Molecule-Assembled Mitochondria Targeting Nanofibers for Enhanced Photodynamic Cancer Therapy In Vivo

Photodynamic therapy (PDT) has emerged as an attractive alternative in cancer therapy, but its therapeutic effects are limited by the nonselective subcellular localization and poor intratumoral retention of small-molecule photosensitizes. Here a fiber-forming nanophotosensitizer (PQC NF) that is composed of mitochondria targeting small molecules of amphiphilicity is reported. Harnessing the specific mitochondria targeting, the light-activated PQC NFs produce approximately 110-fold higher amount of reactive oxygen species in cells than free photosensitizers and can dramatically induce mitochondrial disruption to trigger intense apoptosis, showing 20–50 times better in vitro anticancer potency than traditional photosensitizers. As fiber-shaped nanomaterials, PQC NFs also demonstrated a long-term retention in tumor sites, solving the challenge of rapid clearance of small-molecule photosensitizers from tumors. With these advantages, PQC NFs achieve a 100% complete cure rate in both subcutaneous and orthotopic oral cancer models with the administration of only a single dose. This type of single small molecule-assembled mitochondria targeting nanofibers offers an advantageous strategy to improve the in vivo therapeutic effects of conventional PDT.     

Stretchable ITO-Free Organic Solar Cells with Intrinsic Anti-Reflection Substrate for High-Efficiency Outdoor and Indoor Energy Harvesting

Flexible photovoltaic devices are promising candidates for triggering the Internet of Things (IoT). However, the power conversion efficiencies (PCEs) of flexible organic photovoltaic (OPV) devices with high conductivity poly(3,4-ethylene dioxythiophene):polystyrene sulfonate (PEDOT:PSS) electrodes on plastic are lagging behind the rigid devices due to the low transmittance of polyethylene terephthalate (PET)/PEDOT:PSS. Moreover, the poor stretchability of the commonly used plastic substrates largely hinders the practical application of wearable devices. Herein, a novel stretchable indium tin oxide (ITO)-free OPV device with a surface-texturing polydimethylsiloxane (PDMS) substrate for outdoor strong- and indoor dim-light energy harvesting is reported. The high diffuse transmittance and haze effect of the substrate enable stretchable ITO-free devices, yielding a high PCE of 15.3% under 1 sun illumination. More excitingly, the stretchable device based on textured PDMS/PEDOT:PSS maintains a comparable PCE of 20.5% (20.8% for the rigid device) under indoor light illumination. Notably, the stretchable device is much more insensitive to the light direction, maintaining 38.5% of the initial PCE at an extremely small incident angle of 10° (16.3% for glass/ITO-based counterpart). The texturing stretchable substrate provides a new direction for achieving high performance and enhanced light utilization for the stretchable light-harvesting device, suitable for indoor and outdoor applications.     

Public interest in continued use of Chinese government portals: A mixed methods study

Public adoption of policies detailed on government websites is an important topic in the field of e-government research, and researchers have mainly focused on the key factors that influence initial adoption. However, there has been much less discussion on factors influencing the continued use of government websites. This study identifies and tests a theoretical model that predicts consumers’ intentions to continue using government portals, using a mixed methods approach based on Grounded Theory. To construct a theoretical framework of public interest in continued use of government information portals, we interviewed 56 respondents and coded the interview data. Next, we tested the resulting model using data collected from a questionnaire-based survey of 354 users. The Structural Equation Modeling (SEM) results indicate that continued use is influenced by psychological perception, user characteristics, service parameters of the government portals and the government’s idea. Of these, psychological perception was found to have the strongest effect. These findings enrich the theoretical system of e-government public adoption of intention and have important practical significance for the development of Chinese government portals.     

Tungsten‐Based Materials for Lithium‐Ion Batteries

Lithium‐ion batteries are widely used as reliable electrochemical energy storage devices due to their high energy density and excellent cycling performance. The search for anode materials with excellent electrochemical performances remains critical to the further development of lithium‐ion batteries. Tungsten‐based materials are receiving considerable attention as promising anode materials for lithium‐ion batteries owing to their high intrinsic density and rich framework diversity. This review describes the advances of exploratory research on tungsten‐based materials (tungsten oxide, tungsten sulfide, tungsten diselenide, and their composites) in lithium‐ion batteries, including synthesis methods, microstructures, and electrochemical performance. Some personal prospects for the further development of this field are also proposed.     

Binary Controls on Interfacial Magnetism in Manganite Heterostructures

The complex interfacial correlations provide new routes toward tunable functionalities. Here, the wide range of tunabilities for magnetic properties are presented, including Curie temperature (from 245 to 320 K), coercive field (from 2 to 205 Oe), and saturated magnetic moment (from 0.9 to 2.8 µ_B Mn^?1), in a 9‐unit‐cell La_2/3Sr_1/3MnO₃ (LSMO) layer via modifying interfacial boundary conditions. Moreover, the LSMO/PbTiO₃‐based multilayers and superlattices that consist of PbTiO₃/LSMO/NdGaO₃ and PbTiO₃/LSMO/PbTiO₃ interfaces are characterized by two distinct Curie temperatures and coercive fields. The results reveal the feasibility of the interface‐resolved strategy based on boundary modification in fabricating potential devices with multiple accessible states for information storage. The wide‐range modulations on magnetic properties at LSMO/titanate interfaces are explained in terms of binary controls arising from the oxygen octahedral coupling (OOC) and magnetoelectric coupling (MEC). The results not only shed some light on understanding interfacial correlations in oxide heterostructures, but also pave an alternative path for exploring multiple accessible states in all‐oxide‐based electronic devices.     

Tailoring of Photoluminescence Properties in All-Vacuum Deposited Perovskite via Ruddlesden–Popper Faults

Ruddlesden–Popper (RP) faults are well known in oxide perovskites, and are also observed in promising metal halide perovskites. However, the effect of RP faults on optical properties of perovskite has not been systematically investigated. In this study, it is found that RP faults are common planar faults in all-vacuum deposited CsPbBr₃-based perovskite polycrystal thin films, and the density of RP planar faults can be greatly increased by non-stoichiometric composition (Cs-rich) as well as reduced dimensionality (quasi-2D) strategies. The photoluminescence (PL) measurement reveals monotonically increasing peak intensities with higher densities of RP planar faults from Cs-rich, quasi-2D to Cs-rich & quasi-2D samples. The corresponding atomic-scale differential phase contrast maps indicate strongly confined charges within the RP planar fault network, which explains well the relationship between PL enhancement and the density of RP planar faults, and offers an alternative pathway for tailoring the optoelectronic properties of perovskite.     

p型重掺杂应变Si1-xGex基区内建电场的物理机制

采用解析的方法计算了在基区掺杂为高斯分布,Ge组分分布为三角形分布和矩形三角形分布时基区内建电场的变化情况.重新拟合了价带有效态密度公式,并在计算内建电场时考虑了导带有效态密度的影响.发现加入Ge组分后引起的导带有效态密度变化、价带有效态密度变化以及禁带宽度变窄量变化对基区内建电场的影响要大于掺杂对内建电场的影响.Ge组分为三角形分布时,在总的Ge组分一定的条件下,内建电场从发射结到集电结逐渐变大.在任一给定位置x处,内建电场随着Ge组分的增加而增大.当Ge组分分布为矩形三角形分布时,对于给定的Ge组分转折点x1,基区内建电场从发射结到集电结缓慢地增大.在Ge组分恒定的区域,内建电场变化甚微,在Ge组分为线性缓变区域的同一位置x处,内建电场随Ge组分转折点x1的增大而缓慢地增大.此外,在x1附近内建电场变化有一个很大的陡坡.     

Estimation of carrier frequency offsets for MIMO systems with distributed transmit antennas

The problem of estimating the carrier frequency offsets in Multiple-Input Multiple-Output (MIMO) systems with distributed transmit antennas is addressed. It is supposed that the transmit antennas are distributed while the receive antennas are still centralized, and the general case where both the time delays and the frequency offsets are possibly different for each transmit antenna is considered. The channel is supposed to be frequency flat, and the macroscopic fading is also taken into consideration. A carrier frequency offset estimator based on Maximum Likelihood (ML) is proposed, which can separately estimate the frequency offset for each transmit antenna and exploit the spatial diversity. The Cramer-Rao Bound (CRB) for synchronous MIMO (i.e., the time delays for each transmit antenna are all equal) is also derived. Simulation results are given to illustrate the per- formance of the estimator and compare it with the CRB. It is shown that the estimator can provide satisfactory frequency offset estimates and its performance is close to the CRB for the Signal-to-Noise Ratio (SNR) below 20dB.