Kinetic study of the curing behavior of bismaleimide modified with diallylbisphenol A

The curing kinetics of bismaleimide modified with diallylbisphenol A were investigated for different ratios of 1,1′‐(methylene di‐4,1‐phenylene) bismaleimide and diallylbisphenol A with differential scanning calorimetry. Multiheating‐rate and isothermal methods were used to study the kinetics of the curing process. The results indicated that the activation energy changed with the extent of conversion. The activation energy obtained by the multiheating‐rate method was higher than that obtained by the isothermal method. Two kinetic models (autocatalytic and nth‐order) were successfully used to model the curing process. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2229–2240, 2003     

UHMWPE/LDPE复合材料拉伸破坏的声发射特性研究(Ⅱ)

本文续“UHMWPE/LDPE复合材料拉伸破坏的声发射特性研究(Ⅰ)”,进一步研究了UHMWPE/LDPE复合材料拉伸破坏的声发射特性,具体研究了[0°]、[90°]在拉伸破坏过程中声发射参数特征,并对拉伸破坏机理进行了初步的研究。     

Gemini表面活性剂的结构特点及在采油中的应用

文章简要地介绍了Gemini表面活性剂的结构特点；从表面活性剂的作用原理出发，介绍了Gemini表面活性剂的优良性能：如表面张力、泡沫力、润湿力、优异的协同效应、耐温抗盐性等；在此基础上，阐述了该类表面活性剂在油田三次采油上的应用前景。     

塔板结构参数对负荷性能曲线的影响

通过对板式塔流体力学性能的分析，找出了板式塔塔板结构参数对负荷性能图中负荷性能曲线的影响关系，可用于指导板式塔的优化设计和改造。     

水泥厂CDM项目开发

清洁发展机制（cDM）的开发，有利于发达国家温室气体减排任务的实现，又有利于发展中国家的技术进步。文章简要介绍了CDM的基本概念和申报CDM项目应满足的条件，重点介绍了水泥行业开发CDM项目的潜力及其相应的方法学和适用条件：同时还介绍了CDM的开发进程和效益分析。     

注射成型模具排气槽的设计

塑料注射成型模具的排气方式和排气槽结构直接影响塑料制品质量。介绍了塑料注射成型模具的排气方式、排气槽设计经验以及切实可行的排气方案和排气槽结构。     

Effect of Cr3C2 on Valence-Electron Structure and Plasticity of Rim Phase in Ti(C,N)-Based Cermets

Based on the empirical electron theory of solids and molecules, the valence-electron structure (VES) of the rim phase in Ti(C,N)-based cermets was calculated, and the relationship between the VES and plasticity was determined. The results indicated that the plasticity of the rim phase in a Ti(C,N)-based cermet could be defined using the sum of the n _a values for the covalent bonds, and that chromium dissolution in the rim phase improved the plasticity of the rim phase. Moreover, a series of experiments showed that adding Cr₂C₃ to a typical Ti(C,N)-based cermet strengthened the interface. Based on those results, a Ti(C,N)-based cermet with added Cr₃C₂ was manufactured; the new cermet had more than twice the transverse rupture strength of a typical cermet.     

Glass‐transition temperature in the curing process of bismaleimide modified with diallylbisphenol A

The T_g‐conversion relationship, during the thermal curing of different stoichiometric formulations of 1,1′‐(methylene‐di‐4,1‐phenylene) bismaleimide (BMI), modified with o,o′‐diallyl bisphenol A (DABA), was investigated. The DiBenedetto equation was used to model this relationship for the formulation of DABA‐1 (BMI : DABA, 1 : 1). Based on this model, the T_g‐conversion relationship of formulation DABA‐0.5 (BMI : DABA, 1 : 0.5) was modeled. The high consistency between the model curve and experimental data showed that the change of T_g, attributed to copolymerization between BMI and DABA in DABA‐0.5, in the low‐conversion regime, was the same as that in DABA‐1. This also verifies that, for the formulation DABA‐0.5, copolymerization and homopolymerization do not overlap with each other. The reactions progressed sequentially and homopolymerization occurred after completion of copolymerization. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3244–3247, 2004     

基于软件定义网络和移动边缘计算的车联网高效任务卸载方案

随着车联网(IoV)中车辆和智能应用数目的增加使计算密集型任务激增,传统架构难以满足用户需求。为解决车联网计算资源不足且分配不均匀、应用时延需求无法满足、任务能耗成本较高的问题,结合移动边缘计算(MEC)和软件定义网络(SDN),设计了一种从宏基站到MEC服务器到车辆的车联网架构中的高效任务卸载方案,并提出一种改进的低复杂度非支配排序遗传算法,优化任务卸载成本和MEC服务器的负载均衡率。实验仿真结果表明,相比于随机卸载,NO-MEC卸载,NO-I卸载,传统NSGA、NSGA-Ⅱ卸载,GA卸载,Q-learning卸载,DQN卸载方案,所提方案有着更低的卸载成本,更优的负载均衡率,得到近似最高的系统效用,能够给车联网中的车辆用户带来更优质的网络服务。