GIS用环氧树脂的增韧改性研究

制备了一种聚氨酯型热致性液晶聚合物,采用液晶增韧改性环氧树脂,分析液晶的含量对环氧树脂力学性能和耐热性的影响。在环氧树脂中同时添加液晶和Al2O3制备了三元共混体系,并对共混体系的力学性能和电性能进行分析。结果表明:当液晶与环氧的质量比为3∶100时,复合材料的冲击强度相对于纯环氧树脂体系提高了60%,拉伸强度和弯曲强度也分别提高了80%和87%,而且液晶的加入对环氧的耐热性基本没影响。在室温下,三元体系的介电常数是二元体系介电常数的1.5倍。     

基于多特征融合条件随机场的人脸图像分割

由于发型、头部姿势、服装、遮挡等现象的多样性,人脸图像分割一直是一个具有挑战性的课题。为了提高复杂背景图像的人脸分割正确性,提出了一种基于多特征融合条件随机场（CRFs）的方法。该模型建立在图模型上,图中的每一个节点对应一个超像素,每一条边缘则连接一对相邻的超像素。使用颜色和纹理特征定义节点的能量函数（一元能量函数）,使用位置信息和相邻超像素之间的差异定义边缘的能量函数（二元能量函数）。分割是通过条件随机场融合节点能量函数和边缘能量函数推理而得。考察了该模型在2个无约束人脸数据库上的分割性能,实验结果表明该方法可以有效地从复杂人脸图像中分割出面部皮肤、头发和背景区域。     

电压间谐波对紧凑型荧光灯光闪变效应的实验研究

为进行实验研究,对IEC闪变仪模型中的加权滤波器进行分解,提出闪变仪的分解模型,该模型可直接导入实验获得的光通量信号以进行光闪变强度Pst计算,实验验证了该模型的可行性和有效性;设计并建立了实验装置,利用高准确度照度计采集紧凑型荧光灯在含有特定间谐波频率和幅值的电压下的光通量输出,使用闪变仪分解模型,对其在间谐波电压下的光闪变效应进行实验研究,获得了紧凑型荧光灯在不同间谐波频率和含量下的光闪变强度Pst,并据此提出了针对紧凑型荧光灯光闪变的间谐波限制曲线。     

配电网三相不平衡过电压有源抑制方法研究

分析三相不平衡电压的产生机理,提出有源抑制方法,设计了有源逆变装置,等效为可控电流源,安装在中性点与地之间,优化控制注入电流的大小和相位,能强迫电网三相电压平衡。仿真分析和样机实验测试结果表明,该方法不需要测量线路对地参数,抑制三相不平衡过电压速度快、准确度高,甚至能将中性点位移电压抑制到零。     

The flame‐retardant properties and mechanisms of poly(ethylene terephthalate)/hexakis (para‐allyloxyphenoxy) cyclotriphosphazene systems

Para‐allyl ether phenol derivative of cyclophosphazene (PACP) was prepared and used as a filler to modify the flame‐retardant properties of poly(ethylene terephthalate) (PET) by melting‐blending. The mechanism of flame‐retardant was discussed and the influences of flame‐retardant contents to the mechanical properties were studied. The results revealed that the incorporation of only 5 phpp PACP (0.37 wt % phosphorus containing) into PET matrix can distinctly increase the flame retardancy of PET/PACP composition, and it has a little effect on the mechanical properties of PET. The high flame‐retardant performance of PET/PACP composite was attributed to the combination of condensed‐phase flame retardant and gas‐phase flame retardant. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42711.     

Simultaneous detection and removal of metal ions based on a chemosensor composed of a rhodamine derivative and cyclodextrin-modified magnetic nanoparticles

A variety of chemosensors have been reported for detection of metal ions. However, the metal ions could not be separated and removed at the same time for the goal of water purification. This paper presents to detect and remove metal ions from aqueous solution simultaneously by a fluorescence chemosensor and functional magnetic nanoparticles. A novel probe adamantyl (AD)–maleic anhydride (MAH)–rhodamine B (RhB) was designed and synthesized from RhB, ethylene diamine, MAH, and AD. AD–MAH–RhB showed high selectivity and sensitivity to metal ions in aqueous solution. The sensing mechanism was explored by FTIR and mass spectra. The results suggested that AD–MAH–RhB could conjugate with metal ions and form the binding complexes with various stoichiometries of probe and metal ions. Moreover, β-cyclodextrin-modified magnetic nanoparticles (CD-MNP) were fabricated and used as host materials to form inclusion complex of CD-MNP and AD–MAH–RhB-metal ions. Then, the metal ions could be removed by an outer magnet, which were confirmed by fluorescent spectrum. The probe and CD-MNP had the great potential application for sewage treatment.