钢管除锈机设计与经验

介绍了钢管除锈机的基本原理及设计过程,实践证明:使用钢管除锈机不仅保证了除锈质量,还提高了工作效率。     

Insights into the intrinsic interaction between series of C1 molecules and surface of NiO oxygen carriers involved in chemical looping processes

Understanding and modulating the interaction between various reactive molecules and oxygen carriers are the key issue to achieve process intensification of chemical looping technology. C1 chemical molecules play an important role in many reactions involved with chemical looping processes. However, up to now, there is still a lack of systematic and in-depth understanding of the adsorption mechanism of C1 molecules on the surface of oxygen carriers (OCs). In this work, the intrinsic interaction between a series of C1 molecules composed of CH₄, CO, CO₂, CH₃OH, HCHO and HCOOH and surface of NiO OCs in the chemical looping process have been studied using density functional theory calculations. Various adsorption configurations of C1 molecules and also different adsorption sites of NiO have been considered. The structural features of stable configuration of C1 molecules on the surface of NiO OCs have been obtained. Further, the interacted sites, types and strengths of C1 molecules on the surface of NiO have been directly pictured by the independent gradient model methods. Also, the nature of the interaction between C1 molecule and NiO surface has been investigated with the aid of energy decomposition analysis from a quantitative view.     

空压机组汽轮机排气压力、温度高原因分析及解决方法探讨

1概况 空压机汽轮机组是空分装置原料和动力的提供者,主要由空压机和工业汽轮机两部分组成.汽轮机为注入凝汽式汽轮机,型号NK-32/36/16-3,级数为1冲动级15反动级,功率9022kW,额定转速7270 r/min,主蒸汽压力6.9 Mpa,主蒸汽温度550℃,主蒸汽流量通常31.9t/h,最大36.8t/h,排汽压力通常0.015MPa,最大0.04MPa,排汽温度通常55℃,最大120℃.但由于多种原因,注汽一直未投,平常为全凝汽式运行.     

聚氯乙烯塑料中多种邻苯二甲酸酯类增塑剂的同时测定

为了在线监控聚氯乙烯塑料中增塑剂的含量,利用傅立叶变换红外光谱法-ATR技术测定样品的红外光谱,采用偏最小二乘法对所测红外光谱进行分析,建立了一种无损快速分析方法,定量地测定聚氯乙烯塑料中多种邻苯二甲酸酯类增塑剂的含量。该方法测量精密度的变异系数小于6%,测量准确度的变异系数小于3%。该方法不受基体的干扰,简单快速,适合于流水线的质量控制。     

基于浏览器 /服务器的橡胶加工网络测控系统

通过对客户机／服务器模式和浏览器／服务器模式的比较，选择浏览器／服务器模式组建了基于Internt/Intranet的远程橡胶加工网络测控系统，并介绍了系统的开发模式、方法和注意事项。     

Rheological properties of bitumen in water emulsions with added solids

Experimental work was carried out to investigate the rheological properties of bitumen in water emulsions containing solids of different shape and size. The bitumen volumetric concentration was varied up to 60%, solids free basis, and the solids volume fraction (total volume basis) was varied up to 0.2. Irregular-shaped silica sand (average diameter: 9 and 33 μm) and smooth spherical glass beads (average diameter: 27 and 44 μm) were used as the added solids. In the low shear stress range, shear thinning behavior was observed for bitumen in water emulsions. At high shear stress, the viscosity of the emulsions became fairly independent of the shear stress. The addition of solids to the bitumen emulsions increased the mixture viscosity. The addition of irregular-shaped silica sand gave a higher viscosity than a similar addition of the spherical glass beads. The viscosity of the emulsion/solids mixtures was influenced by the solids size as well; the smaller size particles gave a higher viscosity. The addition of solids to the bitumen emulsions also induced shear thickening (dilatancy) behavior at high solids volume fraction. The degree of the shear thickening increased with the oil concentration.     

Complementarity determining region residues aspartic acid at H55, serine at H95 and tyrosines at H97 and L96 play important roles in the B72.3 antibody-TAG72 antigen interaction

Structural analysis derived from the crystallographic studyof the chimeric B72.3 antibody illustrated some major atomicinteractions between complementarity determining region (CDR)residues. For example, hydrogen bonds are formed between H35/H95,L50/H97, H53/H55 and H96/L96 respectively. These CDR residuesmay play important roles in the B72.3–TAG72 (antibody-antigen)interaction either by direct interaction with the TAG72 antigenor by maintaining a CDR loop conformation through atomic interactionsbetween CDR residues. In order to confirm these assumptions,we altered these CDR residues by site-directed mutagenesis anddetermined binding affinities of these mutant chimeric antibodiesfor the TAG72 antigen in a solid-phase radioimmunoassay. Wefound that H55, H95, H97 and L96 are important CDR residuesfor the B72.3–TAG72 interaction. Single amino acid substitutionsof aspartic acid and serine by alanine at H55 of CDR2 and atH95 of CDR3 respectively and of tyrosine by phenylalanine atH97 and L96 of CDR3, significantly reduced the binding affinityfor the TAG72 antigen by 20-, 8-, 16- and 45-fold respectively.Therefore, this study reveals some of the requirements for maintainingthe integrity of the B72.3 antibody combining sites.     

多孔β-TCP陶瓷药物载体结构与性能的影响因素

本分析了影响多孔β-TCP陶瓷药物载体结构与性能的因素，确定了制备多孔β-TCP陶瓷药物载体的技术路线和工艺参数。     

近十年常温干法精脱硫专利技术发展动态

收集了近十年来国内的常温干法精脱硫专利，并分类列举出各种脱硫剂的物化性质和几种常温精脱硫工艺，重点阐述了该技术的优缺点及其未来发展方向。     

碳酸二苯酯技术发展现状及展望

综述了碳酸二苯酯多种合成技术的发展现状，重点介绍了碳酸二甲酯与苯酚酯交换法和氧化羰基化法技术，并对碳酸二苯酯技术在国内的发展进行了展望。