What is the Effect of Critical Surface Tension of PbSO3 Thin Film?

This study focuses on the critical surface tension of lead sulfite (PbSO₃) crystalline thin film produced with chemical bath deposition on substrates (commercial glass).The PbSO₃ thin films were deposited at room temperature at different deposition times. The structural properties of the films were defined and examined according to X-ray diffraction (XRD) and the XRD results such as dislocation density, average grain size, and no. of crystallites per unit area. Atomic force microscopy was used to measure the film thickness and the surface properties. The critical surface tension of the PbSO₃ thin films was measured with an optical tensiometer instrument and calculated using the Zisman method. The results indicated that the critical surface tension of films changed in accordance with the average grain size and film thickness. The film thickness increased with deposition time and was inversely correlated with surface tension. The average grain size increased according to deposition time and was inversely correlated with surface tension.     

Effects of sodium caseinate‐ and milk protein concentrate‐based edible coatings on the postharvest quality of Bing cherries

Bing cherries were coated with sodium caseinate‐ or milk protein concentrate‐based edible coatings. Besides the proteins (100 g kg^?1), the coating formulations also included glycerol (about 300 g kg^?1 protein) and either beeswax or a stearic–palmitic acid blend at a concentration of 0, 100 or 300 g lipid phase kg^?1 of protein. All coatings, especially those containing 300 g kg^?1 stearic–palmitic acid blend, successfully reduced water loss of the fruits. The edible coatings had a beneficial effect on the sensory quality of the cherries, and there were significant (p < 0.05) effects of the coating treatments on soluble solids, titratable acidity and pH. Copyright © 2004 Society of Chemical Industry     

Temperature Dependent Current Transport Mechanism of Photopolymer Based Al/NOA60/p-Si MPS Device

A photopolymer based Al/Norland Optical Adhesive 60 (NOA60)/p-Si MPS (metal-polymer-semiconductor) device was fabricated by a combination of vacuum evaporation and smear technique. The current transport properties of the device were investigated by using the forward bias current–voltage (I-V) characteristic in the temperature range of 80–300 K. The cross-sectional structure of polymer/semiconductor was revealed by the scanning electron microscope (SEM) image and it was seen that the NOA60 photopolymer was tidily coated on the p-Si surface. According to the I-V measurements at room temperature, the MPS device exhibits a good rectification ratio of 8140 at?±?1 V. The temperature-dependent I-V measurements (I-V-T) were analyzed based on the thermionic emission (TE) theory and an abnormal increase in zero-bias barrier height (BH) and a decrease in ideality factor (n) was observed with increasing temperature. Additionally, two different linear regions with distinct values from the theoretical value of the Richardson constant (A*) were observed in the conventional Richardson plot. Such deviations from the ideal TE theory have been attributed to the effect of BH inhomogeneities. Gaussian distribution (GD) of the BH model has applied the I-V-T results and the double GD BH with mean values of 0.75?±?0.08 eV (80–140 K) and 1.02?±?0.11 eV (140–300 K) were calculated. Moreover, the A* value of 31.4 A/cm²K² was calculated close to the known value of p-Si from the modified Richardson plot. Thus, it has been concluded that the current transport of the Al/NOA60/p-Si MPS device can be explained by TE with a double GD BH model for a wide temperature region.

     

Determination of the quality and purity characteristics of olive oils obtained from different regions of Turkey,depending on climatic changes

Virgin olive oils (VOOs) obtained from olives grown in different regions of Turkey under changing climatic conditions sometimes show different sensory and chemical properties. This study was planned to determine whether these deviations are due to climatic changes or not. For this purpose, five different olive varieties (Ayvalık, Memecik, Gemlik, Nizip Yağlık, Kilis Yağlık) of commercial importance were harvested from the provinces/districts (four different region) where cultivation is intense during the 2017/2018–2020/2021 harvest years. Every year, olive samples were collected from 3 orchards from 13 provinces/districts. One hundred and fifty-six samples were subjected to the purity, quality and sensory analysis. Basic climatic values (average, minimum and maximum temperature, humidity and precipitation) were examined for four consecutive years. All of the examined olive oil samples were determined within the legal limits in terms of fatty acid composition and fatty acid ethyl ester values. However, delta-7-stigmastenol value from the sterol composition was found to be above 0.5% in some samples in all the years studied (total 21 samples). Delta-7-stigmastenol values of olive oil samples varied between 0.16% and 1.14%. Multiple linear regression analysis was applied using a genetic algorithm-based inverse least squares method to determine whether there is a relationship between climate data and delta-7-stigmastenol values. According to this result, it has been determined that the delta-7-stigmastenol value is high when the annual average relative humidity is low and the annual average temperature is high. There is an urgent need to make forward-looking plans due to climate change.     

Effect of roasting on the physico-chemical properties,fatty acids,polyphenols and mineral contents of tobacco (Nicotiana tabacum L.) seed and oils

The physico-chemical properties, phytochemicals, mineral contents of tobacco (Nicotiana tabacum L.) seeds grown at Samsun province in Turkey were evaluated. The oil contents of tobacco seeds ranged from 20.6% (control) to 29.0% (microwave-roasted). L*, a* and b* values of tobacco seeds ranged from 32.38 to 35.61; from 6.32 to 6.78; from 13.72 to 14.27, respectively. Total phenolic contents of tobacco seed extract and oils were reported between 31.02 (oven-roasted) and 34.42 mg GAE/100 g (microwave-roasted) to 4.60 (microwave-roasted) and 6.45 mg GAE/100 g (oven-roasted), respectively. Total flavonoid values of raw and roasted tobacco seed extract and oils were determined between 26.62 (oven) and 67.10 mg/100 g (control) to 21.57 (control) and 44.71 mg/100 g (microwave-roasted), respectively. Gallic acid, 3,4-dihydroxybenzoic acid and catechin are the predominant phenolic components of raw and roasted tobacco seed oils. The amounts of oleic and linoleic acid in raw and roasted tobacco seed oils ranged from 10.23% (oven-roasted) to 12.48% (control) and 73.72% (control) to 76.63% (oven-roasted), respectively. The abundant elements found in seeds were K, P, Ca, Mg, S and Fe. The mineral amounts of the roasted seeds were found higher than that of the control. The highest increase was detected in oven roasted tobacco seeds.     

The role of coal in energy production—Consumption and sustainable development of Turkey

Energy is one of the indispensable factors regarding the assurance of social prosperity and economic development of a country. The developing countries struggle to obtain energy sources reliable in the long term to complete their economic development, and the developed countries struggle to get them to keep their present prosperity levels. Coal seems to continue its indispensable position among the other energy sources for many years because of its production in more than 50 countries, the least effect it has from the price fluctuation and its usage lifespan of more than 200 years. The countries that are aware of it have investments in mining fields in the countries rich in coal reserves, and they continue investing considerable amount of money.     

Dynamic analysis of a trickle bed reactor by moment technique

The performance of a trickle bed reactor is investigated by the moment technique. Residence time distributions of SO₂ tracer in both gas (Helium) and liquid (distilled water) effluents are used to predict zero reduced and first absolute moments and these values are compared with the derived theoretical expressions. Correlations are suggested for gas-liquid mass transfer coefficient, liquid hold up, and extent of axial mixing in liquid phase.True adsorption equilibrium constant of the system is estimated as 0.378 from liquid full bed experiments and contacting efficiency of the trickle bed reactor is found as 0.987.Effect of axial dispersion is not significant on gas-liquid mass transfer coefficient since absorption factor is small, but is found to be quite important on the true estimation of adsorption factor.