An architectural evaluation method for conservation of traditional dwellings

Historic urban sites and traditional houses are the most important evidence of the past life style. The conservation of these traditional values in the context of conservation and revitalization of architectural heritage is in a sense the preservation of culture. The main goal of conservation is to enliven cultural properties by evaluating their architectural, historical, environmental, visual and aesthetic characteristics. These evaluation studies, which are essential in the context of conservation plans, are inevitable phases to determine the principles of the plans. This study is aimed to propose a method for the architectural evaluation phase, which is essential before conservation decisions. The proposed method is based on a gradation system. Odunpazar? district in Eski?ehir/Turkey is determined as the area to test this gradation method. It is proposed that this method explains the systematic way for evaluating architectural features belonging to historic sites whose conservation plans are to be prepared. In the study, traditional buildings are evaluated from the point of their exterior and interior architectural characteristics and classified as different value groups: A, B, C and D. This grouping will be advantageous to conservation decisions. Different technical teams may be organized to be responsible for these various value groups. As a result, a systematic approach for the determination of specialized teams and required equipment will be achieved. Thus, an accurate determination of required time and cost estimates will be realized.     

Mean grain size determination in marbles by ultrasonic first backwall echo height measurements

In ultrasonic grain size determination several techniques are in use. In this paper, the Ultrasonic Relative Attenuation (URA) method has been used to estimate the mean grain size of marble samples. Also, mean grain size versus first backwall echo height graphs have been plotted to see the direct relation between these two parameters. The results show less than 10% difference compared with values obtained in an optic microscope. In a comparison, mean grain size values of marbles determined by ultrasonic velocity methods are given.     

Measurements of the total molecular differential attenuation coefficients of some compounds for scattering of γ-rays

The differential attenuation coefficients for total scattering have been measured using the Si(Li) detector at photon excitation energy of 59.5 keV for Fe₂O₃, Y₂O₃, Nb₂O₅, SeO₂, Sb₂O₅ and BaO compounds at seven angles ranging from 60° to 120° at intervals of 10°. The obtained results have been compared with relativistic and non-relativistic theoretical values.     

Statistical Modeling of β-galactosidase Inhibition During Lactose Hydrolysis

A statistical model approach called response surface methodology was used to describe the product and substrate inhibition effect on β-galactosidase enzyme during lactose hydrolysis. The effect of independent variables, namely the initial concentrations of lactose (73 - 146 mM), galactose (44 - 122 mM) and glucose (83 - 167 mM) on the reaction rate of β-galactosidase was evaluated. The enzymatic reaction rate was influenced by both combined and individual effects of all the substrate and products. Although, glucose acted as an activator at low lactose and low galactose concentrations, glucose caused the inhibition of β-galactosidase at higher concentrations of lactose and galactose. The effect of galactose concentration on β-galactosidase enzyme was in the direction of inhibition. At low lactose concentrations and high glucose concentrations, galactose concentration became more effective on the reaction rate.     

The contact problem of an orthotropic non-homogeneous elastic half space

The problem of a rigid punch on an elastic half plane with orthotropic and non-homogeneous material is considered. The axes of orthotropy are chosen to coincide with the Cartesian coordinate system in which one axis is parallel to the edge of the half plane and the other is perpendicular to it. Non-homogeneity is introduced in both directions of orthotropy as continuous functions along these directions. Using the Fourier Transform Technique, the mixed boundary value problem is reduced to a singular integral equation which is solved numerically. The formulation of the problem is obtained for a rigid punch with arbitrary shape.     

Modelling of heat and moisture transport during drying black grapes

In this work, heat and moisture transport occurred during drying of black grapes in a laboratory dryer were investigated. In the experiments, the air was passed through the chamber at a variety of flow rates (0.5, 0.75, 1.0 and 1.25 m s^?1) and temperatures (40, 50, 60 and 70 °C). Thermal and moisture diffusivities were determined. The possibility of expressing the moisture removal from the grapes was searched with the fourteen one‐layer drying models selected from the literature. Among all the models, the Page model was found the best for explaining the experimental results. The effects of the drying temperature and air velocity on the constants and coefficients of Page model and diffusivities were also investigated by multiple combinations of the different equations as the linear, power, logarithmic, exponential, polynomial, inverse polynomial and Arrhenius type by non‐ linear regression analyses. Models obtained were also analysed statistically using t‐test, RMSE, MBE and χ².     

Removal of basic dyes from aqueous solutions by crosslinked‐acrylic acid/acrylamidopropane sulfonic acid hydrogels

In this study, Acrylic acid (AA)/2‐acrylamido‐2‐methlypropane sulfonic acid (AMPS) hydrogels were prepared by free radical polymerization in aqueous solutions of AA, AMPS, and N,N‐methylenebisacrylamide (NMBA) as crosslinker. Potassium persulfate (PPS)/potassium bisulfide (PBS) were used as initiator and accelerator pair. The water absorption capacities and dye adsorption properties of the hydrogels were investigated. Adsorption properties of the hydrogels were evaluated by depending on different adsorption conditions such as different initial dye concentration and contact time. The concentrations of the dyes were determined using UV/Vis Spectrophotometer at wavelength 530 nm for safranine T (ST) and 622 nm for brilliant cresyl blue (BCB). Adsorption kinetic studies showed that pseudo‐first order kinetic model is suitable to explain the adsorption kinetic data of the hydrogels. Langmuir and Freundlich isotherm models were used to describe adsorption data. The result revealed that the adsorption of basic dyes onto hydrogels fit very well both Langmuir and Freundlich isotherms. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Synthesis and characterization of imine‐coupled polyphenols containing carbazole units

Imine coupled phenolic monomers containing carbazole unit were synthesized in four steps. The monomers were polymerized via oxidative polycondensation by air as oxidant in an aqueous alkaline medium at 50°C. The structures of compounds were confirmed by ultraviolet–visible (UV–vis), Fourier transform infrared, and ¹H‐ and ¹³C‐NMR techniques. The conductivity measurements of these polymers were made by the four‐point probe technique and iodine was used as doping agent. The highest occupied molecular orbital, the lowest unoccupied molecular orbital, and electrochemical and optical band gap values were calculated by the results of the UV–vis and the cyclic voltammetry measurement, respectively. The number‐average molecular weight, weight‐average molecular weight, and polydispersity index values were determined by the size exclusion chromatography technique. Also, thermal behavior of these polymers was determined by thermogravimetric/differential thermal analysis measurements in a N₂ atmosphere between 20 and 1000°C. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

The synthesis,characterization, electrochemical character,catalytic and antimicrobial activity of novel,azo-containing Schiff bases and their metal complexes

Three novel Schiff base ligands containing the azo group, 2-((E)-(4-((E)-phenyldiazenyl)phenylimino)methyl)phenol, 3-((E)-(4-((E)-phenyldiazenyl)phenylimino)methyl)benzene-1,2-diol and 4-((E)-(4-((E)-phenyldiazenyl)phenylimino)methyl)benzene-1,2,3-triol, were synthesized from the reaction of p-aminoazobenzene with salicylaldehyde, 2,4-dihydroxybenzaldehyde and 2,3,4-trihydroxybenzaldehyde, respectively. The mononuclear Co(II) and Cu(II) complexes of the Schiff base ligands were prepared and characterized using elemental analyses, IR, UV–visible spectroscopy, magnetic susceptibility and conductance measurements; ¹H NMR and mass spectra of the ligands were also recorded. The Co(II) and Cu(II) metal complexes are formed by the coordination of the N and O atoms of the ligands. The electrochemical properties of the metal complexes were investigated at 100 mV s^?1 scan rate in DMSO; the oxidative C–C coupling properties of the Co(II) and Cu(II) complexes were investigated on the sterically hindered 2,6-di-tert-butylphenol (DTBP). In addition, the Schiff base ligands and their complexes were evaluated for both their in vitro antibacterial activity using the disc diffusion method.     

Current Urban Discourse,Urban Transformation and Gentrification in Istanbul

In the mid-2000s, unprecedented economic growth provided a catalyst for Istanbul's transformation. Tolga İslam outlines the background to large-scale urban development and renewal projects that have been undertaken by local authorities throughout the city. Copyright © 2010 John Wiley & Sons, Ltd.