镁铝锆复合金属氧化物的制备及对硼吸附性能的研究

实验成功制备了镁铝锆复合金属氧化物。考察了硼初始浓度、溶液pH、接触时间、温度、Cl-浓度对镁铝锆复合金属氧化物对溶液中硼吸附效果的影响。结果表明,Cl-浓度对硼的吸附影响很小,在温度为25℃,镁铝锆复合金属氧化物投加量为2.5 g/L,溶液pH为6,吸附时间为300 min,硼质量浓度为200 mg/L时,对硼的吸附效果最好,吸附量可以达到34.07 mg/g。镁铝锆复合金属氧化物对硼的吸附平衡符合准二级动力学模型和Langmuir吸附等温模型。     

基于ASP.NET的批量数据导入方法的研究与实现

基于Excel的批量数据导入方法,极大地提高了数据导入的准确性。该文通过与传统的数据导入方法相比较,介绍了两种更为有效的批量数据导入方法,大大提高了数据导入的效率。     

启动压力影响低渗透油田产量递减规律机理研究

中高渗透油藏分析方法是否仍适合低渗透油藏尚需验证。针对此问题,在低速非达西渗流理论的基础上,研究低渗透油藏的产量规律,并给出相应的油田产量递减率与产量、生产时间的算式,以及低渗透油田产量递减率通式。     

HMX/AP/Al/HTPB推进剂燃速模拟计算

考察了 HMX/AP/HTPB 推进剂及其组分的热分解特性,当混合氧化剂HMX 和 AP 之质量比为1:1时,其热分解曲线呈现出独特的单峰放热分解特征。考察了十种添加剂对 HMX、AP、HMX/AP 和 HMX/AP/HTPB 热分解性能影响以及对 HMX/AP/Al/HTPB 推进剂燃速的影响。提出了改进的 BDP 模型和燃速模拟计算。     

基于期望最大化算法和求容积卡尔曼平滑器的气动参数辨识算法

针对初值和噪声统计特性未知情形下的飞行器系统辨识的问题,提出了基于期望最大化(expectation maximization,EM)和求容积卡尔曼平滑器(cubature Kalman smoother,CKS)的辨识算法。该算法用期望最大化算法对初值和噪声的统计特性进行估计;用求容积卡尔曼平滑器估计状态向量和未知参数。在期望最大化算法的求期望步骤中,所求的期望值通过求容积规则获得,用较少的采样点保证了估计精度;在期望最大化算法的最大化步骤中,未知量的最优值以解析解形式给出,减小了计算量。仿真结果说明,该算法在飞行器气动参数辨识问题中,能给出较好的辨识结果。与其他方法的对比验证说明新算法具有辨识精度高、收敛速度快等优点。     

Influence of bubble diameter and solids concentration on bubble stability: Development of a novel analytical approach

The properties and thickness of the bubbles in the froth control the flotation process. There is no work showing how to measure bubble film composition and thickness by a straightforward manner. In this work, a novel approach, a custom-designed bubble cell associated with layer interferometry（in the UV-vis region） and FT-IR spectroscopy was used to investigate the effect of solid particle type（hydrophilic vs hydrophobic）, concentration and bubble diameter on stability of a bubble blown in air. Stability was quantified by measuring bubble lifetime and hydrated film thickness. Kerosene with silicone oil as a foaming agent was used to evaluate the impact of bubble diameter（test series I）. Frother solutions（MIBC, Dowfroth 250, Hexanol and F-150） were used for the solid type concentration experiments（test series II）. In the first series of experiments, it was determined that as the diameter of a bubble increased from 10 to 25 mm, so did the hydrated film thickness from 350 to 1000 nm. In the second series, as the silica concentration increased（0 to 10%）, an increase in bubble lifetime and hydrated film thickness was resulted（130%-250%）. An impact of solid hydrophobicity was found but to a lesser degree than expected. It is possible that the small particle size（〈0.1 m） of silica was responsible for this behavior. The findings are used to interpret the effect of solids in flotation froth.     

A novel approach to prevent bubble coalescence during measurement of bubble size in flotation简

Effect of frothers in preventing bubble coalescence during flotation of minerals has long been investigated. To evaluate the performance of a frother, an apparatus to measure the bubble size is a basic necessity. McGill Bubble Size Analyzer （MBSA） or bubble viewer that has been developed and completed by McGill University＇s Mineral Processing Group during the last decade is a unique instrument to serve this purpose. Two parameters which are thought to influence the bubble size measurements by McGill bubble viewer include water quality and frother concentration in the chamber. Results show that there is no difference in Sauter mean （D32） when tap or de-ionized water was used instead of process water. However, the frother concentration, in this research DowFroth 250 （DF250）, inside the chamber exhibited a pronounced effect on bubble size. Frother concentration below a certain point can not prevent coalescence inside the chamber and therefore caution must be taken in plant applications. It was also noted that the frother concentration which has been so far practiced in plant measurements （CCC75-CCC95） is high enough to prevent coalescence with the bubble viewer.     

Correspondence of bubble size and frother partitioning in flotation

The size of bubbles created in the flotation process is of great importance to the efficiency of the mineral separation achieved. Meanwhile, it is believed that frother transport between phases is perhaps the most important reason for the interactive nature of the phenomena occurring in the bulk and froth phases in flotation, as frother adsorbed in the surface of rising bubbles is removed from the bulk phase and then released into the froth as a fraction of the bubbles burst. This causes the increased concentration in the froth compared to the bulk concentration, named as frother partitioning. Partitioning reflects the adsorption of frother on bubbles and how to influence bubble size is not known. There currently exists no such a topic aiming to link these two key parameters. To fill this vacancy, the correspondence between bubble size and frother partitioning was examined. Bubble size was measured by sampling-for-imaging （SFI） technique. Using total organic carbon （TOC） analysis to measure the frother partitioning between froth and bulk phases was determined. Measurements have shown, with no exceptions including four different frothers, higher frother concentration is in the bulk than in the froth. The results also show strong partitioning giving an increase in bubble size which implies there is a compelling relationship between these two, represented byCFroth/CBulk andD32. TheCFroth/CBulk andD32 curves show similar exponential decay relationships as a function of added frother in the system, strongly suggesting that the frother concentration gradient between the bulk solution and the bubble interface is the driving force contributing to bubble size reduction.     

行走在华夏文化的摇篮中——西北和中原城市一瞥

自古以来,我们一直把黄河称作是中华民族的摇篮,是哺育华夏文明的母亲河,因为农耕文明的诞生和延续,需要与之相匹配的自然环境。在计划经济时代,中原地区的3个一级城市特色各异：郑州是省会城市,开封是消费城市,洛阳是重工业城市。现在的中原城市群是7大国家级城市群之一,它以郑州为中心,以洛阳为副中心,以开封等地区性中心城市为节点,构成了紧密联系圈。     

对潭口新区工程方案编制与实践的认识

潭口新区建设方案编制以节能降耗为出发点,机采系统依靠井底流压和目标产量确定工作参数,杆柱组合采用能耗最低设计方法,根据斜井抽油杆侧向力分布状况设计抽油杆扶正器设置间距;注水系统优化地面管网布局,降低了高压注水单耗;集输系统对单井集油管线进行了优化设计,充分利用油井伴生气资源,实现了单管常温集输和单管油气密闭集输,减少了原油损耗,降低了区块的能耗水平。