A method for preparing composite diffusion coating alloy on ceramic surface

Metallization of the ceramic surfaces of Si3N4 and Al2O3 was carried out in a composite diffusion coating vacuum furnace using a Ti-Cu composite target. The experimental process and influencing factors were discussed. Optical microscope (OM), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), X-ray diffusion (XRD) and sound emissive scratch test (SEST) were applied to evaluate the alloy layer formed on the ceramic surface. It was indicated that the diffusion coating alloy layer contained Cu, Ti, Fe, Al and Si etc. XRD result indicated that the diffusion coating alloy layer was composed of CuTi2, Cu, Si2Ti and CuTi, Al2TiO5, Ti3O5. It was found that the diffusion coating alloy layer got bonded with ceramic well, and no spallation occurred under the maximum load of 100N. Deposited Si3N4 ceramic was welded with Q235 and the joining quality was examined. Robust joint was formed between Si3N4 ceramic/Q235. This present method has advantages in high efficiency and low cost and provides a new approach for producing ceramic and metal bond.     

材料组织对高频焊管接头裂纹的影响

利用扫描电镜、断口分析和能谱分析手段，研究了材料组织和夹杂对高频焊接头裂纹和开裂的影响。通过调整焊接工艺可以减小这种影响，并提出了改进意见。     

碳钢表面激光熔覆铁基B_4C陶瓷涂层的组织与性能

利用5 kW横流连续CO2激光器,采用粉末预置法在Q235钢表面进行了激光熔覆铁基B4C陶瓷涂层的试验研究.通过试验,优化了工艺参数,深入分析了熔覆层的显微组织及相组成,测试了熔覆层显微硬度、耐磨损及耐腐蚀性能.结果表明,铁基B4C陶瓷复合涂层与基体达到良好的冶金结合,熔覆层组织主要是由短小柱状枝晶与细小的等轴晶组成,其组成相为α-Fe、Fe3C、Fe3(B,C)、Fe2B、CrB、Cr23C6等化合物,熔覆层中还发现未熔的B4C颗粒.与基体相比,熔覆层显微硬度显著提高,最高可达到1372 HV0.2,约为基体188 HV0.2的7倍;磨损实验表明,熔覆层与基体表面都出现了磨粒磨损特征的犁沟,熔覆层表面磨损的犁沟比基体浅且细密,熔覆层的耐磨性能显著提高.电化学测试结果也表明,熔覆层的耐腐蚀性能也得到了提高.     

5A06铝合金焊接接头裂纹失效分析EI北大核心CSCD

针对5A06铝合金焊缝附近出现的裂纹进行了分析。5A06铝合金母材、焊缝及热影响区组织分析结果表明,材料成型后的组织不均匀,并且存在夹杂物,晶内和晶界有析出相出现。采用光学显微镜对裂纹的扩展特征进行分析,结果表明,裂纹在材料边缘夹杂物处启裂,以沿晶的特征进行扩展。采用SEM对断口进行微观和宏观分析,断口中存在二次裂纹,断口为脆性断裂。     

镁/铝合金双金属叠层板的拉深性能

镁/铝合金双金属叠层板兼具镁合金与铝合金两种金属材料的优势,可用于生产同时具有良好耐腐蚀性、轻量化及减震性的产品。而钣金件的生产通常都包括拉深成形,因此首先采用DYNAFORM软件模拟镁/铝双金属叠层板的拉深过程,模拟结果表明,镁板与拉深凸模接触时,镁/铝双金属叠层板的拉深性能较好。利用自制的温热拉深模具对不同厚度AZ31镁合金/1060铝合金双金属叠层板在100~270℃温度范围内进行拉深实验,研究板坯厚度、成形温度等因素对镁/铝双金属叠层板拉深性能的影响,并分析拉深后得到的筒形件的壁厚分布。结果表明,拉深过程中的最大拉深力随着叠层板板厚的增加、板坯成形温度的降低而增大;双金属叠层板拉裂的危险区域与单金属板拉深一样出现在凸模圆角处。与镁合金、铝合金单层板拉深相比,镁/铝双金属叠层板拉深使筒形件的凸耳减小。     

Microstructure and properties of Nd:YAG laser welded AZ31B magnesium alloy

Biodegradable magnesium-based alloys are very promising materials for temporary implants. Laser welding is an important joining method in such application. In this study, the as-rolled AZ31B magnesium alloy sheets of 1 mm in thickness were successfully joined by Nd ： YAG laser welding. The microstructure and properties of the welded joint were investigated. The result shows that the welded joint is characterized by a narrow heat-affected zone, finer grains and a large number of precipitates distribute in the matrix in the weld. Microhardness of the weld is significantly improved to 72 HV 0. 05 as compared to 55 HV 0. 05 of the base metal. Tensile strength of butt-welded joint is 180. 24 MPa, which is 76. 8% that of the base metal. The electrochemical corrosion experiment shows that the corrosion resistance of laser welded joint is significantly improved in a 3.5 wt. % NaCl solution.     

高含量B_4C/Al基复合材料磨损行为研究

对质量分数分别为20%、30%和40%的高含量B4C/Al基复合材料的磨损行为进行了研究,分析了颗粒含量、载荷变化以及磨损时间对该复合材料磨损性能的影响,探索了该复合材料磨损过程的微观机制。结果表明:B4C/Al基复合材料的磨擦系数随B4C含量的增加而减小,材料耐磨损性能随B4C硬质颗粒含量的增加而提高;随载荷从30 N增加到70 N,B4C/Al复合材料的磨擦系数先减小再增加,材料磨损速率随载荷增加而增大。随磨损进行,整个磨损过程体现出阶段性的变化,复合材料的摩擦系数先减小再增加,磨损速率先缓慢增大,然后较快增长。高含量B4C/Al基复合材料磨损过程主要表现为犁削磨损和黏着磨损的磨损方式,同时还伴随有氧化磨损机制。     

镁合金表面等离子喷涂+激光重熔Al-Si基纳米Si_3N_4复合涂层

为了改善镁合金表面的性能,将等离子喷涂和激光重熔技术相结合,利用5 kW横流连续CO2激光器,在AZ31B镁合金表面进行了激光重熔Al-Si+1%nano-Si3N4等离子喷涂复合涂层的试验研究。通过扫描电子显微镜、能谱分析仪、X射线衍射仪分析了重熔层的组织、成分分布和重熔前后的物相及结合界面,用显微硬度仪和电化学工作站测试并对比复合涂层重熔前后的硬度和腐蚀性能。结果表明,等离子喷涂层经激光重熔后与镁基体达到了良好的冶金结合,在激光作用下,重熔层析出的金属间化合物AlN、Mg2Si及弥散的铝硅固溶体强化相有效提高了其显微硬度,最高值达到514 HV0.05,是基体的10倍。在析出强化相作用下,重熔层的耐蚀性得到明显提高,自腐蚀电流较喷涂层和镁基体降低一个数量级。     

热输入对超薄443铁素体不锈钢组织性能的影响

针对443铁索体不锈钢焊接接头存在粗晶组织与性能脆化等问题进行研究,采用光学显微镜(OM)、扫描电子显微镜(SEM)分析了不同焊接方法焊后接头组织和性能的变化.采用钨极氩弧焊(TIG)、脉冲钨极氩弧焊(P-TIG)和脉冲激光焊(P-LBW)三种焊接方法进行焊接,分析了不同热输入对超薄443铁素体不锈钢焊接接头微观组织、拉伸性能和杯突性能的影响规律.结果表明,焊接热输入是影响该铁素体不锈钢焊接接头组织和性能的重要因素,采用脉冲焊接方法来细化组织可以有效提高焊接接头综合性能.     

Mechanical and corrosion properties of 445J2 ultra pure ferritic stainless steel joint

The microstructure, mechanical and corrosion resistance properties of 445J2 ultra pure ferritic stainless steel thin plate joints conducted by the pulsed current gas tungsten arc welding (PCGTAW) were discussed in this paper. In order to avoid weld defects, the appropriate welding process was adjusted. The joints were subjected to optical microscopy, transverse static tensile, plastic deformation, intergranular corrosion and electrochemistry corrosion tests. The results indicated that the weld zone (WZ) is characterized with columnar grains and equiaxed grains and the heat-affected zone (HAZ) shows coarse ferrite grains due to the rapid solidification of thin plate welding. The PCGTAW joint exhibited acceptable mechanical properties and equivalent corrosion resistance properties as the base metal.