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Maximum solid solubility (Cmax) of different transition metals in metal solvent can be described by a semi-empirical equation using function Zf that contains electronegativity difference, atomic diameter and electron concentration. The relation between Cmax and these parameters of transition metals in vanadium solvent was studied. It is shown that the relation of Cmax and function Zf can be expressed as In Cmax = Zf = 7. 316 5- 2. 780 5 (△X)^2- 71. 278δ^2-0. 855 56n^2/3. The factor of atomic size parameter has the largest effect on the Cmax of the V binary alloy; followed by the factor of electronegativity difference; the electrons concentration has the smallest effect among the three bond parameters. Function Zf is used for predicting the unknown Cmax of the transition metals in vanadium solvent. The results are compared with Darken-Gurry theorem, which can be deduced by the obtained function Zf in this work. 相似文献
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研究了Al对TiV0.8-xCr1.2Alx(x=0、0.05、0.1、0.15、0.2)合金的结构与贮氢性能的影响.XRD、PCT等测试研究表明:TiV0.8-xCr1.2Alx合金均为单相bcc结构,铸态时主相为树枝状晶组织;随着Al含量由0增加到6.67 at%,合金的晶格常数变大,吸氢量和放氢量减小,氢化物标准生成焓变与生成熵变增大.放氢的平台压随着Al含量的增加而线性增大.TiV0.75Cr1.2Al0.05合金最大吸氢量达3.887%(质量分数),有效吸氢量达2.288%. 相似文献
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