Evidence of Oxygen Ferromagnetism in ZnO Based Materials

Discoveries of room‐temperature ferromagnetism (RTFM) in semiconductors hold great promise in future spintronics technologies. Unfortunately, this ferromagnetism remains poorly understood and the debate concerning the nature, carrier‐mediated versus defect‐mediated, of this ferromagnetism in semiconducting oxides is still open. Here, by using X‐ray absorption (XAS) and X‐ray magnetic circular dichroism (XMCD), it is demonstrated that the oxygen ions have a ferromagnetic response in different ZnO‐based compounds showing RTFM behavior: ZnO nanoparticles capped with organic molecules and ZnO/ZnS heterostructures. These results demonstrate the intrinsic occurrence of RTFM in these systems, and point out that it is not related to the metallic cation but it relays on the conduction band of the semiconductor.     

Reliable M2M/IoT data delivery from FANETs via satellite

The use of unmanned aerial vehicles (UAVs) is rising in several application fields. This work deals with the communication challenges in UAV swarms, or flying ad hoc network (FANET), when taking into account non–line‐of‐sight scenarios. The use of satellites is a necessity in such operating conditions; thus, this work provides architectural considerations and performance assessments when several (FANETs) share an uplink random access satellite channel, fed with M2M/IoT traffic generated from on‐board sensors, to be reliably delivered to a remote ground destination.     

Effect of thermal aging on the interfacial structure of SnAgCu solder joints on Cu

Interfacial structure plays a great role in solder joint reliability. In solder joints on Cu, not only is Kirkendall voiding at the solder/Cu interface a concern, but also the growth of interfacial Cu–Sn intermetallic compounds (IMCs). In this work, evolution of microstructure in the interfacial region was studied after thermal aging at 100–150 °C for up to 1000 h. Special effort was made during sample preparation to reveal details of the interfacial structure. Thickness of the interfacial phases was digitally measured and the activation energy was deduced for the growth of Cu₃Sn. Kirkendall voids formed at the Cu/Cu₃Sn interface as well as within the Cu₃Sn layer. The thickness of Cu₃Sn significantly increased with aging time, but that of Cu₆Sn₅ changed a little. The interfacial Cu₃Sn layer was found growing at the expense of Cu₆Sn₅. Evolution of the interfacial structure during thermal aging is discussed.     

Distance-Based Decision Fusion in a Distributed Wireless Sensor Network

Target classification fusion problem in a distributed, wireless sensor network is investigated. We propose a distance-based decision fusion scheme exploiting the relationship between sensor to target distance, signal to noise ratio and classification rate, which requires less communication while achieving higher region classification rate when compared to conventional majority-vote-based fusion schemes. Several different methods are tested, and very encouraging simulation results using real world experimental data samples are also observed.     

A Software-Optimized Encryption Algorithm

We describe the software-efficient encryption algorithm SEAL 3.0. Computational cost on a modern 32-bit processor is about 4 clock cycles per byte of text. The cipher is a pseudorandom function family: under control of a key (first preprocessed into an internal table) it stretches a 32-bit position index into a long, pseudorandom string. This string can be used as the keystream of a Vernam cipher. Received 3 May 1996 and revised 17 September 1997     

The intelligent envelope: The current state of the art

Solar components integrated in the building envelope can provide an important contribution to the utilisation of renewable energy sources for the climatization of the building indoor space, when these components are designed for optimal efficiency and when they are equipped with an appropriate control of their operating parameters.The aim of the R & D in this field is to modify the characteristics of windows and curtain walls in order to improve the thermal and lightning performances and to develop facade-integrated components, performing active functions of indoor climatization and remote space daylighting. The utilisation of this components, operating under automatic control, reduce the energy consumption in winter, increase the reduction of overheating in summer and operate mechanical ventilation for indoor spaces. The main design objective of researchers and producers is to produce reliable, low cost, high efficient industrialised solar components which can be integrated in a wide range of building typologies. The introduction of automation into the operation of movable elements of the passive solar systems could solve several problems.     

Nanoimprinted,Submicrometric, MOF‐Based 2D Photonic Structures: Toward Easy Selective Vapors Sensing by a Smartphone Camera

In this work, a soft‐lithographic approach to fabricate submicrometer metal organic framework (MOF)‐based 2D photonic structures is described. Nanometric zeolitic imidazole framework material ZIF‐8 (zinc) is chosen as the sensible MOF material because of its chemical stability and its vapor selective adsorption properties. Two different systems are fabricated: nanopatterned colloidal ZIF‐8 homo‐ and ZIF‐8/TiO₂ heterostructures. Several features (stripes, squares, etc.) with dimensions of 200 nm are replicated on different substrates such as silicon, flexible plastics, and even aluminum cans, over relatively large surfaces (up to 1 cm²). In addition, the use of these photonic MOF‐heterostructures as very low‐cost sensing platforms compatible with smartphone technology is demonstrated. This method relies on the evaluation of the change in diffraction efficiency of the photonic MOF‐patterns, induced by the MOF refractive index variation, which is simply detected by a charge coupled device (CCD) camera, as those integrated in smartphones, without need for complex optical instrumentations for transduction data processing. Performances of the sensors are first evaluated using isopropyl alcohol adsorption/desorption cycling as a model case. In addition, a “real” environmental issue is tackled. Selective detection of styrene in presence of interfering water is demonstrated at concentrations below the human permissible exposure limit. In situ ellispometric analyses are also carried out in order to confirm the sensor performances and to propose a mechanism for styrene uptake into the nanoMOFs.     

Mobile ad hoc networking: imperatives and challenges

Mobile ad hoc networks (MANETs) represent complex distributed systems that comprise wireless mobile nodes that can freely and dynamically self-organize into arbitrary and temporary, “ad-hoc” network topologies, allowing people and devices to seamlessly internetwork in areas with no pre-existing communication infrastructure, e.g., disaster recovery environments. Ad hoc networking concept is not a new one, having been around in various forms for over 20 years. Traditionally, tactical networks have been the only communication networking application that followed the ad hoc paradigm. Recently, the introduction of new technologies such as the Bluetooth, IEEE 802.11 and Hyperlan are helping enable eventual commercial MANET deployments outside the military domain. These recent evolutions have been generating a renewed and growing interest in the research and development of MANET. This paper attempts to provide a comprehensive overview of this dynamic field. It first explains the important role that mobile ad hoc networks play in the evolution of future wireless technologies. Then, it reviews the latest research activities in these areas, including a summary of MANET’s characteristics, capabilities, applications, and design constraints. The paper concludes by presenting a set of challenges and problems requiring further research in the future.     

Molecular Heterojunctions of Oligo(phenylene ethynylene)s with Linear to Cruciform Framework

Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO–LUMO energy gaps. OPE3, OPE3–DTF, and OPE3–tetrathiafulvalene (TTF) can form good self‐assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe–atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3–TTF > OPE3–DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero‐bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.