Prediction of dye concentrations in a three‐component dye mixture solution by a PCA‐derivative spectrophotometry technique

Derivative spectrophotometry is one of the most important techniques that can be used to determine the dye concentration. In addition, principal component analysis (PCA) is a linear method to condense the dimensionality of large numbers of absorbance spectra. In this work, PCA and derivative spectrophotometry techniques are used to improve the accuracy of Beer's law prediction of the concentrations in three‐component dye mixtures. The performance of the new method is compared with the normal Beer's law by calculation absolute error, relative error, and ternary relative error of prediction. As obtained results indicate, the prediction accuracy of dye concentration prediction in PCA‐derivative spectrophotometry method is higher than normal Beer's law method. © 2009 Wiley Periodicals, Inc., Col Res Appl, 2010.     

Vibration reduction on city buses: Determination of optimal position of engine mounts

This study is composed of three essential parts. The first part describes an indirect semi-experimental method which is used to reconstruct the excitation force of an operating diesel engine from the acceleration data measured at the mounting points. These internal forces can not be directly measured with force sensors; they have to be derived from the dynamic deformation of the engine support, so a theoretical analysis is carried out to derive the equations for the force re-construction.The second part deals with prevention of low frequency vibration of the powertrain from spreading to the rest of the vehicle. Three uncoupling techniques are used to minimize these vibrations. The first technique reduces the non-diagonal elements of stiffness matrix. The second technique uses the elastic axes decoupling criterion. The third technique uncouple the torque roll axis (TRA) by using the previously determined excitation efforts.In the third part, numerical and experimental results are discussed. The solicitations deducted and the positions of mounts allowing decoupling of the powertrain are presented.     

Online monitoring of diallyldimethylammonium chloride polymerization

Diallyldimethylammonium chloride, which is an acidic salt with numerous applications, was polymerized in water at three different monomer concentrations and at three different pHs which the monomer is in charged form. Reactions were investigated by the automatic continuous online monitoring of polymerization technique. Conversion, molecular weight, and reduced viscosity were monitored. The reaction is found to be second‐order with respect to monomer. Rate constants and molecular weights tend to increase with pH and concentration. POLYM. ENG. SCI., 54:1350–1356, 2014. © 2013 Society of Plastics Engineers     

Practical evaluation of relationship between concrete resistivity,water penetration,rapid chloride penetration and compressive strength

There are several factors and test methods for evaluating the durability of concrete. In recent years a great deal of attention has been paid to research and development of relationships of these parameters for production of sustainable concretes: water penetration and Rapid Chloride Penetration Test (RCPT) methods which are most commonly used to evaluate the permeability of concrete are two of the most famous methods specified by BS EN-12390-8:2000 and ASTM C1202 respectively. Concrete surface resistivity (SR) test is also a suitable indicator for concrete penetration and chloride ion permeability. It is a non-destructive, simple, rapid and economical method that can also be used on site.The present study is an exploratory research concerned with the relationship of these methods. Based on the correlation of concrete resistivity with water penetration and Rapid Chloride Penetration Test (RCPT) results, two new models for relating these parameters are presented.     

Fatty acid composition and sensory properties of Wels catfish (Silurus glanis) hot smoked with different sawdust materials

This study aims to compare chemical, physical and sensorial parameters of the Wels catfish (Silurus glanis), hot smoked using vine, poplar, lemon tree and oak sawdust as well as corncob. Significant differences (P < 0.05) in proximate composition were found between fresh and smoked samples; however, the changes in fatty acid composition were less significant. In the fatty acid composition of control group, monounsaturated fatty acids (41.60%) had the highest share in fatty acids, which was followed by saturated fatty acids (29.95%) and polyunsaturated fatty acids (28.34%). The major fatty acids were observed to be C16:0, C18:0; C16:1 n‐7, C18:1 n‐9c, C18:1 n‐9t and C18:2 n6c. There were significant differences (P < 0.05) between the groups considering their colour measurement results. General preference criteria such as appearance, odour, texture, colour and taste were chosen for the sensorial analysis, which were rated by the panellists. According to the results of overall appearance, the fillet pieces smoked with lemon tree (9.00), poplar (8.66), corncob (8.00), oak (7.33) and vine (5.33) sawdust were determined as the most preferred, in order.     

Development of a new analytical tool to design hierarchical truss beams for natural frequency

A set of recursive equations are introduced for optimum design of a wide range of hierarchical truss beams to satisfy a minimum required natural frequency. The design equations are based on a general analytical solution, which are derived based on a critical dimensional analysis. A practical example is examined in both 2D and 3D spaces, which promises substantial mass reduction, as much as 99%, when using high order hierarchical truss beams. The results are verified by numerical evaluation of three case studies. The approach looks also very promising to design nanostructures when it comes to the problems associated with vibration.     

Fast Separation of Capsaicinoids from Peppers by Reversed Phase Ultra-Performance Liquid Chromatography: Comparation with Traditional High-Performance Liquid Chromatography Methods

A new chromatographic method for the separation of major capsaicinoids in peppers has been developed. Nordihydrocapsaicin, capsaicin, dihydrocapsaicin, homocapsaicin, and homodihydrocapsaicin have been separated by reversed-phase ultra-performance liquid chromatography. A gradient method has been developed using two solvents: 0.1% acetic acid in water and 0.1% acetic acid in methanol. The developed method allows the full separation of capsaicinoids in less than 3 min, with high reproducibility (relative standard deviation < 4.3%) and repeatability (relative standard deviation < 3.6%). Robustness regarding the total amount of methanol in the sample was determined. Comparison with previous reversed-phase high-performance liquid chromatography methods using both monolithic and conventional columns was also studied. Finally, the method was applied in the determination of major capsaicinoids in 16 hot pepper samples produced in Spain.     

Preparation of silver nanostructure from silver(I) coordination polymer and fabrication of nano silver(I) bromide by reverse micelles technique

A new one-dimensional silver(I) coordination polymer, [Ag(μ-bpfb)(NO₃)]_n (1); bpfb = N,N′-bis(4-pyridylformamide)-1,4-benzene, has been synthesized and characterized by IR, ¹H NMR and ¹³C NMR spectroscopy. The single crystal X-ray data show that the silver(I) 1D coordination polymer grows into a three-dimensional network by hydrogen bonding and π–π stacking interactions. Compound 1 with nanorod morphology was also prepared by sonochemical method. The cetyltrimethylammonium bromide (CTAB) as a cationic surfactant was used in reverse micelles technique to obtain spongy silver(I) bromide nanoparticles from compound 1. Also, different silver nanoparticles have been prepared via direct calcination at 673 K and thermal decomposition in oleic acid from compound 1. The nanostructures of [Ag(μ-bpfb)(NO₃)]_n (1), silver and silver(I) bromide were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDAX) analysis. Thermal stability of compound 1 in both bulk and nano-sized form was studied by thermal gravimetric (TG) and differential thermal (DT) analyses.