Synthesis of onion-like mesoporous silica from sodium silicate in the presence of α,ω-diamine surfactant

Mesoporous silicas with vesicular and onion-like morphologies were assembled through hydrogen-bonding pathway from sodium silicate as silica source and electrically neutral α,ω-diamine, Jeffamine D2000 surfactant (H₂NCH(CH₃)CH₂[OCH₂CH(CH₃)]₃₃NH₂) as template in aqueous media at different synthesis temperatures (25, 60 and 100 °C). Assembling the material at 100 °C afforded onion-like core shell mesoporous silica, while at relatively lower temperature, e.g. 25 and 60 °C, multilamellar vesicles were obtained. Mesoporous silica with onion-like morphology was also obtained by a two-step synthesis involving an aging period of 20 h at room temperature followed by a hydrothermal stage (1–12 h) at 100 °C. The heavily cross-linked (Q⁴/Q³ ratio of 4.43) onion-like mesophase silica exhibited high hydrothermal stability. The BET surface area, pore volume and KJS (Kruk-Jaroniec-Sayari) pore diameter of the onion-like mesoporous silica were found to be 464 m² g⁻¹, 1.16 m³ g⁻¹ and 7.2 nm, respectively.     

Sol–Gel Assisted Preparation of Chromia–Silica Catalysts for Non-Oxidative Dehydrogenation of Propane

Preparation of continuous silica gel in the presence of dissolved Cr(NO₃)₃ leads to a hard high surface area (710 m²/g) microporous xerogel. Formation of the gel in the pore structure of mesoporous Pore-Expanded MCM-41 (PE-MCM-41) and macroporous commercial Cab–O–Sil silica results in retention of the mesoporous structure in the case of PE-MCM-41, and the formation of a powder with a broad pore size distribution in the case of Cab–O–Sil silica. Comparison of the catalytic activities in non-oxidative dehydrogenation of propane revealed a linear correlation of the initial conversion with the surface area for all three samples. The sample prepared from PE-MCM-41 through a sol–gel assisted procedure was the most active, particularly with respect to the catalysts prepared by simple wet impregnation with chromium nitrate.     

H2 sensors based on WO3 thin films activated by platinum nanoparticles synthesized by electroless process

Platinum (Pt) nanoparticles were successfully synthesized on tungsten oxide (WO₃) thin films by electroless process without any further post-treatment. The prepared Pt nanoparticles were characterized by X-ray diffraction, X-ray photoelectron spectroscopy and field-emission scanning electron microscopy. Gas sensors based on the Pt–WO₃ films were found to provide repeatable and significant responses to ppm-level H₂. The size of Pt nanoparticles increases with the deposition time and has improved the sensing characteristics of the sensors. The work in this paper paves a facile way to the fabrication of Pt nanoparticles on metal oxide surface at a low temperature (68 °C).     

MQBV: multicast quality of service swarm bee routing for vehicular ad hoc networks

Vehicular ad hoc networks (VANETs) are witnessing in recent years a rapid development for road transmissions and are considered as one of the most important types of next generation networks, in which drivers can have access anywhere and anytime to information. However, vehicles have to deal with many challenges such as the links failures due to their frequent mobility as well as limited degrees of freedom in their mobility patterns. In this paper, we propose a new quality of service multicast and multipath routing protocol for VANETs, based on the paradigm of bee's communication, called multicast quality of service swarm bee routing for VANETs (MQBV). The MQBV finds and maintains robust routes between the source node and all multicast group members. Therefore, the average end‐to‐end delay and the normalized overhead load should be reduced, while at the same time increasing the average bandwidth and the packet delivery ratio. Extensive simulation results were obtained using ns‐2 simulator in a realistic VANET settings and demonstrated the efficiency of the proposed protocol. Copyright © 2013 John Wiley & Sons, Ltd.     

Classification of Static and Dynamic Behavior in Chemostat for Plasmid-Bearing,Plasmid-Free Mixed Recombinant Cultures

The singularity theory is combined with continuation techniques to classify the static and dynamic behavior in a chemostat involving the competition between plasmid-bearing and plasmid-free cell populations. The analysis of the static bifurcation allows the derivation of analytical conditions for the coexistence of the competing populations and for the safe operation of the’bioreactor. The analysis of dynamic bifurcation, on the other hand, shows the ability of the model to predict the coexistence of the two populations in a state of stable limit cycle. Analytical conditions with respect to any growth kinetics are derived for the occurrence of Hopf points in the model. The combination of results of both static and dynamic bifurcation helps to construct a useful picture, in the multidimensional parameter space, of the different behavior predicted by the model.     

Blast furnace slags as functional fillers on rheological,thermal, and mechanical behavior of thermoplastics

Blast furnace slags (BFS) is a secondary byproduct of iron industry, which has a combination of acidic and basic oxides and show a complex, multiphase structure. If appropriately tailored, BFS could be an effective functional filler, improving the property profile of thermoplastics such as polypropylene (PP) and polystyrene (PS). As a raw material, the proposed filler may introduce both economic and ecological advantages, as it is considered an inexpensive secondary product rather than a natural resource. The current study aims at investigating the effect of incorporating BFS as a micro‐sized filler on the rheological, thermal, and mechanical behavior of PP and PS. BFS types in this study are air‐cooled, crystalline, and amorphous, grounded types. Both types are ground into 71, 40, and 20 μm batches and introduced in 10, 20, and 30 weight fractions via melt kneading. Mixtures are then formed into 4‐mm and 2‐mm thick plates via compression molding. Slight increase in rheological factors is observed with increasing filler loading. BFS hinders the crystallization of PP, resulting in slight increase of crystallization temperatures (T_c) and lowering of crystallization enthalpy (ΔH_c). No significant effect of filler on transition temperatures (T_g) is reported. Mechanically, BFS increases the tensile modulus of PP, but decreases its strength. For PS formulations, a modest toughening effect is observed by slag filler. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43021.     

Synthesis and Characterization of Some Nonionic Bolaamphiphiles

A series of nonionic bolaamphiphiles were synthesized from the reaction of fluoroalkylene (dimercaptoacetates) with maleate crown ethers. Surface activity of the new surfactants was evaluated on the basis of surface tension measurements. The new fluorinated bolamphiphiles exhibit a remarkable lowering of surface tension in comparison with nonfluorinated analogues.     

Advances in Control Technologies for Wastewater Treatment Processes:Status,Challenges, and Perspectives

This paper presents a thorough review of control technologies that have been applied to wastewater treatment processes in the environmental engineering regime in the past four decades. It aims to provide a comprehensive technological review for both water engineering professionals and control specialists, giving rise to a suite of up-to-date pathways to impact this field in light of the classified technology hubs. The assessment was conducted with respect to linear control, linearizing control, nonlinear control, and artificial intelligence-based control. The application domain of each technology hub was summarized into a set of comparative tables for a holistic assessment. Challenges and perspectives were offered to these field engineers to help orient their future endeavor.      

On consensus algorithms design for double integrator dynamics

This paper considers the consensus problem of double integrator multi-agent systems where: (i) each agent is subject to input saturations, and (ii) the velocity (second state) of each agent is not available for feedback. We present new consensus algorithms that handle simultaneously the above mentioned situations. Sufficient conditions are derived such that consensus algorithms developed for first- and second-order multi-agent systems in ideal situations can be used to account for input saturations and remove the requirement of velocity measurements. To illustrate the effectiveness of the proposed approach, we propose solutions to two different second-order consensus problems in the case where the input is saturated and the velocity states are not available for feedback and simulation results are provided in each case.