Regional Flood Frequency Analysis in Tunisia: Identification of Regional Distributions

Best-fit distributions of floods in Tunisia are determined based on L-moment diagram and statistical tests. GEV and GLO distributions provided the best fit to seven and three regions of Tunisia respectively. In each homogeneous region, hierarchical approaches and regression models were developed for gauged and ungauged watersheds. The first two parameters of the distributions (GEV and GLO) were estimated from measured data while the third parameter was represented by the regional average value weighted by the record length of all stations in the region. The obtained parameters were correlated to the catchment size. Quantiles obtained by the proposed models were compared with those obtained using local conventional models. Statistical tests showed that the proposed models provided a much better agreement with observed floods than any of the conventional methods generally used in Tunisia.     

An infobutton for Web 2.0 clinical discussions: the knowledge linkage framework

This paper aims to develop an infobutton to automatically retrieve published papers corresponding to a topic-specific online clinical discussion. The knowledge linkages infobutton is designed to supplement online clinical conversations with pertinent medical literature from Pubmed. The project involves three distinct steps: 1) Clinical messages around a specific problem are grouped together into a thread. 2) These threads are processed using Metamap to link the conversations to keywords from the MeSH lexicon. 3) These keywords are used in a novel search strategy to retrieve a set of papers from Pubmed, which are then returned to the user. A pilot study using the messages from 2007 and 2008, was conducted to compare the knowledge linkage search strategy to a vector space model and extended Boolean model. The knowledge linkage model proved to be significantly better in terms of precision ( p = 0.013 and 0.003, respectively) and recall ( p = 0.351 and 0.013). Pertinent papers were returned to over 55% of the threads. This approach has demonstrated how clinicians can supplement their peer communications with evidence based research. Future work should focus on how to improve the threading and keyword-mapping strategies.     

Autonomous terrain-following for unmanned air vehicles

This paper presents an integrated guidance and control design scheme for an unmanned air vehicle (UAV), and its flight test results. The paper focuses on the longitudinal control and guidance aspects, with particular emphasis on the terrain-following problem. An introduction to the mission, and the terrain-following problem is given first. Waypoints for climb and descent are defined. Computation of the reference trajectory in the vertical plane is discussed, including a terrain-following (TF) algorithm for real-time calculation of climb/descent points and altitudes. The algorithm is particularly suited for online computation and is therefore useful for autonomous flight. The algorithm computes the height at which the vehicle should fly so that a specified clearance from the underlying terrain is always maintained, while ensuring that the vehicle’s rate of climb and rate of descent constraints are not violated. The output of the terrain-following algorithm is used to construct a smooth reference trajectory for the vehicle to track. The design of a robust controller for altitude tracking and stability augmentation of the vehicle is then presented. The controller uses elevators for pitch control in the inner loop, while the reference pitch commands are generated by the outer altitude control loop. The controller tracks the reference trajectory computed by the terrain-following algorithm. The design of an electromechanical actuator for actuating the control surfaces of the vehicle during flight is also discussed. The entire guidance and control scheme is implemented on an actual experimental vehicle and flight test results are presented and discussed.     

Spectroscopic studies of sol–gel grown CdS nanocrystalline thin films for optoelectronic devices

CdS is one of the highly photosensitive candidate of II–VI group semiconductor material. Therefore CdS has variety of applications in optoelectronic devices. In this paper, we have fabricated CdS nanocrystalline thin film on ultrasonically cleaned glass substrates using the sol–gel spin coating method. The structural and surface morphologies of the CdS thin film were investigated by X-ray Diffraction (XRD) and Field Emission Scanning Electron Microscopy (FESEM) respectively. The surface morphology of thin films showed that the well covered substrate is without cracks, voids and hole. The round shape particle has been observed in SEM micrographs. The particles sizes of CdS nanocrystals from SEM were estimated to be～10–12 nm. Spectroscopic properties of thin films were investigated using the UV–vis spectroscopy, Photoluminescence and Raman spectroscopy. The optical band gap of the CdS thin film was estimated by UV–vis spectroscopy. The average transmittance of CdS thin film in the visible region of solar spectrum found to be～85%. Optical band gap of CdS thin film was calculated from transmittance spectrum ～2.71 eV which is higher than bulk CdS (2.40 eV) material. This confirms the blue shifting in band edge of CdS nanocrystalline thin films. PL spectrum of thin films showed that the fundamental band edge emission peak centred at 459 nm also recall as green band emission.     

Reinforcement effect of nanodiamond on properties of epoxy matrix

Epoxy/nanocrystalline diamond nanocomposites composites were prepared by dispersing ultrasonically, 0.4, 0.7, 1.0, and 4.0 wt% acid‐treated nanocrystalline diamond (NCD) powder in epoxy matrix. Fourier infrared spectroscopy was utilized to study the moieties attached to the nanodiamond particles. The trace elements present in NCD powder before and after acid treatment were analyzed by ion beam techniques. Thermomechanical properties of the nanocomposites showed that incorporation of low content (0.4 wt%) of nanodiamond powder into epoxy matrix enhanced the storage modulus, loss modulus, and hardness by ∼68, ∼55, and ∼86%, respectively, over neat epoxy. By increasing the concentration of modified NCD to 0.7 wt% resulted in lower values of hardness and thermomechanical properties but still remain higher than neat epoxy. An increasing trend in properties was again observed at 4 wt% concentration of modified nanofiller. The glass transition temperature was up shifted to ∼110°C over neat epoxy. The mechanisms responsible for enhanced properties of epoxy matrix are also discussed in detail. POLYM. COMPOS., 34:811–818, 2013. © 2013 Society of Plastics Engineers     

Pollen morphological investigations of family Cactaceae and its taxonomic implication by light microscopy and scanning electron microscopy

The family Cactaceae is the diversified group of angiosperm plants whose pollen statistics has been used for taxonomic identification. In this article, we present the pollen morphology of eight species belong to seven taxonomically complex genera of Cactaceae including Astrophytum, Cylindropuntia, Echinocereus, Echinopsis, Mammillaria, Opuntia, and Thelocactus using light and scanning electron microscopy. The pollen grains were acetolyzed, measured, described, and electron photomicrographs were taken. Cactaceae can be characterized by presenting different palynomorphological features including pollen type, sculpturing, polar and equatorial diameter, aperture orientation, exine thickness, P/E ratio, and echini features. Four types of pollen shapes, that is, prolate spheroidal (three species), subprolate (two species), prolate (two species), and oblate spheroidal in Echinocereus reichenbachii were observed. The polar and equatorial diameter observed maximum in O. ficus indica 116.95 and 112.27 μm while minimum in M. compressa 38.42 and 21.05 μm. Pollen of two types, tricolpate in members of subfamily Cactioideae and pantoporate in the Opuntioideae were examined. The fertility percentage has been observed maximum in Opuntia macrocentra (83.84%) and minimum in Opuntia ficus‐indica (57.89%). Exine sculpturing showing great variations such as granulate, reticulate, granulate perforate and micro‐echinate foveolate ornamentation was examined only in Echinopsis eyriesii. A key to species, based on pollen micromorphological attributes, has been constructed for correct identification of complex cactus species.     

Throughput-efficient coalition formation of selfish/altruistic nodes in ad hoc networks: a hedonic game approach

In this paper, we analyze the problem of throughput-efficient distributed coalition formation (CF) of selfish/altruistic nodes in ad hoc radio networks. We formulate the problem as a hedonic CF game with non-transferable utility and propose different preference relations (CF rules) based on individual/group rate improvement of distributed nodes. We develop a hedonic CF algorithm, through which distributed nodes may self-organize into stable throughput-efficient disjoint coalitions. We apply the concept of frequency reuse over different coalitions, such that the members of each coalition will transmit over orthogonal sub-bands with the available spectrum being optimally allocated among them. We study the computational complexity and convergence properties of the proposed hedonic CF algorithm under selfish and altruistic preferences, and present means to guarantee Nash-stability. In addition, we identify the scenarios in which a CF process might lead to instability (CF cycle), and we propose methods to avoid cycles and define different exit procedures if a CF cycle is inevitable. Performance analysis shows that the proposed algorithm with optimal bandwidth allocation provides a substantial gain, in terms of average payoff per link, over existing coalition formation algorithms for a wide SNR range.     

Gas Sensing of NiO‐SCCNT Core–Shell Heterostructures: Optimization by Radial Modulation of the Hole‐Accumulation Layer

Hierarchical core–shell (C–S) heterostructures composed of a NiO shell deposited onto stacked‐cup carbon nanotubes (SCCNTs) are synthesized by atomic layer deposition (ALD). A film of NiO particles (0.80–21.8 nm in thickness) is uniformly deposited onto the inner and outer walls of the SCCNTs. The electrical resistance of the samples is found to increase of many orders of magnitude with the increasing of the NiO thickness. The response of NiO–SCCNT sensors toward low concentrations of acetone and ethanol at 200 °C is studied. The sensing mechanism is based on the modulation of the hole‐accumulation region in the NiO shell layer upon chemisorption of the reducing gas molecules. The electrical conduction mechanism is further studied by the incorporation of an Al₂O₃ dielectric layer at NiO and SCCNT interfaces. The investigations on NiO–Al₂O₃–SCCNT, Al₂O₃–SCCNT, and NiO–SCCNT coaxial heterostructures reveal that the sensing mechanism is strictly related to the NiO shell layer. The remarkable performance of the NiO–SCCNT sensors toward acetone and ethanol benefits from the conformal coating by ALD, large surface area of the SCCNTs, and the optimized p‐NiO shell layer thickness followed by the radial modulation of the space‐charge region.     

Review of carbon dioxide (CO2) based heating and cooling technologies: Past,present, and future outlook

Refrigerants bearing high global warming potential (GWP) and ozone depletion potential (ODP) were outlawed or facing time-beared permission under the Montreal (1987), Kyoto (1997) protocols, F-Gas law (2015), Paris Accord (2016), and recent Kigali Amendment to Montreal Protocol (2019). In order to modify followed by the paradigm shift of existing heating and cooling systems, American Society of Heating, Refrigeration, and Air-Conditioning Engineers (ASHRAE) envisaged natural and synthetic refrigerants (Synrefs) are under investigation globally. Carbon dioxide (CO₂) is a popular natural refrigerant (Natref) replacing Synrefs used in commercial heating, ventilation, air conditioning, and refrigeration (HVAC&R) systems globally. A rampant rise is observed in markets of Asia (Japan and China), North America (the United States and Canada), the Australian continent, and Africa (South Africa) by reaching 20 000 CO₂-stores around the globe. The European markets are leading the utilization of CO₂ in the heat pump, and refrigeration, CO₂ based markets estimate 14% of the total food retail stores (400 m²). Japan is the second leading market of CO₂ heat pump and refrigeration with more than 10 200 CO₂ condensing units. CO₂ transcritical systems have a share of more than 10% in only European market (large stores); however, their share is less than 10% of total stores in other major markets of the world. New pump and compressor-driven transcritical CO₂ systems integrate ejectors, condensers, and booster systems to reduce energy consumptions, enhance efficiency, efficacy, and coefficient of performance. This article reports a critical review of the CO₂ based heating, cooling, and refrigeration system and presents updated literature along with barriers and challenges on commercial use of Natref-based heating and cooling applications worldwide.     

Synthesis and EMI shielding studies of polyaniline grafted conducting nanohybrid

Polyaniline (PANI) grafted conducting nanohybrids are successfully synthesized by emulsion graft polymerization. Maximum grafting of 644% is obtained on sepiolite at optimized concentrations and reaction conditions. The Fourier transform infrared (FT-IR) spectra of sepiolite grafted polyaniline (MS-g-PANI) nanohybrid revealed the presence of stretching vibrations of C=C bonds of polyaniline at 1580 and 1490 cm⁻¹ along with the characteristic peaks of sepiolite. Increased thermal stability of the nanohybrid is observed with the increase in polyaniline grafting. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) are used to study the structural changes caused by grafting. A progressive increase in electrical conductivity is observed with the increase in grafting yield. Maximum electrical conductivity of 0.427 Scm⁻¹ is observed in the nanohybrid having 644% grafting. 24.2 dB (>99% attenuation) EMI shielding effectiveness has been exhibited by the developed nanohybrids in X-band frequency range.