New observations in micro-pop-in issues in nanoindentation of coarse grain alumina

The present experiments were focused on nanoindentation behaviour and the attendant “micro-pop-in” in a dense (～95% of theoretical) coarse-grain (～20 μm) alumina ceramic as a function of loading rate variations at three constant peak loads in the range of 10⁵–10⁶ μN. Based on the experimental results here we report for the first time, to the best of our knowledge, an increase in intrinsic nano scale contact resistance as well as the nanohardness with the loading rate. These observations were explained in terms of the correlation between the nanoscale plasticity and shear stress active just underneath the nanoindenter.     

Zincated Nanoclay Polymer Composites (ZNCPCs): Synthesis,Characterization, Biodegradation and Controlled Release Behaviour in Soil

Novel zincated nanoclay polymer composites (ZNCPCs) with variable percentage of commercial bentonite and nanobentonite (8%, 10% and 12% of monomer for each case) were synthesized. Polyacrylic acid-Polyacrylamide copolymer was synthesized using N, N-Methylene bisacrylamide as crosslinker and ammonium persulfate as initiator. Clays as well as ZNCPCs were characterized by XRD, SEM, TEM and FTIR. 12% nanoclay containing formulation showed slowest release rate. ZNCPCs containing 8% clay recorded highest Zn content as well as highest equilibrium water absorbency. Biodegradation study revealed that Aspergillus spp was more effective as compared with Trichoderma spp in degradation of ZNCPCs.     

Exact Lithologic Boundary Detection Based on Wavelet Transform Analysis and Real-Time Investigation of Facies Discontinuities Using Drilling Data

Abstract

Exact detection of lithologic boundaries is one of the main challenges in exploration, drilling operations, and geology. Investigation of facies discontinuities has been performed using petrophysical data regarding sharp changes along the wellbore. Due to the fact that recorded well logging signals contain lots of high-frequency waves (noise), detection of the layer boundaries comes with some uncertainties that should be eliminated by denoising those signals. Wavelet transform analysis is a good approach to denoise the signals and its ability has been proven in several studies. In this study, implementation of wavelet transform analysis resulted in an innovative approach for exact differentiation of neighborhood lithologic units.

Detection of boundaries between different layers, especially the ones in the vicinity of the reservoir during drilling operations, is one of the crucial issues in petroleum well engineering. This purpose is usually achieved by cutting analysis and geological maps, which are not accurate enough and may cause substantial problems. Unconfined rock compressive strength can be considered as an accurate criterion to detect geological boundaries. In this study, an artificial neural network (ANN) model is developed that can predict the unconfined rock compressive strength of formations being drilled by importing 10 drilling parameters as inputs. Because rock strength will experience sudden changes while entering the next layer, it can be used as a key parameter to determine boundaries.     

Effect of input variability on the quality of laser shock processing

Laser shock processing (LSP) involves high-energy laser radiation combined with suitable overlays to generate high-pressure pulses on the surface of the metal. The stress wave generated due to high pressure pulses propagates into the material causing the surface layer to yield and plastically deform, and thereby, develop a significant residual compressive stress in the surface region of the substrate material. The developed compressive stress field is beneficial to improve surface properties such as fatigue, wear, and corrosion. To improve the understanding of the shock hardening process, investigation into the physical processes involved is necessary. In the first part of this paper, the temporal variation in the pressure intensity and spot size is calculated by using a two-dimensional recoil pressure prediction model. Using an explicit non-linear FEA code, ANSYS LS-DYNA, the deformation behavior and residual stresses in the substrate material are predicted. In the second part, a probabilistic approach to the modeling and analysis of LSP is presented in this paper. Various factors that affect the probabilistic performance of the LSP are grouped into categories and a select number of factors known to be significant, for which the variability could be assessed, are modeled as random variables (such as recoil pressure, laser beam spot size, substrate material properties and others). The potential of the probabilistic approach in predicting the structural integrity of the laser-shocked components is addressed.     

Exploring the role of the spacers and acceptors on the triphenylamine-based dyes for dye-sensitized solar cells

Six triphenylamine-based dyes were explored for their application in dye-sensitized solar cells (DSSCs). Dyes 1–3 and dyes 4–6 possess cyanoacrylic acid (C-acceptor) and rhodanine-3-acetic acid (R-acceptor), respectively. Stilbene (in dyes 2 and 5) and bis(styryl)benzene (in dyes 3 and 6) were used as π-spacers. There is no π-spacer in the dye 1 and 4. To elucidate the role of π-spacers, optical, electrochemical, and photovoltaic properties of the dyes were studied. Among C-acceptor dyes, dye 2 exhibits the highest light-to-electricity conversion efficiency of 4.45%, followed by dye 3 (4.16%). Similarly, among R-acceptor dyes, dye 5 is the best. These results indicate that stilbene is a better π-spacer over bis(styryl)benzene. Although bis(styryl)benzene could extend the light absorption range (in dye-adsorbed TiO₂ film), its tendency to promote intermolecular π-π stacking is possibly the reason for its poor performance in DSSCs. Furthermore, the conjugation break in the R-acceptor moiety attached to the TiO₂ surface limits the electron injection of R-acceptor dyes poorer than C-acceptor dyes. Density functional theory calculations were performed for the dye-(TiO₂)₈ cluster, assuming a bidentate chelation of a carboxylic acid group with Ti⁴⁺ of TiO₂ anatase. The natural bond orbital (NBO) analysis indicated relatively more electron-accepting ability of cyanoacrylic acid over rhodanine-3-acetic acid.     

A Three-Phase AC-to-DC Power Transistor Converter-Controlled DC Motor Drive

A three-phase ac-to-dc power transistor converter that is suitable for speed control of a dc motor and for a variable dc power supply is investigated. The availability of power transistors of fairly high power rating has made the task of ac-to-dc conversion relatively easy due to simplification of the converter circuit configuration. The external performance characteristics of the power transistor converter-controlled separately excited dc motor are obtained by employing the equal pulsewidth modulation (EPWM) control technique with 18 pulses per half-cycle of the supply voltage and are verified experimentally. There is good agreement between experimental and theoretical results. The external performance is also evaluated under constant torque operation. The use of inductance-capacitance (LC) filters for reducing the effect of predominant supply harmonics is briefly discussed. Experimental oscillograms of some typical waveforms are illustrated to verify the basic principles of operation.     

Simulation, modeling, and crystal growth of Cd0.9Zn0.1Te for nuclear spectrometers

High-quality, large (10 cm long and 2.5 cm diameter), nuclear spectrometer grade Cd_0.9Zn_0.1Te (CZT) single crystals have been grown by a controlled vertical Bridgman technique using in-house zone refined precursor materials (Cd, Zn, and Te). A state-of-the-art computer model, multizone adaptive scheme for transport and phase-change processes (MASTRAP), is used to model heat and mass transfer in the Bridgman growth system and to predict the stress distribution in the as-grown CZT crystal and optimize the thermal profile. The model accounts for heat transfer in the multiphase system, convection in the melt, and interface dynamics. The grown semi-insulating (SI) CZT crystals have demonstrated promising results for high-resolution room-temperature radiation detectors due to their high dark resistivity (ρ≈2.8 × 10¹¹ Θ cm), good charge-transport properties [electron and hole mobility-life-time product, μτ_e≈(2–5)×10⁻³ and μτ_h≈(3–5)×10⁻⁵ respectively, and low cost of production. Spectroscopic ellipsometry and optical transmission measurements were carried out on the grown CZT crystals using two-modulator generalized ellipsometry (2-MGE). The refractive index n and extinction coefficient k were determined by mathematically eliminating the ∼3-nm surface roughness layer. Nuclear detection measurements on the single-element CZT detectors with ²⁴¹Am and ¹³⁷Cs clearly detected 59.6 and 662 keV energies with energy resolution (FWHM) of 2.4 keV (4.0%) and 9.2 keV (1.4%), respectively.     

Immittance response of CaSnO3 prepared by self-heat-sustained reaction

The potential of CaSnO3 for application as a capacitor component possessing a small temperature coefficient of capacitance has been examined by ac small-signal measurements at elevated temperatures (25–300°C) in the frequency range 5–13 MHz. The samples were synthesized by a novel technique called self-heat-sustained (SHS) reaction. The ac data were acquired for the CaSnO3 samples sintered at various temperatures with varying soak temperatures, T, and some times, t (1200°C T 1600°C 2 h t 48 h). An analysis of the electrical data in more than one complex-plane formalism indicated relaxation processes. The resistance of these sintered samples was dominated by the grain boundaries, and the capacitance exhibited near-linear behavior at elevated temperature for several decades of measurement frequency. The electrical behavior has been correlated with the evolved microstructure in these samples in conjunction with the results obtained in a previous study for solid-state reaction (SSR) derived sintered bodies. The multi-plane analytical criteria provided a meaning for the lumped equivalent circuit representation including the origin and purpose of the contributing elements extracted from each complex plane formalism.     

Effect of environmental pollutants on the C-reactive protein of a freshwater major carp, Catla catla

C-reactive proteins (CRP) have been affinity purified to electrophoretic homogeneity from the sera of major carp, Catla catla before and after exposure to environmental pollutants. Exposure to these pollutants elevate the levels of circulating CRPs to 2.8-3.5 times the normal values. Kinetic studies of metal intoxication indicate that a unique molecular variant of CRP is present in the serum at the peak level of acute phase induction, and this variant coexists with normal CRPs. Carbohydrate analysis and lectin binding reveals that these CRPs are glycoproteins differing significantly in total carbohydrate contents. Their electrophoretic mobilities in native gel are different but become identical on desialylation and deglycosylation implying that the molecular variants vary in the glycan parts. All these forms of CRP contain two nonidentical subunits of Mr 22 and 29 kDa. Examination of their immunological crossreactivity demonstrate their similarity in overall molecular topology but their differences in the quantitative extent of binding are reflected.