‘Green’ synthesis and optical properties of silver–chitosan complexes and nanocomposites

Silver nanoparticles were synthesized in a chitosan biopolymer by an in situ ‘green’ chemical procedure, using d-glucose as the reducing agent. The reaction intermediates (silver–chitosan complexes) as well as the obtained nanocomposites were investigated using transmission electron microscopy, UV–vis, FTIR and photoluminescence spectroscopy. The theoretical analysis of the UV–vis absorption of the Ag–chitosan complexes suggested that the significant contribution to the complex spectrum arises from clusters of silver containing 4–9 atoms. The absorption spectrum of the nanocomposite exhibited a strong surface plasmon resonance band at 406 nm. The photoluminescence behavior of the pure chitosan, the silver–chitosan complexes and the nanocomposites were discussed in terms of morphology and silver weight content.     

Prevention of Clostridium outgrowth in heated and hermetically sealed meat products by nitrite – a review

This paper discusses several hypotheses regarding the inhibition of Clostridium in cured meat. It focuses on the binding of iron, as there is some evidence that inhibition of Clostridium botulinum outgrowth in nitrite-cured meat products is mainly due to iron binding in such a way that it is no longer available for outgrowth of Clostridium spores. This strong binding also explains the antioxidative properties of nitrite in these products. The binding of iron, in all probability, requires no more than a moderate amount of nitrite which, after binding as nitric oxide to the haem group, is unavailable for reactions leading to N-nitroso compounds either. Other reactions of nitrite, which also could lead to Clostridium inhibition, are not discussed in detail here.     

Stability of sulphadimidine during raw fermented sausage preparation: reaction of sulphadimine with nitrite

 Raw fermented sausage was prepared from a dough to which sulphadimidine (SDM), a drug frequently used in animal husbandry, was added. With the aid of thermospray-mass spectroscopy further evidence was obtained that, during preparation, reactions with nitrite added to the dough resulted in the formation of desamino-SDM and 4-hydroxydesamino-SDM. An indication was obtained that traces of chlorodesamino-SDM were present in the brine, but this observation could not be established. Received: 22 March 1999 / Revised version: 10 May 1999     

Giant Shapiro Steps in a Superconducting Network of Nanoscale Nb Islands

Recently, a dynamic vortex Mott transition has been observed in an array of superconducting nanodots. Here, we report the effect of the interaction of microwave radiation on this system and we show the occurrence of giant Shapiro steps.     

Optimal orientation in flows: providing a benchmark for animal movement strategies

Animal movements in air and water can be strongly affected by experienced flow. While various flow-orientation strategies have been proposed and observed, their performance in variable flow conditions remains unclear. We apply control theory to establish a benchmark for time-minimizing (optimal) orientation. We then define optimal orientation for movement in steady flow patterns and, using dynamic wind data, for short-distance mass movements of thrushes (Turdus sp.) and 6000 km non-stop migratory flights by great snipes, Gallinago media. Relative to the optimal benchmark, we assess the efficiency (travel speed) and reliability (success rate) of three generic orientation strategies: full compensation for lateral drift, vector orientation (single-heading movement) and goal orientation (continually heading towards the goal). Optimal orientation is characterized by detours to regions of high flow support, especially when flow speeds approach and exceed the animal''s self-propelled speed. In strong predictable flow (short distance thrush flights), vector orientation adjusted to flow on departure is nearly optimal, whereas for unpredictable flow (inter-continental snipe flights), only goal orientation was near-optimally reliable and efficient. Optimal orientation provides a benchmark for assessing efficiency of responses to complex flow conditions, thereby offering insight into adaptive flow-orientation across taxa in the light of flow strength, predictability and navigation capacity.     

Modeling and development of an ANN-based smart pressure sensor in a dynamic environment

In many engineering applications, a capacitive pressure sensor (CPS) is placed in a dynamic environment in which the temperature variation is quite large. Since the response characteristics of a CPS are highly nonlinear and temperature dependent, in such situations, complex signal processing techniques are needed to obtain correct readout of the applied pressure. We have proposed an artificial neural network (ANN)-based smart capacitive pressure sensor, whose response characteristics can be estimated within an accuracy of ±1% error over a wide variation of temperature starting from −50°C to 150°C. This modeling scheme automatically takes care of all the nonidealities, such as, nonlinearity, offset, gain and temperature dependence, of the sensor. A novel idea of automatic collection of temperature information and its feeding into the ANN model is also proposed. In the practical implementation of this scheme, the hardware complexity poses a serious impairment. Since the tanh() functions are needed for implementation in the ANN-based model, to reduce the hardware requirement, we provide a simple scheme for computation of tanh(). Sensitivity analysis of the model with respect to the finite word-length constraint on the final stored weight values, and number of terms used in the implementation of tanh() function, have been carried out. A microcontroller-based implementation scheme for the ANN-based model is also suggested.     

万桥园

<正>序生命之路——致"万桥园"每座园林都有一个故事。它们是诗,在诉说。我们的园林讲述的是生命的故事,人的生命之路。这条路跌宕起伏,忍辱负重,讲述了忧愁河上的众桥。在这座园林中,生命是一条绵延不绝的蜿蜒小路,更恍如一座迷宫。     

Dissolved Silicon and Its Origin in Belgian Beers—A Multivariate Analysis

Beer is a quintessential part of Belgian heritage. We performed a detailed analysis of factors controlling Si content in Belgian beers as a case study to coincide with the 2011 IBiS meeting in Antwerp (Belgium). Beer is one of the richest dietary sources of Si. Three decades of research have yielded evidence of a role for Si in human physiology: it plays an essential role in bone mineral density and reduces the biological availability of aluminium. We analysed 119 Belgian beers: highest dissolved Si concentrations were found in high fermentation, traditionally brewed ales. Concentrations ranged between 214 and 2,071 μmol L^???1. This is probably due to the complexity and length of the brewing procedure: longer, more complicated processing and presence of brewing sediment in the bottle allows more Si to dissolve out of the base products like hop, barley or even rice. As a side effect of fermentation, alcohol content was related to Si content.     

Investigation of the physico‐mechanical properties of electrospun PVDF/cellulose (nano)fibers

The electro‐activity and mechanical properties of PVDF depends mainly on the β‐phase content and degree of crystallinity. In this study, cellulose fibers were used to improve these characteristics. This could be achieved because the hydroxyl groups on cellulose would force the fluorine atoms in PVDF to be in the trans‐conformation, and the cellulose particles could act as nucleation centers. Electrospinning was used to prepare the PVDF/cellulose (nano)fibrous films, and this improved the total crystallinity and the formation of β‐crystals. However, the presence and amount of cellulose in PVDF were found to have little influence on the β‐phase content and on the total crystallinity of PVDF. Improvements in the extent of crystallinity and the β‐phase content were primarily brought about by the chain‐ and crystal orientation as a result of electrospinning. The thermal stability of PVDF in the composites slightly increased with increasing cellulose content in the composites up to 1.0 wt %, while the modulus and tensile strength significantly increased up to the same filler level. The dielectric storage permittivity also increased with increasing cellulose content, but the presence of cellulose had no influence on the dynamics of the γ‐ and β‐relaxations of the PVDF. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43594.     

Fatty acid profile and affective dysregulation in irritable bowel syndrome

Irritable bowel syndrome (IBS) is a functional gastrointestinal disorder with a high co-occurrence with affective dysregulation. Affective disorders have been associated with specific changes in the PUFA and cholesterol profile. In IBS, similar changes may be present as have been reported in patients with affective disorders. This exploratory study investigates (i) the level of affective dysregulation (AD) in IBS patients and healthy controls; (ii) PUFA and cholesterol profiles in IBS patients compared with controls; and (iii) associations between PUFA and cholesterol parameters with the level of AD. Blood samples were obtained for determination of the FA composition of plasma phospholipids and serum cholesterol in 23 diarrheapredominant IBS patients and 23 healthy matched controls. AD was scored using the Symptom Check List depression scale, the Hospital Anxiety and Depression Scale, and the Hamilton Depression Rating Scale. The level of AD was higher in IBS patients compared with controls. PUFA and cholesterol profiles did not differ significantly between groups. Total n−3 PUFA and cholesterol were significantly negatively associated and the ratio of n−6 to n−3 PUFA and the ratio of arachidonic acid to EPA were significantly positively associated with the level of AD. The findings of the present study reveal that AD was higher in IBS patients compared with healthy controls and that changes in PUFA and cholesterol profiles were significantly associated with the level of AD. These results warrant further studies regarding the role of PUFA and cholesterol status in the co-occurrence of AD and functional gastrointestinal disorders.