复分解法制备磷酸二氢钾的研究

介绍了以工业氯化钾和工业磷酸为基本原料，采用复分解法，在氯化钾过量的情况下，加入氨水作为pH值调节剂，制备磷酸二氢钾（KH2PO4）的研究。产品含量大于92％，原料转化率（以磷酸计）大于85％，无三废产生。     

间甲基苯甲脒盐酸盐的合成研究

间甲基苯甲脒盐酸盐是农药和医药研究领域一个十分重要的原材料和中间体。间甲基苯甲脒盐酸盐的两步合成法是先以盐酸羟胺制备间甲基苯甲脒肟再通过加氢还原即可得到。在制备间甲基苯脒肟时，单因素考察了常规热反应、微波合成法、超声波合成法对间甲基苯脒肟产率的影响。并探索了一锅法合成间甲基苯甲脒盐酸盐的可行性。所得化合物由沸点、氢谱、质谱确认。实验结果表明：三种方式合成间甲基苯甲脒肟，其产率从大到小依次为：微波合成法>超声波合成法>常规热反应。本实验采用两步法合成间甲基苯甲脒盐酸盐的总产率为58.05%，采用一锅法合成间甲基苯甲脒盐酸盐的产率为78.19%。两步法和一锅法均可用于合成间甲基苯甲脒盐酸盐。     

Cu2O-CuAlO2-Cu基金属陶瓷导电性能研究

通过热压技术制备Cu2O-10CuAlO2-xCu金属陶瓷材料，并对其导电性能进行了研究。结果表明，Cu2O-10CuAlO2-xCu在Cu含量超过15wt．％后呈金属导电性。材料的微观结构观察及物理性能测试表明，金属陶瓷材料的电导率不仅取决于材料的金属相含量，还取决于金属相颗粒尺寸和孔隙率的大小。材料中金属相的颗粒尺寸取决于热压工艺参数，随着热压温度的升高而增大，但随热压压力的升高而减小。     

水声传感阵列指向性与系统传输性能研究

针对浅海水声通信中水汽界面和海底的反射产生多途效应对信号传输的影响,依据水下声传输原理,分析了水声信道中的噪声特点和产生多途效应机理,研究水声信道中声传感器指向性与传输性能关系,探讨水声传感阵列方式在水下通信环境的优势,设计合理的阵元间连接形式、阵列驱动电路和阻抗匹配电路,保证有效的功率耦合效率。经水下试验测试表明:采用一定指向性的声阵列结构,利用单个阵元波束宽度小于10°,构成阵列结构的波束宽度小于30°,并进行一定阻抗匹配,可减小能量损失,有效提高水声通信系统性能。     

A UNIFIED FRAMEWORK OF TARGETED MARKETING USING CUSTOMER PREFERENCES

One of the fundamental tasks of targeted marketing is to elicit associations between customers and products. Based on the results from information retrieval and utility theory, this article proposes a unified framework of targeted marketing. The customer judgments of products are formally described by preference relations and the connections of customers and products are quantitatively measured by market value functions. Two marketing strategies, known as the customer‐oriented and product‐oriented marketing strategies, are investigated. Four marketing models are introduced and examined. They represent, respectively, the relationships between a group of customers and a group of products, between a group of customers and a single product, between a single customer and a group of products, and between a single customer and a single product. Linear and bilinear market value functions are suggested and studied. The required parameters of a market value function can be estimated by exploring three types of information, namely, customer profiles, product profiles, and transaction data. Experiments on a real‐world data set are performed to demonstrate the effectiveness of the proposed framework.     

A Stability Criterion for Semi-Discrete Difference Schemes of Hyperbolic Conservation Laws on Uniform Grids

In the present study, the stability condition for semi-discrete difference schemes of hyperbolic conservation laws obtained from Fourier analysis is simplified. This stability condition can be applied only to linear difference schemes with constant coefficients implemented with periodic boundary treatment. It could often give useful results for other cases, such as schemes with variable coefficients, schemes for nonperiodic problem and nonlinear problem. However, this condition usually leads to a trigonometric inequality, which makes it not convenient to use. For explicit difference schemes on uniform grids, this trigonometric inequality can be converted to polynomial form. Furthermore, if the scheme is a high-order one, the polynomial can be factorized into a simple form. Thus, it is much easier to solve than the inequality obtained directly from Fourier analysis. For compact difference schemes and conservative schemes, similar results are obtained. Some applications of this new stability criterion are shown, including judging the stability of two schemes, proving the upstream central schemes to be stable, constructing a stable upwind dissipation relation preserving (DRP) scheme and constructing an optimized weighted essentially non-oscillatory (WENO) scheme. Since WENO schemes are nonlinear schemes, the stability analysis in the present study is performed on their underlying linear schemes. According to the numerical tests, the underlying linear scheme should be stable, otherwise the corresponding WENO scheme may display instability. These applications demonstrate that this criterion is convenient and efficient for judging the linear stability of semi-discrete difference schemes and constructing stable upwind difference schemes.     

PIV Investigations of Flow Patterns in the Entrance Configuration of Plate-fin Heat Exchanger

Flow characteristics in the entrance of plate-fin heat exchanger have been investigated by means of particle image velocimetry （PIV）. The flow field was measured using the two-frame cross-correlation technique. Streamline and velocity contour graphs at different cross-sections were obtained in the experiment. The experimental results indicate that flow maldistribution in the conventional header is very serious, while the improved header configuration with punched baffle can effectively improve the uniformity. The flow maldistribution parameter in plate-fin heat exchanger has been reduced from 1.21 to 0.21, and the ratio of the maximum velocity to the minimum is reduced from 23.2 to 1.8 by installing the punched baffle. The results suggest room for the optimum design of plate-fin heat exchanger.     

PEG1000强化钾盐催化硫醇β-羟乙基化反应

在常压、无溶剂条件下,以聚乙二醇(PEG)为相转移剂,钾盐为催化剂,碳酸乙烯酯(EC)和硫醇(RSH)为原料合成了β-羟乙基烷基硫醚(RSCH2CH2OH).系统考察了PEG对不同钾盐在RSH的β-羟乙基化反应中的固/液相转移作用以及EC用量对RSCH2CH2OH选择性的影响.通过GC和GC-MS计算与测定RSH转化率、RSCH2CH2OH选择性和副产物.结果表明,PEG本身没有催化活性,与单独加入0.5％(以RSH物质的量为基准,下同)K2CO3相比,同时加入1.0％PEG和0.5％K2CO3可显著提高RSH转化率和反应速率.PEG相对分子质量<1000时,PEG对K2CO3催化活性的强化作用随着PEG链长度的增长而增强.RSCH2CH2OH的选择性随着EC与RSH物质的量比(≥1.02)的增大而降低,副产物为乙烯基烷基硫醚和乙二醇.无溶剂条件下,PEG的加入能有效打破钾盐催化剂与液相反应物之间的相界面限制,增强钾盐催化活性,缩短反应时间,提高产品收率.     

耐磨抗冲击氧化铝陶瓷异型件的研制

主要研究了高铝快速磨罐、弧形衬板、球磨机磨口、研钵等异型件的配方及注浆成型工艺。试验配制了高铝泥浆用复合稀释荆及复合添加剂，使制品的显微结构均匀，密度得到了显著提高。     

PET/纳米TiO2复合材料松弛行为的研究

以PET/纳米TiO2复合材料为对象,采用TMA、DMTA等手段,从分子运动的角度对该复合体系的松弛行为进行了研究.结果表明,纳米粒子在聚合物基体中与分子链通过物理或化学作用限制分子链的运动与松弛.体现在复合体系的温度-形变谱图中,随纳米TiO2含量的增加,玻璃化转变提前,橡胶平台降低,黏流温度升高.在温度黏弹谱中,与纯PET相比PET/纳米TiO2复合体系的嶙a变提前,储能模量增加,低温下损耗模量也有所增加.