Producing High-Quality Titanium Alloy by a Cost-Effective Route Combining Fast Heating and Hot Processing

Powder metallurgy is a very attractive method for producing titanium alloys, which can be near-net-shape formed and have freedom in composition selection. However, applications are still limited due to product affordability. In this paper, we will discuss a possible cost-effective route, combining fast heating and hot processing, to produce titanium alloys with similar or even better mechanical properties than that of ingot metallurgy titanium alloys. Two titanium alloys, Ti-5Al-5V-5Mo-3Cr (Ti-5553) and Ti-5Fe, were successfully produced from HDH titanium powder and other master alloy powders using the proposed processing route. The effect of the processing route on microstructural variation and mechanical properties have been discussed.     

Tandem Chemoselective 1,2‐/1,4‐Migration of the Thio Group in Keto Thioesters: An Efficient Approach to Substituted Butenolides

We report herein an efficient and mechanistically unique tandem chemoselective 1,2‐/1,4‐migration of the thio group in keto thioesters that provides substituted butenolides in moderate to excellent yields. Thus, α‐keto thioesters in the presence of stabilized phosphonate carbanions undergo tandem 1,2‐sulfur migration; whereas 1,4‐migration of the thio group has been achieved with the same thioesters after the treatment with Wittig reagents followed by BF₃⋅OEt₂‐catalyzed tandem reaction. The crossover experiments and the isolation of intermediates reveal a stepwise mechanism for both of these transformations.

     

Traffic grooming,routing, and wavelength assignment in an optical WDM mesh networks based on clique partitioning

In wavelength routed optical networks, the number of wavelength channels is limited due to several constraints and each wavelength as well as each lightpath support traffic in the Gbps range. On the other hand, the traffic requested by an individual connection is still in the Mbps range. Therefore, to utilize the network resources (such as bandwidth and transceivers) effectively, several low-speed traffic streams have to be efficiently groomed or multiplexed into one or more high-speed lightpaths. The grooming problem of a static demand is considered as an optimization problem. In this work, we have investigated the traffic grooming problem with the objective of maximizing the network throughput for wavelength-routed mesh networks and map this problem to the clique partitioning problem. We have proposed an algorithm to handle general multi-hop static traffic grooming based on the clique partitioning concept. The efficiency of our approach has been established through extensive simulation on different sets of traffic demands with different bandwidth granularities for different network topologies and compared the approach with existing algorithms.     

Didecyl ester of 4‐sulfophthalic acid as a plast dopant and emulsifier in the chemical polymerization of aniline into polyaniline salt

Polyaniline salt was synthesized through the chemical oxidation of aniline with sodium persulfate as the oxidant and didecyl ester of 4‐sulfophthalic acid via three different polymerization pathways (aqueous, emulsion, and interfacial). In these polymerization processes, the ester acted as a novel plast dopant and as an emulsifier. The yield, conductivity, and number of ester units present in the polyaniline salts were determined. A polyaniline salt prepared by emulsion polymerization was soluble in chloroform and showed excellent solution‐processing properties. Polyaniline samples prepared by aqueous or interfacial polymerization were not soluble in chloroform. A soluble polyaniline salt was successfully synthesized through the washing of an organic layer containing the polyaniline salt with water in emulsion polymerization. X‐ray diffraction spectra of polyaniline salts prepared by the three different methods showed an ordered, layer‐type supramolecular structure. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

钢框架非比例损伤识别

提出能够鉴别损伤位置和截面损伤严重程度的钢框架非比例破坏监测方法。所提出的方法由两部分组成,一是损伤识别,二是损伤严重程度分析。损伤识别和严重程度分析均以结构动力性质的变化作为损伤的判据,以此来确定损伤位置和严重程度。所提方法中损伤判别的重要特点是能够在损伤严重程度分析之前,精确地区分不同的损伤区域。与整个结构尺寸相比,损伤区域相对较小,因此,确定损伤严重程度的计算量更小。检测方法的另一个特点是有些特征值或振型对噪声相对不敏感。采用所提检测方法对几个框架进行验证,结果表明,该方法能够成功地检测及量化截面的损伤。     

Phytic acid and extractable phosphorus of pearl millet flour as affected by natural lactic acid fermentation

Lactic acid fermentation of pearl millet flour decreased its phytic acid content and increased extractable phosphorus. Fermentation at 40 and 50°C for 72 h or longer eliminated phytic acid almost completely; extractable phosphorus was more than doubled. Lower temperatures (20 and 30°C) were less effective. The changes in concentration of phytic acid and extractable phosphorus may be attributed partly to phytase activity inherent in pearl millet flour.     

Testing Mechanical Stresses of Bearing Steel I-Beams of Automobile Overpass Using Magnetic and Tensometric Methods

Russian Journal of Nondestructive Testing - Magnetoelastic demagnetization of load-bearing I-beams of an automobile overpass in the city of  Tyumen during one month of its operation in...     

The effect of Sr-doped zinc oxide nanoadditives on the performance and emission parameters of a VCR engine powered by soybean biodiesel

In the present study, the effects of soybean biodiesel (SB)–diesel blends containing 1% strontium (Sr) doped zinc oxide (ZnO) nanoparticles (NPs) on the performance and emission parameters of a variable compression ratio (VCR) engine were investigated. To make the fuel blends, 25% soybean biodiesel (SB25) was added to the diesel. To improve the blend's stability, Sr/ZnO NP additions were blended with SB25 at 50 and 75 ppm utilizing an ultrasonication method and a surfactant at 2%. Various physicochemical techniques, such as X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, and ultraviolet spectroscopy, were used to characterize the produced NPs. These blends improved overall engine characteristics when used with a VCR. In comparison to the absence of nanoadditives, the brake thermal efficiency increased by 10.37% and the brake-specific fuel consumption decreased by 16.76% while using 50 ppm Sr/ZnO NPs additive in SB25 (SB25Sr/ZnO50). In addition, the presence of Sr/ZnO in SB25 results in lower harmful emissions such as hydrocarbon, CO, CO₂, and smoke, which are reduced by 11.20%, 13.81%, 41.43%, and 21.34%, respectively, when compared to SB25 fuel. The Sr/ZnO NPs in the blend are an excellent choice for improving engine emission and performance.     

Rheological studies of two component high build epoxy and polyurethane based high performance coatings

The work presented in this article involves the study of rheometric profile of several rheological additives in two-component (2K) high build epoxy zinc phosphate primer and two-component high build aliphatic polyurethane topcoat. Viscosity profile and thixotropic behavior at different shear rates have been determined for both the paints using Physica MCR 301 Rheometer of Anton Paar. The valuable information derived from these measurements led to better insight into the influence of these rheological additives on important paint properties like flow and leveling, sag control, in-can settling during storage, etc. Rheometric results were also compared with the results obtained during the actual application of these experimental coatings on mild steel panels. From the rheological study it was concluded that the thickeners based on surface-modified clay and organically modified castor oil derivative work well in epoxy zinc phosphate primer whereas polyurea-based thickener showed better results than other rheological additives in the case of the 2K polyurethane system. Measurement of low shear and high shear viscosity response of different thickeners helps in predicting storage and application behavior of these coatings which correlates well with the actual observation.