Tracking of airborne radionuclides from the damaged Fukushima Dai-ichi nuclear reactors by European networks

Radioactive emissions into the atmosphere from the damaged reactors of the Fukushima Dai-ichi nuclear power plant (NPP) started on March 12th, 2011. Among the various radionuclides released, iodine-131 ((131)I) and cesium isotopes ((137)Cs and (134)Cs) were transported across the Pacific toward the North American continent and reached Europe despite dispersion and washout along the route of the contaminated air masses. In Europe, the first signs of the releases were detected 7 days later while the first peak of activity level was observed between March 28th and March 30th. Time variations over a 20-day period and spatial variations across more than 150 sampling locations in Europe made it possible to characterize the contaminated air masses. After the Chernobyl accident, only a few measurements of the gaseous (131)I fraction were conducted compared to the number of measurements for the particulate fraction. Several studies had already pointed out the importance of the gaseous (131)I and the large underestimation of the total (131)I airborne activity level, and subsequent calculations of inhalation dose, if neglected. The measurements made across Europe following the releases from the Fukushima NPP reactors have provided a significant amount of new data on the ratio of the gaseous (131)I fraction to total (131)I, both on a spatial scale and its temporal variation. It can be pointed out that during the Fukushima event, the (134)Cs to (137)Cs ratio proved to be different from that observed after the Chernobyl accident. The data set provided in this paper is the most comprehensive survey of the main relevant airborne radionuclides from the Fukushima reactors, measured across Europe. A rough estimate of the total (131)I inventory that has passed over Europe during this period was <1% of the released amount. According to the measurements, airborne activity levels remain of no concern for public health in Europe.     

Investigation of closure of internal cracks during rolling by FE model considering crack surface roughness

Internal cracks often appear in cast slabs, and their evolution during hot deformation directly affects the product quality. In this paper, the authors investigate the closure behavior of internal cracks during plate rolling using a finite element (FE) model that takes into account the roughness of the crack surface. Influences of the roughness and reduction ratio on the closure of cracks are analyzed. The simulated results show that the models with consideration of the initial crack roughness can be used to investigate the formation of residual voids around the crack after rolling. The simulation results are validated by experimental observations. Finally, we propose an explanation of the crack closure mechanism during rolling.     

Construction materials development in sulfur–iodine thermochemical water-splitting process for hydrogen production

The sulfur iodine (SI) water splitting cycle for hydrogen production consists of three coupled chemical reactions, which includes the generation and decomposition of HI. The _HIx${\mathrm{HI}}_x$ environment is extremely corrosive and the severity increases with temperature. Immersion coupon corrosion screening tests were performed on materials selected from four classes of corrosion resistant materials: refractory metal, reactive metal, superalloys and ceramics. Of the materials tested, only Ta and Nb-based refractory metals and ceramic mullite can tolerate the extreme _HIx${\mathrm{HI}}_x$ environment. Severe pitting and dissolution was observed in two different reactive metal zirconium. A nickel based superalloy, C-276, also showed severe dissolution in _HIx${\mathrm{HI}}_x$ solution. The materials which showed good corrosion behavior will undergo further long-term immersion testing to assess performance. In addition, C-ring, U-bend and DCB test samples fabricated from qualified materials will be tested under stress corrosion conditions to investigate their crack initiation and growth properties.     

Creep deformation of Alloys 617 and 276 at 750–950 °C

Alloys 617 and 276 were subjected to time-dependent deformation at elevated temperatures under sustained loading of different magnitudes. The results indicate that Alloy 617 did not exhibit strains exceeding 1 percent (%) in 1000 h at 750, 850 and 950 °C when loaded to 10% of its yield strength (YS) values at these temperatures. However, this alloy was not capable of sustaining higher stresses (0.25YS and 0.35YS) for 1000 h at 850 and 950 °C without excessive deformation. Interestingly, Alloy 617 showed insignificant steady-state creep rate at 750 °C irrespective of the applied stress levels. Alloy 276 almost met the maximum creep deformation criterion when tested at 51 MPa–750 °C. Severe creep deformation of both alloys at 950 °C could be attributed to the dissolution of carbides and intermetallic phases remaining after solution annealing or precipitated during quenching.     

A Simulation Study for Optimizing Grain Size in Poly-Crystalline Silicon Material Using Impedance Spectroscopy

Silicon - This paper uses impedance spectroscopy as a simulation tool to analyze grain boundaries properties in poly-crystalline materials. The interfacial structure at grain boundaries in...     

Enhanced Piezoelectric,Ferroelectric, and Electrostrictive Properties of Lead-Free (1-x)BCZT-(x)BCST Electroceramics with Energy Harvesting Capability

Next-generation electronics and energy technologies can now be developed as a result of the design, discovery, and development of novel, environmental friendly lead (Pb)-free ferroelectric materials with improved characteristics and performance. However, there have only been a few reports of such complex materials’ design with multi-phase interfacial chemistry, which can facilitate enhanced properties and performance. In this context, herein, novel lead-free piezoelectric materials (1-x)Ba_0.95Ca_0.05Ti_0.95Zr_0.05O₃-(x)Ba_0.95Ca_0.05Ti_0.95Sn_0.05O₃, are reported, which are represented as (1-x)BCZT-(x)BCST, with demonstrated excellent properties and energy harvesting performance. The (1-x)BCZT-(x)BCST materials are synthesized by high-temperature solid-state ceramic reaction method by varying x in the full range (x = 0.00–1.00). In-depth exploration research is performed on the structural, dielectric, ferroelectric, and electro-mechanical properties of (1-x)BCZT-(x)BCST ceramics. The formation of perovskite structure for all ceramics without the presence of any impurity phases is confirmed by X-ray diffraction (XRD) analyses, which also reveals that the Ca²⁺, Zr⁴⁺, and Sn⁴⁺ are well dispersed within the BaTiO₃ lattice. For all (1-x)BCZT-(x)BCST ceramics, thorough investigation of phase formation and phase-stability using XRD, Rietveld refinement, Raman spectroscopy, high-resolution transmission electron microscopy (HRTEM), and temperature-dependent dielectric measurements provide conclusive evidence for the coexistence of orthorhombic + tetragonal (Amm2 + P4mm) phases at room temperature. The steady transition of Amm2 crystal symmetry to P4mm crystal symmetry with increasing x content is also demonstrated by Rietveld refinement data and related analyses. The phase transition temperatures, rhombohedral-orthorhombic (T_R-O), orthorhombic- tetragonal (T_O-T), and tetragonal-cubic (T_C), gradually shift toward lower temperature with increasing x content. For (1-x)BCZT-(x)BCST ceramics, significantly improved dielectric and ferroelectric properties are observed, including relatively high dielectric constant ε_r ≈ 1900–3300 (near room temperature), ε_r ≈ 8800–12 900 (near Curie temperature), dielectric loss, tan δ ≈ 0.01–0.02, remanent polarization P_r ≈ 9.4–14 µC cm⁻², coercive electric field E_c ≈ 2.5–3.6 kV cm⁻¹. Further, high electric field-induced strain S ≈ 0.12–0.175%, piezoelectric charge coefficient d₃₃ ≈ 296–360 pC N⁻¹, converse piezoelectric coefficient ${(d_{33}^{\ast })}_{\mathrm{ave}}$≈ 240–340 pm V⁻¹, planar electromechanical coupling coefficient k_p ≈ 0.34–0.45, and electrostrictive coefficient (Q₃₃)_avg ≈ 0.026–0.038 m⁴ C⁻² are attained. Output performance with respect to mechanical energy demonstrates that the (0.6)BCZT-(0.4)BCST composition (x = 0.4) displays better efficiency for generating electrical energy and, thus, the synthesized lead-free piezoelectric (1-x)BCZT-(x)BCST samples are suitable for energy harvesting applications. The results and analyses point to the outcome that the (1-x)BCZT-(x)BCST ceramics as a potentially strong contender within the family of Pb-free piezoelectric materials for future electronics and energy harvesting device technologies.     

Radiation-curable prepreg composites

Advanced composites, specifically carbon-fiber-reinforced epoxies, are used extensively for a variety of demanding structural applications, primarily because of their high strength-to-weight and stiffness-to-weight ratios, corrosion resistance, and damage tolerance characteristics. Electron beam (EB) treatment can be used to produce useful physical and/or chemical changes in plastics and composites by initiating various polymerization and crosslinking reactions. The advantages of using EB rather than thermal curing for carbon-fiber-reinforced epoxy composites include curing at ambient temperature, reduced curing times, and fewer volatiles. An EB-curable carbon fiber-acrylated epoxy composite is being developed for various applications. The tensile properties of the 14-ply EB-cured epoxy laminate were comparable with the properties of the thermally cured laminates used in the aircraft industry. Research is continuing to develop resin formulations and select coupling agents to improve the compression properties of EB-cured laminates.     

New and simple synthetic strategy for two-dimensional ultra-microporous aromatic framework for selective uranium capture in liquid

Uranium is a key element to improve nuclear energy demands, and thereby the extraction of uranium from seawater is a strategic way to address uranium sustainability. Herein, a novel two-dimensional porous aromatic framework (AO-PAF), which possesses an ultra-microporous architecture with an ordered structure, excellent stability and selectivity of uranium extraction from a liquid phase. AO-PAF shows excellent uranium adsorption capacities of 637 (mg/g) and 3.22 (mg/g) in simulated and natural seawater attributable to the selective uranium coordinating groups on highly accessible pores on the walls of open channels. In addition, benefiting from the super-hydrophilicity due to the presence of amidoxime groups attributes high selectivity and ultrafast kinetics with an uptake rate of 0.43 ± 0.03 (mg/g·day) and allowing half-saturation within 1.35 ± 0.09 days. This strategy demonstrates the potential of PAF not only recovery of uranium and can be extended for other applications by sensible planning of target ligands.     

Transformation of Contact‐Explosives Primary Amines and Iodine(III) into a Successful Chemical Reaction under Solvent‐Free Ball Milling Conditions

Any synthetic transformation using contact‐explosives primary amines and hypervalent iodine(III) (phenyliodine diacetate) in constrained media (extreme conditions) is practically impossible. Herein, we report a method of controlling the explosion into a successful chemical reaction using the acid‐salt NaHSO₄. As a proof‐of‐concept, we considered mechanochemical (ball‐milling) cross dehydrogenative coupling (CDC) reaction for the amidation of aldehydes via C H activation. An isothermal titration calorimetric (ITC) study was helpful to understand the enthalpy changes during the reactions before and after addition of NaHSO₄.