Gas-phase driven nano-machined TiO2 ceramics

A simple, inexpensive gas phase reaction termed as “nanocarving process” converts TiO₂ grains into arrays of single crystal nanofibers by selective and anisotropic etching. This process is conducted by exposing dense polycrystalline TiO₂ to a H₂/N₂ environment at 700 °C. The dimensions of nanofibers are around 20 nm in diameter and 1 μm in length. The preferred crystallographic orientation for the nanocarving process is the <001> direction. Nanoparticles composed of Fe and Ni were observed on the surface of TiO₂ that formed nanofiber tips. Sintering parameters before the nanocarving treatment play a critical role in the formation of nanofibers. As sintering temperature and time increased, the rate of nanofiber generation decreased. Moreover, it was observed that by varying the heat treatment conditions, it is possible to create other structures like nanowhiskers and nanofilaments. Nanowhiskers were formed by reoxidation of nanofiber-formed TiO₂ over 600 °C. Nano-filaments were generated by heat treating sintered TiO₂ in N₂-carrying water vapor at 700 °C.     

Microstructure, permeability and rheological behavior of lost foam refractory coatings

The effect of microstructure on rheology and permeability of three commercial lost foam refractory coatings available on the market called samples I, II, and III, respectively was investigated in this study. Thermal gravimetric/differential thermal analysis (TG/DTA) method was used for detailed analysis of the organic components and to determine the thermal stability of the coatings. Particle shape and size and particle size distribution (PSD) were obtained by optical microscopy and morphological studies were carried out by scanning electron microscopy (SEM). Also the scanning electron microscopy energy dispersive X-ray analysis (SEM/EDXA) technique was used for elemental analysis of refractory particles. To determine the crystalline structure of the samples, X-ray diffraction (XRD) analysis was carried out. Permeability measurements were conducted with a modified apparatus originally used for determining the permeability of casting sand. Finally the rheological behavior of the samples was investigated using a rotating coaxial rheometer to provide the flow curve for coating suspensions. The studies revealed that coating I has the highest permeability, which can be due to its large mean particle size and wide particle size distribution (PSD). Furthermore it was found that the investigated refractory coatings behave as non-Newtonian fluids with shear thinning behavior. All coatings exhibited yield stresses, indicate that they behave as Bingham-type pseudoplastic fluids.     

A new time-delay estimation in multipath

This paper addresses a new approach to time-delay estimation based upon the autocorrelation estimator (AE). The primary aim of this paper is to estimate time-delays in a multipath environment in absence of prior knowledge of the channel. The maximum likelihood estimator (MLE) and AE are two computational tools that are used to determine the parameters of a multipath channel. MLE requires some priori knowledge of the source signal and the channel; AE can be a blind estimator but it is more suitable for a simple propagation model (one extra path). Under the multipath assumption we prove that if the observation sequence is zero padded the performance of MLE exceeds that of AE, however, at the price of higher computational efforts. The general autocorrelator estimator (GAE), based on autocorrelation of the received signal, is introduced. The GAE is formulated as a blind estimator, and the pertinent Cramer-Rao lower bounds (CRLB) are derived. We also develop an algorithm to estimate the parameters of a multipath environment based on the new generalization. The performance of this algorithm is examined for different signal-noise scenarios. Our results show that the time-delays are estimated accurately based on the proposed algorithm.     

Human immunodeficiency virus infection and stroke in young patients

OBJECTIVE: To determine the association between human immunodeficiency virus (HIV) infection and stroke among young persons. DESIGN: Retrospective case-control study. SETTING: Large, inner-city public hospital. PARTICIPANTS: All patients aged 19 to 44 years with a diagnosis of stroke, whose HIV status was determined, admitted from January 1990 through June 1994. Controls matched for age and sex were selected from patients who were admitted during the same period for status asthmaticus whose HIV status was known. MAIN OUTCOME MEASURE: The associations of HIV infection with all strokes and with cerebral infarction, after adjustment for other cerebrovascular risk factors, were evaluated by Mantel-Haenszel stratified analyses. The subtypes and causes of stroke in HIV-infected patients were compared with HIV-seronegative patients. RESULTS: The HIV infection was associated with stroke (odds ratio [OR], 2.3; 95% confidence interval [CI], 1.0-5.3) and cerebral infarction (OR, 3.4; 95% CI, 1.1-8.9), after adjustment for other cerebrovascular risk factors. Among patients with stroke, cerebral infarction was more frequent in HIV-infected patients than in HIV-seronegative patients (20 [80%] of 25 vs 48 [56%] of 88, P = .04). The frequency of cerebral infarctions associated with meningitis (P < .001) and protein S deficiency (P = .06) was higher in HIV-infected patients than in seronegative patients. CONCLUSIONS: Our study suggests that HIV infection is associated with an increased risk of stroke, particularly cerebral infarction in young patients. This risk is probably mediated by increased susceptibility of HIV-infected patients to meningitis and protein S deficiency.     

Nonlinear two-dimensional velocity profile inversion using timedomain data

An iterative algorithm is developed to solve the nonlinear inverse scattering problem for two-dimensional lossless dielectric inhomogeneities using time-domain scattering data. The method is based on performing Born-type iterations on a volume integral equation and, hence, successively calculating higher-order approximations to the unknown object profile. Both the full-angle and the limited-angle problems are considered. Solutions are obtained for cases where the first-order Born approximation is severely violated. Wideband time-domain scattered field measurements make it possible to use sparse data sets and thus reduce experimental complexity and computation time. Several examples are given to show the ability of this method to invert arbitrarily shaped permittivity profiles using few transmitters and receivers. The high-resolution capability of the algorithm is also demonstrated     

The Staircase to Terrorism: A Psychological Exploration.

To foster a more in-depth understanding of the psychological processes leading to terrorism, the author conceptualizes the terrorist act as the final step on a narrowing staircase. Although the vast majority of people, even when feeling deprived and unfairly treated, remain on the ground floor, some individuals climb up and are eventually recruited into terrorist organizations. These individuals believe they have no effective voice in society, are encouraged by leaders to displace aggression onto out-groups, and become socialized to see terrorist organizations as legitimate and out-group members as evil. The current policy of focusing on individuals already at the top of the staircase brings only short-term gains. The best long-term policy against terrorism is prevention, which is made possible by nourishing contextualized democracy on the ground floor. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Probabilistic stability of uncertain composite plates and stochastic irregularity in their buckling mode shapes: A semi-analytical non-intrusive approach

In this study, the mechanical properties of the composite plate were considered Gaussian random fields and their effects on the buckling load and corresponding mode shapes were studied by developing a semi-analytical non-intrusive approach. The random fields were decomposed by the Karhunen−Loève method. The strains were defined based on the assumptions of the first-order and higher-order shear-deformation theories. Stochastic equations of motion were extracted using Euler–Lagrange equations. The probabilistic response space was obtained by employing the non-intrusive polynomial chaos method. Finally, the effect of spatially varying stochastic properties on the critical load of the plate and the irregularity of buckling mode shapes and their sequences were studied for the first time. Our findings showed that different shear deformation plate theories could significantly influence the reliability of thicker plates under compressive loading. It is suggested that a linear relationship exists between the mechanical properties’ variation coefficient and critical loads’ variation coefficient. Also, in modeling the plate properties as random fields, a significant stochastic irregularity is obtained in buckling mode shapes, which is crucial in practical applications.     

Low-Power Symmetrical Rectifier for Passive UHF RFID Transponder

Rectifier design is one of the challenging issues in passive radio-frequency identification (RFID) systems. Differential structures are good candidates as rectifiers to their high conversion efficiencies. In this paper, a novel structure is proposed to produce symmetrical power-supply utilizing differential circuit configuration simulated in 130nm CMOS technology. The proposed rectifier can provide 1.34 V DC power with 382% voltage conversion efficiency, thus demonstrated its higher performance over existing designs.     

Mechanism of gas absorption enhancement in a slurry droplet containing reactive, sparingly soluble microparticles

The absorption of a gaseous species by a slurry droplet containing reactive and sparingly soluble microparticles is numerically simulated. The problem studied is relevant to spray flue gas desulfurization systems and the objective of this study was to elucidate the effect of the reactive solid particles on the parameters that determine the mass transfer processes. Spherical droplets with internal circulation similar to Hill’s vortex flow were considered. Quasi-steady conservation equations representing the absorbed and dissolved reactant species and equations representing the dissolution of particles were numerically solved using the droplet internal circulation streamline as a coordinate. Second-order and instantaneous chemical reactions were both addressed. The results show that the reactant microparticles enhance the absorption rate by increasing the gradient of the absorbed species beneath the droplet surface. The relative effect of solid particles depends strongly on the droplet internal circulation and diminishes as stronger recirculation occurs.