全文获取类型
收费全文 | 1824篇 |
免费 | 37篇 |
国内免费 | 9篇 |
专业分类
电工技术 | 83篇 |
综合类 | 1篇 |
化学工业 | 377篇 |
金属工艺 | 47篇 |
机械仪表 | 29篇 |
建筑科学 | 24篇 |
能源动力 | 86篇 |
轻工业 | 173篇 |
水利工程 | 1篇 |
无线电 | 163篇 |
一般工业技术 | 348篇 |
冶金工业 | 384篇 |
原子能技术 | 35篇 |
自动化技术 | 119篇 |
出版年
2023年 | 7篇 |
2022年 | 13篇 |
2021年 | 18篇 |
2020年 | 6篇 |
2019年 | 22篇 |
2018年 | 22篇 |
2017年 | 21篇 |
2016年 | 20篇 |
2015年 | 14篇 |
2014年 | 26篇 |
2013年 | 79篇 |
2012年 | 76篇 |
2011年 | 77篇 |
2010年 | 57篇 |
2009年 | 68篇 |
2008年 | 62篇 |
2007年 | 74篇 |
2006年 | 53篇 |
2005年 | 50篇 |
2004年 | 52篇 |
2003年 | 66篇 |
2002年 | 46篇 |
2001年 | 49篇 |
2000年 | 37篇 |
1999年 | 38篇 |
1998年 | 145篇 |
1997年 | 80篇 |
1996年 | 73篇 |
1995年 | 52篇 |
1994年 | 52篇 |
1993年 | 53篇 |
1992年 | 24篇 |
1991年 | 31篇 |
1990年 | 24篇 |
1989年 | 21篇 |
1988年 | 20篇 |
1987年 | 14篇 |
1986年 | 23篇 |
1985年 | 26篇 |
1984年 | 22篇 |
1983年 | 19篇 |
1982年 | 21篇 |
1981年 | 15篇 |
1980年 | 10篇 |
1979年 | 11篇 |
1978年 | 12篇 |
1977年 | 22篇 |
1976年 | 18篇 |
1974年 | 6篇 |
1973年 | 5篇 |
排序方式: 共有1870条查询结果,搜索用时 0 毫秒
51.
Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a water‐miscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020–3025, 2003 相似文献
52.
Shinya Kato Yasuyoshi Kurokawa Shinsuke Miyajima Yuya Watanabe Akira Yamada Yoshimi Ohta Yusuke Niwa Masaki Hirota 《Nanoscale research letters》2013,8(1):361
To achieve a high-efficiency silicon nanowire (SiNW) solar cell, surface passivation technique is very important because a SiNW array has a large surface area. We successfully prepared by atomic layer deposition (ALD) high-quality aluminum oxide (Al2O3) film for passivation on the whole surface of the SiNW arrays. The minority carrier lifetime of the Al2O3-depositedSiNW arrays with bulk silicon substrate was improved to 27 μs at the optimum annealing condition. To remove the effect of bulk silicon, the effective diffusion length of minority carriers in the SiNW array was estimated by simple equations and a device simulator. As a result, it was revealed that the effective diffusion length in the SiNW arrays increased from 3.25 to 13.5 μm by depositing Al2O3 and post-annealing at 400°C. This improvement of the diffusion length is very important for application to solar cells, and Al2O3 deposited by ALD is a promising passivation material for a structure with high aspect ratio such as SiNW arrays. 相似文献
53.
Kenichiro Sato Masahiro Kameda Takao Yasuhara Takashi Agari Tanefumi Baba Feifei Wang Aiko Shinko Takaaki Wakamori Atsuhiko Toyoshima Hayato Takeuchi Tatsuya Sasaki Susumu Sasada Akihiko Kondo Cesario V. Borlongan Mitsunori Matsumae Isao Date 《International journal of molecular sciences》2013,14(11):21513-21524
The number of diabetes mellitus (DM) patients is increasing, and stroke is deeply associated with DM. Recently, neuroprotective effects of glucagon-like peptide-1 (GLP-1) are reported. In this study, we explored whether liraglutide, a GLP-1 analogue exerts therapeutic effects on a rat stroke model. Wistar rats received occlusion of the middle cerebral artery for 90 min. At one hour after reperfusion, liraglutide or saline was administered intraperitoneally. Modified Bederson’s test was performed at 1 and 24 h and, subsequently, rats were euthanized for histological investigation. Peripheral blood was obtained for measurement of blood glucose level and evaluation of oxidative stress. Brain tissues were collected to evaluate the level of vascular endothelial growth factor (VEGF). The behavioral scores of liraglutide-treated rats were significantly better than those of control rats. Infarct volumes of liraglutide-treated rats at were reduced, compared with those of control rats. The level of derivatives of reactive oxygen metabolite was lower in liraglutide-treated rats. VEGF level of liraglutide-treated rats in the cortex, but not in the striatum significantly increased, compared to that of control rats. In conclusion, this is the first study to demonstrate neuroprotective effects of liraglutide on cerebral ischemia through anti-oxidative effects and VEGF upregulation. 相似文献
54.
Shinya Kato Yasuyoshi Kurokawa Yuya Watanabe Yasuharu Yamada Akira Yamada Yoshimi Ohta Yusuke Niwa Masaki Hirota 《Nanoscale research letters》2013,8(1):216
Silicon nanowire (SiNW) arrays were prepared on silicon substrates by metal-assisted chemical etching and peeled from the substrates, and their optical properties were measured. The absorption coefficient of the SiNW arrays was higher than that for the bulk silicon over the entire region. The absorption coefficient of a SiNW array composed of 10-μm-long nanowires was much higher than the theoretical absorptance of a 10-μm-thick flat Si wafer, suggesting that SiNW arrays exhibit strong optical confinement. To reveal the reason for this strong optical confinement demonstrated by SiNW arrays, angular distribution functions of their transmittance were experimentally determined. The results suggest that Mie-related scattering plays a significant role in the strong optical confinement of SiNW arrays. 相似文献
55.
Akihiko Ito Yu You Hirokazu Katsui Takashi Goto 《Journal of the European Ceramic Society》2013,33(13-14):2655-2661
Ba β-alumina films were prepared by laser chemical vapor deposition. Mostly single-phase Ba β-alumina films were obtained at 1125–1200 K and for an Al/Ba molar ratio of 12.4–16.6. BaAl2O4 and α-Al2O3 were codeposited with Ba β-alumina under Ba- and Al-rich conditions, respectively. The Ba β-alumina films consisted of hexagonal grains, and the (1 1 0)-oriented Ba β-alumina films had a fin-like columnar structure. The highest deposition rate reached 120 μm h?1 at around 1200 K. A thin layer of Ba-rich superstructure was formed on the surface of the (1 1 0)-oriented columnar grains. 相似文献
56.
Transparent lutetium niobate (Lu3NbO7) bodies were prepared by reactive spark plasma sintering using Lu2O3 and Nb2O5 powders. Fully dense Lu3NbO7 bodies with density greater than 99.5% of the theoretical were obtained at 1300–1650 °C. The grains steadily grew from 0.1 to 0.6 μm with increasing sintering temperature from 1200 to 1450 °C and significant grain growth from 2.2 to 9.2 μm occurred at 1550–1650 °C. The Lu3NbO7 body sintered at 1450 °C showed the highest transmittance of 63% at 550 nm after heat treatment at 850 °C in air for 6 h. Fully dense, submicron-size transparent Lu3NbO7 exhibited Vickers hardness of ~13.0 GPa and indentation fracture toughness of 1.0 MPa m1/2. 相似文献
57.
Radical polymerization of captodatively substituted alkyl acylamidoacrylates was studied by pulsed laser polymerization using a N2 laser. Propagation rate coefficient of the acrylates was varied with solvents used in spite of a radical mechanism, but little varied with methyl, n-propyl, and isopropyl substituents on the acrylates. Arrhenius parameters for the propagation indicated that a solvent affected mostly on a frequency factor rather than a activation energy. In addition, it was suggested that these captodatively substituted propagating radicals were thermodynamically persistent but kinetically active in propagation, which resulted in rather smooth propagation in spite of bulky 1,1-disubstituted olefins. The mechanism of the polymerizations was discussed in detail on the basis of the kinetic studies and ESR spectroscopy. 相似文献
58.
Kentaro Kuratani Masayasu Uemura Minoru Mizuhata Akihiko Kajinami Shigehito Deki 《Journal of the American Ceramic Society》2005,88(10):2923-2927
We report on the direct deposition of high-quality ZrO2 thin films on various kinds of substrates by the liquid phase deposition method. After reaction for 24 h, thin films formed on various kinds of substrates, and the obtained thin film was comprised of densely packed nano-sized particles. The film annealed at 500°C showed a tetragonal phase at room temperature and this phenomenon has been discussed from the viewpoint of crystallite size effect. The result of optical transmittance measurement revealed that high transparency, more than 70% transmittance, has been achieved for the film after annealing at 900°C. 相似文献
59.
Transparent lutetium oxide (Lu2O3) body was prepared by spark plasma sintering using a two-step pressure profile combined with a low heating rate. The effects of pre-load pressures from 10 to 100 MPa and heating rates from 0.03 to 1.67 K s−1 on the microstructures and optical properties were investigated. With increasing pre-load pressures from 10 to 100 MPa, the grains became smaller with a narrower distribution, whereas the transmittance showed maxima at 30 MPa. The average grain size slightly increased from 0.67 to 0.86 μm as the heating rate increased from 0.03 to 1.67 K s−1, while the transmittance decreased. Transmittances of 60% at 550 nm and 79% at 2000 nm were obtained under a pre-load pressure of 30 MPa at a heating rate of 0.17 K s−1. 相似文献
60.
We prepared a fluorinated gemini surfactant containing a disulfide bond in its spacer chain, [C?F??(CH?)?N(CH?)?CH?CH?SSCH?CH?N(CH?)?(CH?)?C?F??]2Cl, and its analogue with a hexamethylene spacer. Monomeric thiol surfactant, [C?F??(CH?)?N(CH?)?CH?CH?SH]Cl, was readily produced by the cleavage of the gemini surfactant using dithiothreitol in water. The critical micelle concentration was determined using surface tension, conductivity, and fluorescence probe methods. The critical micelle concentration of the monomeric surfactant was significantly larger than that of the gemini surfactant. The surface tension of aqueous solution for the cleaved monomeric thiol surfactant returned gradually to the original value through the formation of the disulfide bond via air oxidation. 相似文献