Electrospun Poly(styrene) Fibers as a Protection for the First- and the Second-Generation Grubbs’ Catalyst

The study presents a novel method for protection of the first- and the second-generation Grubbs’ catalyst, by incorporation in poly(styrene) fibers through electrospinning technique. Both catalysts are sensitive to the presence of the amine hardeners in the epoxy-based self-healing composites and require protection from deactivation to retain their ability to promote polymerization reaction of the healing agent. Comparison of healing efficiencies of both catalysts suggested that poly(styrene) fibers offer better protection and dispersion for the first-generation Grubbs’ catalyst, although all the samples exhibited high-healing efficiency. Difference in stereoselectivity between two catalysts was also indicated.     

Hydrogen Effervescence from Aluminum Alloy Melts

With expansion of integrated computational materials engineering, new mathematical models are required for the assessment of processes that traditionally were manually monitored on factory production floors. The Richards logistic function is used to describe the total amount of porosity in an as-cast aluminum alloy sample after treatment under near vacuum and atmospheric pressures. The acquired function constants were correlated to the different process parameters during solidification. It is found that the Richards logistic function describes the best formation of porosity in aluminum alloy melts. The maximum porosity (M _P) and lowest porosity level (L _P) constants are directly related to the highest and lowest porosity levels in the analyzed samples, while the rate (r) defines the increase of porosity with respect to an increase in dissolved hydrogen between the threshold and mass transfer limits. The Richards logistic function can be used instead of traditional low-order mathematical equations to predict threshold limit and amount of porosity in solidified aluminum alloys by assessing the hydrogen concentration in aluminum alloy melts.