CO<Subscript>2</Subscript> adsorption at high pressures in MCM-41 and derived alkali-containing samples: the role of the textural properties and chemical affinity

The adsorption properties of N₂ and CO₂ of MCM-41 and derived alkali-containing samples were analyzed over a wide range of pressures (up to ~4500 kPa) and temperatures (between 30 and 300 °C). The high-pressure and high-temperature experiments were carried out on pure MCM-41 and K- and Na-impregnated derived samples. It was analyzed the influence of pressure and temperature on the CO₂ capture capacity on pure and impregnated samples. The adsorption performance was correlated to the structure and textural properties of the materials using X-ray diffraction and N₂ adsorption–desorption measurements. The addition of an alkaline element changes the textural properties of the material increasing the pore size, which positively affected the CO₂ adsorption capacity of these materials at high pressure. In addition, the isosteric heats of adsorption gave information about the chemical affinity between the impregnated materials and CO₂. The CO₂ adsorption at ~ 4500 kPa for the samples with 5 wt% Na at 100 and 200 °C were 77.98 and 9.79 mmol g^?1, respectively, while the pure MCM-41 adsorbs only 8.92 mmol g^?1.     

An access detection and machine cycle tracking system for machine safety

Abrasive water jet (AWJ) machining is characterized by its versatility, i.e., it can be applied to a wide variety of materials. Currently, one important application is for manufacturing gem artifacts, especially agate, which is the largest gemological material produced in the state of Rio Grande do Sul. However, one of the main obstacles to its popularization is the cost associated with the process, due to the high abrasive consumption required for a good quality surface finish. In this sense, this research paper presents a study of the influence of the main process parameters (traverse speed and abrasive mass flow rate) on the surface finish of agates machined by AWJ. The experimental procedure used three different traverse speeds, four abrasive mass flow rate in two different thicknesses of agate’s plates. Surface roughness and angle of striation marks were observed for different depths from the jet entrance surface. Results were analyzed using analysis of variance (ANOVA). Through the study, it was found that the machined surface finish varies according to the depth from the entrance surface of the abrasive jet. Also, it was concluded that the surface finish of the machined surface by AWJ (surface roughness and striation marks) of the agate’s plates machined by AWJ exhibits similar results for both thicknesses tested. ANOVA showed that the traverse speed is more significant than abrasive mass flow rate for the material studied with respect to the surface finish. Thus, for a small material thickness, it is possible to use high traverse speed and low abrasive mass flow rate which makes the process more economical.     

Simplified resubmitted lot inspection from defect counts

Nowadays, as low defect rates per item are often expected in practice, conventional single sampling for lot acceptance purposes is rendered inefficient or unduly expensive. For specific producer’s and consumer’s quality and risk requirements, resubmitted lot sampling usually needs, on the average, less inspection effort than single sampling to properly discriminate between satisfactory and unsatisfactory batches. An integer nonlinear programming problem is stated in order to determine the optimal resubmitted lot sampling plan based on defect count data with limited producer and consumer risks. Nonaccepted lots may be resubmitted for sampling inspection a certain number of times. The number of nonconformities per sampled unit is assumed to follow a Poisson distribution. Quasi-optimal inspection schemes for screening submitted lots of manufactured material are derived in closed-forms by using a normal approximation of the incomplete gamma ratio function. Explicit and quite accurate approximations of the smallest number of units to be tested per lot and the maximum tolerable number of nonconformities in the selected sample are presented. The number of resubmissions with minimal inspection effort and controlled risks is also computed. An application to the manufacturing of glass is provided for illustrative purposes.     

Study of shrinkage porosity in spheroidal graphite cast iron

This study aims at identifying the relationship between the shrinkage cavities and the solidification structure in spheroidal graphite cast iron. Cast samples specially designed to contain shrinkage cavities were used. The solidification macrostructure was revealed using the Direct Austempering After Solidification method, while the solidification microstructure was revealed by using colour etching. At the midsection of the pieces, the shrinkage cavities and the solidification structure were observed jointly. The study showed that the classification of shrinkage porosity found in literature does not correspond to the ductile iron solidification model recognized by most of the scientific community. Early solidification models, and therefore shrinkage formation mechanisms, were proposed in instances when there was not a thorough knowledge of the morphology of the solid phases during solidification. Nowadays, defects formation mechanisms can be described with higher accuracy. Therefore, an updated classification of shrinkage porosity for spheroidal graphite iron is proposed.     

Phenol decomposition in water cathode of DC atmospheric pressure discharge in air

We studied phenol decomposition in aqueous solution under the action of DC discharge at atmospheric pressure in air. The decomposition efficiency was 0.017 molecules per 100 eV. When the kinetics of forming destruction products was studied in detail, the peculiarities of air plasma action were revealed for the first time. Plasma action not only results in the formation of oxygen-containing products, which are usually formed under oxygen plasma action (hydroxyhenols, carboxylic acids, aldehydes), but also the formation of nitro phenols. The treatment is accompanied by hydrogen peroxide formation, a pH decrease, and nitric and nitrous acids formation. We also discussed the possible mechanism of the processes and the role of some active species in chemical transformations after determining some parameters of the discharge.