Ti-silicalite as catalyst for gas-phase ammoximation of cyclohexanone with molecular oxygen

The catalyst behaviour of titanium silicalite, which was found the most active and selective catalyst for liquid-phase ammoximation of cyclohexanone to the corresponding oxime with hydrogen peroxide, was investigated in the gas-phase ammoximation with molecular oxygen in and compared with those of pure silicalite and samples of vanadium and chromium silicalites. The results showed that Ti-silicalite is a selective catalyst not only in the reaction with hydrogen peroxide but also in the reaction with molecular oxygen. However, a big limitation was found in the poor activity of the silicalites which do not allow to reach high oxime yields.     

Aging and everyday memory: A cross-cultural study.

Performance on computer-simulated, everyday memory tasks was found to deteriorate with age in 434 Belgian (aged 14–88 yrs) and 434 American Ss matched on gender and age. This age-related memory decline was reasonably consistent across samples. Difficulties in cross-cultural research and the advantages of ecologically valid measurement instruments are discussed. Instruments included a grocery list selective reminding test, the Wechsler Memory Scale, the Benton Visual Retention Test, and the Wechsler Adult Intelligence Scale (WAIS). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Evaluating acrosome reaction steps with brightfield and differential interference contrast microscopy techniques.

Acrosomal integrity of bovine spermatozoa was evaluated using naphthol yellow S-erythrosine B stain with bright-field microscopy, .2% glutaraldehyde fixation with Nomarski optics, and live wet smears with Nomarski optics to compare the evaluation techniques. Four ejaculates per two Holstein bulls were enriched through a Percoll gradient, capacitated with heparin, and acrosome-reacted with lysophosphatidylcholine to prepare spermatozoa for in vitro fertilization. Spermatozoa samples were taken after each preparatory step, and percentage of intact acrosomes was evaluated with the stain, .2% glutaraldehyde, and live wet smear. Acrosomal integrity decreased with each preparatory step across all techniques. The decrease in integrity from heparin to lysophosphatidylcholine indicated that all methods detected the acrosome reaction. Technique means across preparation steps showed no differences. Correlations between microscopy techniques were high. The live wet smear used no fixation methods. Both the naphthol yellow S-erythrosine B stain and the .2% glutaraldehyde techniques employed fixation steps that may have introduced artifacts that could influence the data. The live wet smear evaluated by Nomarski optics allowed a comparable evaluation of the acrosome-reacted bovine spermatozoa. Comparing brightfield with differential interference contrast microscopy for detecting the acrosome reaction in bovine spermatozoa showed that both methods were equally accurate.     

A solenoid-derived wiggler

A novel wiggler design for use in free-electron lasers (FELs) is proposed, consisting of a staggered array of magnetic poles situated inside the bore of a solenoid. The resultant field pattern consists of a periodic transverse magnetic field on axis, as well as a longitudinal guide field. Such a wiggler has several advantages: the longitudinal field acts to confine the electrons near the FEL axis, high fields can be attained at short wiggler periods, the field strength is easily varied, and fabrication and testing of the wiggler are relatively easy. It is planned to use this wiggler design in a far infrared FEL to be built at Stanford University     

Oxidative Stability of Frozen Pork Patties. Effect of Light and Added Salt

Salt (1%) and light effects on oxidative deterioration were followed during freezer storage (?18°C) in a display cabinet. Oxymyoglobin oxidation and lipid oxidation were strongly accelerated by added salt and more moderately by exposure to fluorescent light. The light-dependent lipid oxidation was prevented by using packaging material with incorporated UV-light absorber. However, a UV-light absorber only yielded partial protection against discoloration. The two oxidation processes showed similarities in progression. In contrast to color deterioration, lipid oxidation showed an initial lag period in agreement with previous indications that pigment oxidation was an initiator of lipid oxidation in beef during freezer storage.     

Multivariable controller design in an adaptive control scheme

A multivariable control system design approach in the frequency domain is presented. The issue of control system redesign in an adaptive control scheme is discussed. Expert system techniques have been used for the automated design of controllers for multivariable systems. Design knowledge has been represented using rules, facts and objects. The design process consists of a sequence of operations obtained by heuristics and experience in the the design techniques. An automated design session of a multivariable plant using the expert system demonstrates that the expert system appears to work well in its prototype implementation.     

Improved cellulase production by stable Clostridium cellulolyticum mutants

Methods for the production of mutants of the cellulase producer Clostridium cellulolyticum ATCC 35319 were examined using an agar plate screening technique. Spontaneous and UV light-induced mutants were isolated, some of which exhibited a high level of both endoglucanase and exoglucanase activities as assayed using CMC (carboxymethyl cellulose) and PNPCb (paranitrophenyi-β-cellobioside) respectively. The volumetric enzyme activities were up to 2.5 times those of the wild strain.