Evaporation of polymer-solvent mixtures

Summary The Stefan-Winkelmann diffusion technique has been used to determine vapor pressures of high boiling point compound-solvents mixtures. Data are reported at a temperature of 67°C for the mixtures polyphenyl ether (6 rings) — benzene and carbowax 1500 — benzene and at a temperature of 100°C for the mixtures polyphenyl ether (6 rings) — toluene and tricresylphosphate-toluene. The range of concentration is only limited by the appearance of a solid phase, and results are in good agreement with those determined by vapor pressure osmometry.Nomenclature A Vapour source - B Flowing gas phase - c Concentration, g-mol/cm³ - D_AB Molecular diffusion coefficient, cm₂/s - h_i Total interface depth, cm - K Parameter defined by equation (6), dimensionless - I Polymer or high boiling point compound - M_A Molecular weight - N_AZ Molar flux, g-mol/(cm₂) (s) - P_A Partial pressure at the interface, atm - P Total pressure, atm - R Gas constant, (atm) (cm₃) / (°K) (g-mol) - T Temperature, °K - t Time, s - Y_A Molar fraction at the interface, dimensionless - z_o Initial interface depth, cm - z_i Drop of the interface depth, cm - z Interface position Greek Letters _A Density of the liquid phase, g/cm³     

PI regulation for a class of bioreactors: stability and performance

Stability and performance features of linear PI compensation for continuous bioreactors are studied in this paper. First, it is established that conventional PI control can be represented as the combination of an I/O inverse dynamics feedback with a modeling error dynamic estimator. Then, the analysis of the closed‐loop dynamics carried out with singular perturbation tools shows that PI control can recover the stability and performance induced by exact I/O inverse dynamics feedback controller. The theoretical results are illustrated via a typical numerical example. Copyright © 2012 John Wiley & Sons, Ltd.     

Modèles Hydrodynamiques pour la Séparation des Courants dans un Décanteur Pilote

Despite of its general use in industry, particle sedimentation is still a not well understood unit operation. Hydrodynamics is complex in essence, mainly because the possible volumes are depending on the operating conditions, which in turn has consequences on the stability of the equipment in unsteady state conditions.     

Influence of air oxidation on the pressure exerted by coking coals during carbonization

The effects of air oxidation of three Spanish coals on the pressure exerted during carbonization have been studied. Coals were oxidized by air in an oven at 120 and 140 °C. The extent of oxidation was assessed by the Audibert-Arnu dilatometer test. Coal samples oxidized at different levels were subjected to the Koppers-lncar laboratory coking pressure test. The results obtained indicated that for coals classified as ‘dangerous’ the ‘danger’ increased and reached a maximum at a certain level of oxidation, after which it decreased sharply. This behaviour did not occur with coals classified as safe.     

Isolation of the trail recruitment pheromone ofSolenopsis invicta

TheSolenopsis invicta trail pheromone is synthesized by the Dufour's gland and is released through the sting apparatus. The recruitment subcategory of theS. invicta trail pheromone was shown to be composed of a mixture of the orientation pheromone, (Z,E)--farnesene and an unidentified homosesquiterpene consisting of three rings and one double bond (C-1). C-1 is present in worker Dufour's glands at only 75 pg per worker equivalent. This is the first report that demonstrates that different exocrine products from the same gland control different subcategories of behavior related to mass recruitment.     

Humic fertilizers by oxiammoniation of hydrolyzed olive pits residues

Hydrolyzed olive pit residues from the production of furfural were ammoniated to obtain a nitrogenenriched humic fertilizer. Samples had been previously oxidized with nitric acid. The oxidized samples were further ammoniated in a batch reactor in the following range of experimental conditions: T = 80–210°C, , solid/liquid ratio, S/L = 0.5–2.8 w/w and reaction time, t = 1–4 h.Planning of experiments was made by statistical design and results were fitted by multiple non-lineal regression polynomials. The product consists of two fractions: a water soluble fraction which contains most of the nitrogen (10–13 wt%) and a solid fraction with a very low nitrogen content (<4.0 wt%), which is likely to be fixed during the oxidation step. The soluble fraction can be used as a humic fertilizer and the solid product as a soil conditioner.     

Experimental verification of analytic modeling of erbium-doped silica fiber amplifiers pumped at 1480 nm

Gain measurements are carried out for different lengths of three types of erbium-doped silica fiber with different pump powers at 1480 nm. From these measurements a relation is established for each type of fiber between gain and the attenuation factor of the pump power. This relation is in complete agreement with the one predicted by an analytic model based on overlapping factors, which makes it possible to obtain methods for the experimental characterization of doped fibers.     

Batch process monitoring in the original measurement's space

Quality control and safety related issues have become more and more important in industrial production of high added value products and chemical specialities during last years. In this regard, many successful applications of multivariate statistical process control (MSPC) for monitoring and diagnosis of batch processes have been presented. It is a common industrial practice to monitor the batch progress by exploiting the information contained in a historical database of successful batches using projection techniques such as principal components analysis (PCA), partial least squares (PLS) and independent component analysis (ICA). In this work, a new MSPC strategy for batch process monitoring is presented. Its distinctive feature is that it works in the space of the original variables. The technique uses only the T²-statistic for detection and identification purposes. The identification of the set of observations that signal the fault is accomplished by decomposing the T²-statistic as a unique sum of each variable contribution. Performance comparisons among the proposed strategy and the most popular PCA-based approaches are carried out by simulation of polymerization and penicillin cultivation batch processes. Results show that the new approach can be successfully applied to monitor this kind of processes since it works very well during both fault detection and identification stages.     

Fabrication and characterization of a miniaturized planar voltammetric sensor array for use in an electronic tongue

A planar voltammetric sensor array for use in an electronic tongue was fabricated using a combination of microfabrication techniques. The techniques of e-beam evaporation and pulsed laser deposition were applied to prepare a device that contained all of the electrodes integrated on a silicon die (6 mm × 6 mm). The working electrodes were metals gold, platinum, iridium and rhodium. They were characterized by SEM and EDX, and by electrochemical investigation of the packaged dies with cyclic voltammetry in solutions of sulfuric acid and of ferrocene carboxylic acid in aqueous buffer solution. The robustness and reproducibility of the devices were assessed by potential cycling in acid solution.     

Stability of Local On‐Ramp Metering Control Laws

A framework for stability analysis of local on‐ramp metering control strategies based on the cell transmission model is presented. Within this framework, it is possible to formulate Lyapunov and input‐state stability results for on‐ramp metering control strategies in an open section of highway with on‐ramps. Using this analysis, recommendations for the design of on‐ramp metering control laws set points are derived. Two examples on the use of such analysis are presented. One deals with the stability analysis of a local on‐ramp metering control law and the other with the design of a disturbance observer that, used in combination with the local on‐ramp metering control law, provides a more robust response to traffic regulation. Simulation results are included that confirm the possibility of using this framework to test the impact of local on‐ramp metering control strategies.