A new model for nanofluid conductivity based on the effects of clustering due to Brownian motion

Conductivity values of nanofluids calculated with the model proposed by Nan et al. 1 consistently underestimate the corresponding measured values for 20 sets of experimental data from 12 published studies; thus the conclusion of the recent International Nanofluid Property Benchmark Exercise 2 which stated that it is not necessary to resort to other theories (e.g., Brownian motion, liquid layering, and aggregation) for the interpretation of the INPBE database cannot be generalized. In view of this situation, a new model which takes into account clustering and micro‐convection is proposed and compared with experimental data for five nanofluids (with different particle sizes and a range of particle concentrations) as well as two previously published models. The maximum difference between the predictions of the proposed model and the measured values is 6.7% of the latter. © 2011 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.20350     

Domestic Water and Sanitation in Cyclones and Floods in Bangladesh and a Proposed Research Agenda

ABSTRACT

Water is one of the top priority item s i relief activities but the appropriateness and effectiveness of this activity may be questioned. Water and sanitation (WS) are inseparable and together they play major roles in the transmission of the pathogen of diarrhoeal disease. Thousands of people die or suffer from WS-related diseases during postdisaster periods. Here we present WS-related experiences gained after Bangladesh's 1991 cyclone and the views of participants in a regional and a national (local) workshop on this matter held in Bangladesh. About 63 per cent of the water purifying tablets (WPTs) distributed after the 1991 cyclone were found to have lost potency Relief personnel lack basic knowledge about WS practices and the management of WS provision. Participants in the two workshops documented serious problems i this field at both regional and national levels. Major issues for research may include: an appropriate environmental preparedness plan; appropriate waste disposal technologies; appropriate water treatment methods; self- help activities during vulnerable periods; and health education related to WS in disaster situations.     

Co-optimization of carbon dioxide storage and enhanced oil recovery in oil reservoirs using a multi-objective genetic algorithm （NSGA-II）

Climate researchers have observed that the carbon dioxide （CO2） concentration in the atmosphere have been growing significantly over the past century. CO2 from energy represents about 75% of the greenhouse gas （GHG） emissions for Annex B （Developed） countries, and over 60% of global emissions. Because of impermeable cap rocks hydrocarbon reservoirs are able to sequester CO〉 In addition, due to high-demand for oil worldwide, injection of CO2 is a useful way to enhance oil production. Hence, applying an efficient method to co-optimize CO2 storage and oil production is vital. Lack of suitable optimization techniques in the past led most multi-objective optimization problems to be tackled in the same way as a single objective optimization issue. However, there are some basic differences between the multi and single objective optimization methods. In this study, by using a non- dominated sorting genetic algorithm （NSGA-II） for an oil reservoir, some appropriate scenarios are proposed based on simultaneous gas storage and enhanced oil recovery optimization. The advantages of this method allow us to amend production scenarios after implementing the optimization process, by regarding the variation of economic parameters such as oil price and CO2 tax. This leads to reduced risks and time duration of making new decisions based on upcoming situations.     

Two-dimensional problem for thermoviscoelastic materials with fractional order heat transfer

Abstract

The model of equations of thermo-viscoelasticity with fractional order heat transfer is constructed. Some fundamental theorems on the linear coupled and generalized theories of thermo-viscoelasticity can be easily obtained as special cases. The medium is assumed initially quiescent. Laplace and Fourier integral transforms are utilized. The method of the matrix exponential which constitutes the basis of the state–space approach of modern control theory is applied to the system of two-dimensional equations. The resulting formulation is applied to a thermal shock half-space problem. The inversion process for Fourier and Laplace transforms is carried out using numerical method based on Fourier series expansions. Numerical results are given and illustrated graphically for the problem considered. Comparisons are made with the results predicted by the coupled theory and generalized theory. The effect of the fractional order parameter on all the considered fields is examined.     

An investigation on the role of ytterbium in ytterbium promoted γ-alumina-supported nickel catalysts for dry reforming of methane

Addition of low quantities of ytterbium to sol–gel prepared Ni/γ-Al₂O₃ catalysts has been shown to lead to significant increases in catalytic activity and long term stability in the catalytic conversion of CO₂ and CH₄ into syngas (H₂ and CO). The role of ytterbium in these catalysts was investigated in this study through detailed investigations on the structure and composition of ytterbium promoted Ni/γ-Al₂O₃ catalysts using the following techniques: synchrotron X-ray diffraction, X-ray Photoemission Spectroscopy, Transmission Electron Microscopy, Scanning Electron Microscopy/Energy Dispersive X-ray analysis, Temperature Programmed Reduction techniques and N₂ adsorption–desorption isotherms. The results obtained indicated that ytterbium, at small quantities (up to 2 wt%), interacted strongly with the support which in turn altered the interaction between nickel and the support (most notably it was found to completely inhibit the formation of NiAl₂O₄). This decreased interaction between Ni and the support also led to a higher quantity of Ni being present in the catalyst in the form of Ni.     

The Use of Object-Oriented Modeling for Water Resources Planning in Egypt

Water problems are omnipresent and are already becoming a limiting factor in the development of many countries. Currently the balance between the available and required water in Egypt is fragile. Any movement away from the balancing point means either less ambitious economic development or depletion of the resources and degradation of the environment. The continuing revolution in computer hardware and software is expected to provide more insight into the water problems and to alleviate some of the future water crises. In this paper we have investigated potential benefits which can be accrued from the application of object-oriented modeling in water resources.     

Evaluation of the chemical composition and antimicrobial activity of Mentha pulegium,Juniperus phoenicea,and Cyperus longus essential oils from Morocco

The present study evaluates the chemical composition and antimicrobial activity of the essential oils (EOs) of Mentha pulegium L., Juniperus phoenicea L. and Cyperus longus L. from Morocco. The composition of these species was analyzed by GC/MS and 84 components were identified. M. pulegium EO showed a great similarity with EOs coming from other regions, as pulegone, the major component, accounted for about 70% of the EO. The EO of J. phoenicea had as main components α-pinene (24.9%), β-phellandrene (24.4%) and α-terpinyl acetate (12.9%). The EO extracted from C. longus was remarkably rich in sesquiterpene hydrocarbons (83.2%), which included β-himachalene (46.6%), α-humulene (16.9%), and γ-himachalene (10.1%). The antimicrobial activity of these EOs has been evaluated against seven bacteria of significant importance for food hygiene. According to the results, M. pulegium showed the best bacteriostatic and bactericidal effect, followed by J. phoenicea and C. longus. So far as we know, this is the first report on the quantitative composition and biological activity of the essential oil from C. longus. The tested EOs showed a variable degree of antimicrobial activity being M. pulegium the most effective one.     

Hypoglycemic effects of cocoa (Theobroma cacao L.) autolysates

Fat, alkaloid and polyphenol contents of two clones of cocoa (UIT1 and PBC 140) were removed and the remaining powder was autolyzed at pH 3.5 and 5.2. Based on the results, autolysates of UIT produced at pH 3.5 exhibited the highest ability to inhibit α-amylase activity. However, no α-glucosidase inhibition activity was observed under the conditions specified. Autolysates produced under pH 3.5 caused the highest amount of insulin secretion. In streptozotocin-diabetic rats, all cocoa autolysates significantly decreased blood glucose at 4 h. To assure that the results from the assays were not due to the polyphenols of cocoa autolysates qualitative and quantitative tests were applied. According to their results cocoa autolysates were found to be free from polyphenols. Analysis of amino acid composition revealed that cocoa autolysates were abundant in hydrophobic amino acids. It can be suggested that besides other compounds of cocoa, its peptides and amino acids could contribute to its health benefits.     

Enzyme activity and biochemical changes of three date palm cultivars with different softening pattern during ripening

The physicochemical composition changes during palm ripening were studied. The activities of invertase and cell wall-modifying enzymes, namely pectin methylesterase (PME), β-galactosidase (β-Gal), endo-1,4-β-d-glucanase (EGase), and cellulase were monitored during growth and ripening of Shahani, Piarom and Deiry cultivars with different textures. Also, we estimated the concentrations of six organic acids by HPLC. Reducing sugars, most of organic acid, pH and TSS increased up to the full-ripe stage of all date types. On the contrary, moisture, macro and microelements and proteins decreased during the same period. Despite a considerable rise in invertase activity (200 units) during ripening of Shahani, no significant trend could be discerned in Deiry cultivar (8 units) at different stages. Our results also showed that cell wall enzymes were increased in activity during ripening and these increases were coincident with fruit softening. Furthermore, our results showed that the composition and the variation of the chemical compositions mainly depended on the cultivar and maturity stage.     

Phosphorus and nitrogen in the waters of the El-Kabir River watershed in Syria and Lebanon

In order to assess the quality of the waters of the El‐Kabir River, which forms the border between Lebanon and Syria, water samples were collected for phosphorus (P) and nitrogen analyses at 39 sample stations in the river watershed (18 in Syria, 21 in Lebanon). These samples were collected on the main stem and three major tributaries (Nahr al‐Arous and Nahr Nasrive in Syria, Chadra River in Lebanon). Three major springs also were sampled. The sampling was carried out in September 2001, and January, April and August 2002. Nutrient analyses were carried out on samples taken in September 2001, January and April 2002 in Syria, and in September 2001 and August 2002 in Lebanon. The P concentrations were extremely high throughout the watershed, as were the ammonia‐nitrogen and nitrate‐nitrogen concentrations, indicating extensive pollution. Although the nitrite‐nitrogen concentration was relatively low, it is at the upper end of what might be considered normal, thereby perhaps being indicative of some anthropogenic sources. The spring waters were found to be polluted by nutrients. The nutrient sources contributing to the river pollution were mainly from piped, direct sewage discharges from the many settlements throughout the basin. These were supplemented by diffuse sources directly from agricultural fertilizer use and from the indiscriminate disposal of solid wastes into the river and on the stream banks and lands adjacent to the roads of the watershed.