A Case Study on Optimization of Biomass Flow During Single-Screw Extrusion Cooking Using Genetic Algorithm (GA) and Response Surface Method (RSM)

In the present study, response surface method (RSM) and genetic algorithm (GA) were used to study the effects of process variables like screw speed, rpm (x ₁), L/D ratio (x ₂), barrel temperature (°C; x ₃), and feed mix moisture content (%; x ₄), on flow rate of biomass during single-screw extrusion cooking. A second-order regression equation was developed for flow rate in terms of the process variables. The significance of the process variables based on Pareto chart indicated that screw speed and feed mix moisture content had the most influence followed by L/D ratio and barrel temperature on the flow rate. RSM analysis indicated that a screw speed?>?80 rpm, L/D ratio?>?12, barrel temperature?>?80 °C, and feed mix moisture content?>?20% resulted in maximum flow rate. Increase in screw speed and L/D ratio increased the drag flow and also the path of traverse of the feed mix inside the extruder resulting in more shear. The presence of lipids of about 35% in the biomass feed mix might have induced a lubrication effect and has significantly influenced the flow rate. The second-order regression equations were further used as the objective function for optimization using genetic algorithm. A population of 100 and iterations of 100 have successfully led to convergence the optimum. The maximum and minimum flow rates obtained using GA were 13.19?×?10^?7 m³/s (x ₁?=?139.08 rpm, x ₂?=?15.90, x ₃?=?99.56 °C, and x ₄?=?59.72%) and 0.53?×?10^?7 m³/s (x ₁?=?59.65 rpm, x ₂?=?11.93, x ₃?=?68.98 °C, and x ₄?=?20.04%).     

Preferential oxidation of linolenic acid compared to linoleic acid in the liver of catfish (Heteropneustes fossilis andClarias batrachus)

The fate of [1-¹⁴C] linoleic acid and [1-¹⁴C] linolenic acid in the liver slices and also in the liver tissues of live carnivorous catfish,Heteropneustes fossilis andClarias batrachus, was studied. Incorporation of the fatty acids into different lipid classes in the live fish differed greatly from the tissue slices, indicating certain physiological control operative in vivo. The extent of desaturation and chain elongation of linoleic and linolenic acids into long-chain polyunsaturated fatty acids was low. Linolenic acid was oxidized (thus labeling the saturated fatty acid with liberated¹⁴C-acetyl-CoA) in preference to linoleic acid, and this oxidation also seemed to be under physiological control since both of the fatty acids were poorly oxidized in the tissue slices and in the killed fish. These fish can therefore recognize the difference in the acyl chain structures of linoleate and linolenate. The higher oxidation of liolenic acid and poor capacity for its conversion to longer chain, highly unsaturated derivatives indicates a higher demand for the dietary supply of these essential fatty acids in these two species.     

Studies on sulfur vulcanization of natural rubber accelerated combinedly with 2-mercaptobenzothiazole and diphenylguanidine both in presence and absence of dicumyl peroxide

Sulfuration of natural rubber (NR) by the binary accelerator 2-mercaptobenzothiazole (MBT) and diphenylguanidine (DPG) both in presence and in absence of ZnO and stearic acid with or without dicumylperoxide (DCP) was studied in detail. It was observed that the rate of decomposition of DCP in presence of both MBT and DPG is quite similar to that with MBT alone. The reduction of crosslinking depends also on MBT only. Through DPG has no influence on the decomposition rate, it reacts with MBT during the vulcanization process and suppresses the retardation caused by MBT on the DCP vulcanization. In accordance with the initial additiveness of crosslinking in systems containing DCP, the free sulfur decrease, and the rapidity of crosslink formation the vulcanization process of MBT-DPG-S-NR systems was interpreted in terms of a polar mechanism induced by the complex MSH₂NR′R″. In mixtures containing DCP together with sulfur, MBT, DPG, ZnO, and stearic acid, the initial stage of crosslinking is additive as indicated by a mixed reaction as well as by a methyl iodide treatment of the vulcanizates. Comparison with single accelerators shows a pronounced synergistic effect. This is because of the enhanced activity of the MBT-ZnO-stearic acid complex due to DPG which also induces polar sulfuration of NR by forming the active complex MSH₂NR′R″. In presence of ZnO and stearic acid, DCP cannot increase the net crosslink density but suppresses the reversion so much pronounced in its absence.     

Development and application of a simulation model for reservoir management

The success of irrigation system operation and planning depends on accurate quantification of supply and demand, and an equitable distribution of available water. The ultimate aim of this study was to determine how to meet the irrigation water demands if possible or to minimize the gap between the water supply and the demand. Most of the irrigation literature focuses only on the demand and the distribution aspects of this issue Irrigation projects that receive water from reservoirs, however, can be challenging to manage because the annual fluctuations in available water release from a reservoir can have a considerable impact on the irrigation management strategy. In real‐world situations, the reservoir operating rules guide reservoir operators in making actual water release decisions. This study develops a water balance simulation model for reservoir management, as well as testing it for Kangsabati Reservoir, West Bengal, India. Two rule curves for deciding irrigation water available from the reservoir were generated by taking the average and minimum stage values on a daily basis for a 16‐year period (1988–2003). Maintaining a minimum stage of 120.4 m throughout the year served as another rule to decide the release water available for irrigation. The minimum allowable stage of reservoir corresponding to a particular date of the year can be determined from those reservoir specific rule curves generated for irrigation purposes. The maximum permissible water release/outflow for irrigation from the test reservoir was taken as the volume of water available above the minimum allowable stage corresponding to the selected rule curve. The saturated hydraulic conductivity value (K_S) was calibrated to be 4.31 mm day^?1 for Kangsabati Reservoir.     

Experimental investigation of convective heat transfer coefficient of Al2O3/water nanofluid at lower concentrations in a car radiator

For many years, water and ethylene glycol were used as conventional coolants in automotive car radiators, but these coolants offer lower thermal conductivity than is required. This study is focused on the application of water‐based Al₂O₃ nanofluid at lower concentrations in a car radiator. The Al₂O₃ nanoparticles with an average diameter of 50 nm are dispersed in demineralized water at four different volume concentrations (0.1 vol. % to 0.4 vol. %) without any dispersant or stabilizer. Flow rate is varied in the range of 2 l/min to 5 l/min and inlet coolant temperature to the radiator is set to 50 °C, 60 °C, and 70 °C. The results show that the heat transfer coefficient increases with an increase in particle concentration, flow rate, and inlet temperature of coolant and the maximum increase in heat transfer coefficient is 45.87 % compared to pure water. However, the Nusselt number increases with the increase in particle concentration, Reynolds number, and inlet temperature of the coolant. In addition with the experimental study, a regression analysis is performed by using the ANOVA method and generates a correlation for the convective heat transfer coefficient.     

Hydrogen-iodide decomposition over PdCeO2 nanocatalyst for hydrogen production in sulfur-iodine thermochemical cycle

A highly active and stable catalyst for hydrogen-iodide decomposition reaction in sulfur-iodine (SI) cycle has been prepared in the form of PdCeO₂ nanocatalyst by sol-gel method with different calcination temperatures (300 °C, 500 °C, and 700 °C). XRD and TEM confirmed a size around 6–8 nm for PdCeO₂ particles calcined at 300 °C. Raman study revealed large number oxygen vacancies in PdCeO₂-300 when compared to PdCeO₂-500 and PdCeO₂-700. With increase in calcination temperature, the average particle size increased whereas the specific surface area and number of oxygen vacancies decreased. Hydrogen-iodide catalytic-decomposition was carried out in the temperature range of 400°C–550 °C in a quartz-tube, vertical, fixed-bed reactor with 55 wt % aqueous hydrogen-iodide feed over PdCeO₂ catalyst using nitrogen as a carrier gas. PdCeO₂-300 showed hydrogen-iodide conversion of 23.3%, which is close to the theoretical equilibrium conversion of 24%, at 550 °C. It also showed a reasonable stability with a time-on-stream of 5 h.     

海尔兹山纪念堂

正海尔兹山纪念堂是一个独特的纪念场所。为了纪念耶路撒冷所有阵亡的士兵,设计中包含了他们名字。这是和平年代期冀希望的象征。尽管临近耶路撒冷繁华路段,纪念堂设计为一个平静的圣经式场地,整个空间孤隐而静谧。建筑主体空间通过挖掘山体而成,形成个人或集体纪念活动的私密空间。纪念堂上方的山体,以耶路撒冷石塑造出新的曲线。纪念堂形成一个波形漏斗状结构,缓缓通向天际。这种不规则的涡旋状结构为纪念堂营造出不断变化的自然光。     

Wave packet enriched finite element for generalized thermoelasticity theories for thermal shock wave problems

A unified enriched finite element (FE) formulation for two generalized thermoelsaticity theories is developed for the transient thermal shock problems in one and two dimensional domains. Both the displacement and temperature field interpolations are enriched with harmonic functions defined in the local element coordinates. The coupled field finite element equations are derived using the generalized Hamilton’s principle and solved directly in time domain using the standard Newmark-β time integration technique as opposed to the transform techniques usually adopted for thermal shock problems. The method is assessed in comparison with the Laplace transform based analytical solutions and FE solutions with dynamic meshing available in the literature. It is shown that the present solution with a static uniform mesh captures the sharp discontinuities in the temperature and displacement fields and the wave properties of heat conduction very accurately, practically eliminating the severe drawbacks of the conventional FE solutions such as the spurious undulations and flattening out, while maintaining better computational e?ciency.     

3D study of temperature drop behavior of subsonic rarefied gas flow in microchannel

3D Numerical study of temperature variation for subsonic rarefied gas flow in a microchannel is carried out using an in-house MPI-based parallelized DSMC code. The temperature drop in the microchannel decreases with an increase in the aspect ratio whereas it increases with an increase in the pressure ratio, the cross-aspect ratio (CAR), and the Knudsen number. 3D and 2D simulations results are compared and effect of the CAR and Knudsen number are brought out. Finally, a correlation that predicts the temperature drop is formulated along with a list of conditions that ensures a near isothermal flow.