Antibacterial responses of zinc oxide structures against Staphylococcus aureus, Pseudomonas aeruginosa and Streptococcus pyogenes

The antibacterial responses of zinc oxide (ZnO) structures against Staphylococcus aureus, Pseudomonas aeruginosa, and Streptococcus pyogenes were investigated. Two ZnO powder samples, one with rod-like (ZnO-1) and the other with plate-like (ZnO-2) structures, were characterized for their morphological, structural, and optical properties. The rods were 30–120 nm in diameter, and the plates were 40–100 nm thick. XRD results revealed the wurtzite crystallinity of ZnO with average crystallite sizes of 33.72 (ZnO-1) and 39.25 (ZnO-2) nm. ZnO-2 possessed a relatively higher green photoluminescence than that of ZnO-1, suggesting a relatively higher amount of oxygen vacancies in ZnO-2 structures. Optical density measurements showed that both ZnO samples inhibited the growth of S. aureus, P. aeruginosa, and S. pyogenes by 29–98% after 24 h of treatment. The most dramatic growth inhibition was observed in S. pyogenes with 96% and 98% inhibition for ZnO-1 and ZnO-2, respectively, leading to a probable bactericidal phenomenon. The toxicological effect on S. pyogenes was probably due to the absence of catalase, making the bacteria vulnerable to the harmful reactive oxygen species (ROS) released by ZnO. ZnO-1 induced higher inhibition toward S. aureus and P. aeruginosa than that of ZnO-2 because of the smaller particle size of rod structures compared to plate and slab structures. The adhesion of ZnO particles on the membrane of bacteria could be the underlying cause of zinc toxicity effect towards the bacteria. ZnO-1 possessed larger surface area and provided higher amount of zinc atom, thereby inducing higher level of toxicity toward the bacteria. Two possible mechanisms were proposed to explain the inhibition of bacteria, namely, ROS toxicity toward cellular constituents and interaction of zinc with bacteria membrane through adhesion of ZnO particle. Several ZnO morphological-antibacterial correlations were presented in this work.     

Development and characterization of novel modified red mud nanocomposites based on poly(hydroxy ether) of bisphenol A

This study dealt with the use of various quantities of modified red mud as a nanofiller in a poly(hydroxy ether) of bisphenol A (Phe) based matrix. Phe‐based polymer nanocomposites reinforced with acidically and organically modified layered red mud were prepared by a conventional solvent‐casting technique. The best dispersion occurred in the polymer nanocomposites where the interactions between the functional groups of the polymer matrix and those of the organic substitution of the red mud appeared to be the highest. The particle size of the modified red mud was determined by field emission scanning electron microscopy. The as‐synthesized composite films were typically characterized by Fourier transform infrared spectroscopy and X‐ray diffraction. The dispersion of the modified fillers within the matrix was studied by transmission electron microscopy. The thermal properties measured by thermogravimetric analysis showed enhanced thermal stability of a series of composite materials. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Understanding the effects of backbone chemistry and anion type on the structure and thermal behaviors of imidazolium polyimide‐ionenes

Advancements in the performance and properties of ionenes can be achieved via rational molecular design strategies which combine structural elements of ionic liquids (ILs) and high‐performance polymers. The use of imidazole‐amine molecules with asymmetric reactivity has enabled the synthesis of new bis(imidazole) diimide monomers which are then polymerized via the Menshutkin reaction, followed by anion exchange to various molecular species well known in the IL literature. In this work, three types of imidazolium polyimide‐ionene backbones were synthesized starting from 1‐(3‐aminopropyl)imidazole and pyromellitic dianhydride (PMDA) or 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride (6FDA) or from 1‐(4‐aminophenyl)imidazole and 6FDA, with these monomers then reacted with para‐dichloroxylene. The Cl^? anions on the resultant ionenes were then exchanged with one of six molecular anions yielding a total of 18 distinct polymer compositions. The functional groups present within the cationic backbone as well as the anion type were observed to strongly influence both the thermal and organizational properties of these new ionenes. © 2019 Society of Chemical Industry     

Structural,Electrical, and Magnetic Properties of Ferrite–Polymer Composites

Six samples consisting of polypyrrole (PPy), pure NiFe₂O₄ ferrite, and their composites at ratio of 1:4 (PF1), 1:2 (PF2), 3:4 (PF3), and 1:1 (PF4) have been prepared by a coprecipitation method and their structural, electrical, dielectric, and magnetic properties measured experimentally. The direct-current (DC) resistivity was enhanced with increasing ferrite content, while the dielectric constant and loss decreased. The magnetic properties of all the composites and the ferrite revealed a narrow loop, confirming their soft nature. The saturation magnetization, remanence, and coercivity values increased with increasing ferrite content. The obtained parameter values suggest that such materials might be suitable for use in high-frequency applications.     

Development of Social Media Analytics System for Emergency Event Detection and Crisis Management

Social media platforms have proven to be effective for information gathering during emergency events caused by natural or human-made disasters. Emergency response authorities, law enforcement agencies, and the public can use this information to gain situational awareness and improve disaster response. In case of emergencies, rapid responses are needed to address victims’ requests for help. The research community has developed many social media platforms and used them effectively for emergency response and coordination in the past. However, most of the present deployments of platforms in crisis management are not automated, and their operational success largely depends on experts who analyze the information manually and coordinate with relevant humanitarian agencies or law enforcement authorities to initiate emergency response operations. The seamless integration of automatically identifying types of urgent needs from millions of posts and delivery of relevant information to the appropriate agency for timely response has become essential. This research project aims to develop a generalized Information Technology (IT) solution for emergency response and disaster management by integrating social media data as its core component. In this paper, we focused on text analysis techniques which can help the emergency response authorities to filter through the sheer amount of information gathered automatically for supporting their relief efforts. More specifically, we applied state-of-the-art Natural Language Processing (NLP), Machine Learning (ML), and Deep Learning (DL) techniques ranging from unsupervised to supervised learning for an in-depth analysis of social media data for the purpose of extracting real-time information on a critical event to facilitate emergency response in a crisis. As a proof of concept, a case study on the COVID-19 pandemic on the data collected from Twitter is presented, providing evidence that the scientific and operational goals have been achieved.     

Applications of three-dimensional finite-difference seismic modeling in oil field exploitation and simulation

Two-dimensional finite-difference seismic models are excited by a line-source which leads to incorrect amplitudes. Moreover, in a structurally complex environment with strong three-dimensional (3-D) features, the results obtained from such models are often incorrect and do not include any out-of-plane events. On the other hand, 3-D models based on the ray-theory approximation fail to provide vital information such as diffractions and interference patterns which can strongly influence the seismic expression associated with hydrocarbon reservoirs. We present the results of a study in which an approximate version of mapped surfaces was used to carry out a synthetic 3-D finite-difference survey. This followed the necessary adjustment of various horizons and it involved the calibration of synthetic sections by comparing them with the corresponding unmigrated real-data sections. The simulation of reservoir characteristics was accomplished in reference to two key seismic horizons used in the model.     

Solar sterilization of water

According to a WHO report 80% of the diseases in developing countries are due to water related bacteria. Drinking boiled water is one of the solutions to this problem. Fuel wood is scarce but solar energy is plentiful in these countries and may be used to kill bacteria in drinking water. A simple and inexpensive solar device is shown to be effective in elimination of bacteria from water supplying sterilized water for family requirements. It is also shown that water need not be boiled but heated to 65°C only to make it bacteria free.     

All-organic PANI–DBSA/PVDF dielectric composites with unique electrical properties

Novel all-organic polymer high-dielectric permittivity composites of polyaniline (PANI)/poly (vinylidene fluoride) (PVDF) were prepared by solution method and their dielectric and electric properties were studied over the wide ranges of temperatures and frequencies. To improve the interface bonding between two polymers, dodecylbenzenesulfonic acid (DBSA), a bulky molecule containing a polar head and a long non-polar chain was used both as a surfactant and as dopant in polyaniline (PANI) synthesis. Synthesized conducting PANI–DBSA particles were dispersed in poly(vinylidene fluoride) (PVDF) matrix to form an all-organic composite with different PANI–DBSA concentrations. Near the percolation threshold, the dielectric permittivity of the composites at 100 Hz frequency and room temperature was as high as 170, while the dielectric loss tangent value was as low as 0.9. Like typical percolation system, composites experienced high dielectric permittivity at low filler concentrations. However, their dielectric loss tangent was low enough to match with non-percolative ceramic filler-based polymer composites. Maximum electrical conductivity at 24 wt% of PANI–DBSA was mere 10^?6 S/cm, a remarkably low value for percolative-type composites. Increase in the dielectric permittivity of the composites with increase in temperature from 25 to 115 °C for different PANI–DBSA concentrations was always in the same range of 50–60 %. However, the degree of increase in the electrical conductivity with the temperature was more prominent at low filler concentrations compared with high filler concentrations. Distinct electrical and their unique thermal dependence were attributed to an improved interface between the filler and the polymer matrix.     

Facile preparation of size-controlled gold nanoparticles using versatile and end-functionalized thioether polymer ligands

At present, thiol ligands are generally used whenever the classical Brust-Schiffrin two-phase method is employed to prepare metal nanoparticles. In general, the previous research was mainly focused on utilizing small molecular thiol compounds or thiol polymers as the stabilizers in organic phase to obtain small sized and uniform gold nanoparticles (Au NPs). Such preparations are usually associated with the problems of ligand exchange on the nanoparticle's surface due to strong Au-thiol interaction. Herein, we report an approach to produce fairly uniform Au NPs with diameters about 2-6 nm using thioether end-functional polymer ligands (DDT-PVAc and PTMP-PVAc) as the capping agents. These nanoparticles are thoroughly characterized using DLS, TEM, UV-Vis spectroscopy and other complementary techniques. The results indicate that multidentate thioether polymeric ligands (PTMP-PVAc) lead to formation of smaller but special 'multimer' morphology in organic phase; whereas fairly uniform nanoparticles are produced using monodentate thioether functionalized ligands (DDT-PVAc). Further modification of such polymer ligands to introduce the hydrophilic functionalities realizes the phase transfer of Au NPs from organic to aqueous media.