Asiatic acid prevents lipid peroxidation and improves antioxidant status in rats with streptozotocin-induced diabetes

Oxidative stress is a common pathogenesis of diabetes mellitus and asiatic acid (AA) plays an important role in ameliorating those difficulties. The present study was designed the protective effects of AA on altered lipid peroxidation products, enzymic and nonenzymic antioxidants in streptozotocin (STZ)-induced diabetic rats. Diabetes was induced in experimental rats by single dose STZ (40 mg/kg b.w.) injection. Diabetic rats showed significantly increased levels of plasma glucose, thiobarbituric acid reactive substances, lipid hydroperoxides, aspartate aminotransferase, alanine aminotransferase, bilirubin, creatine kinase, urea, uric acid, creatinine and decreased levels of plasma insulin. The activities of enzymatic antioxidants such as superoxide dismutase, catalase, glutathione peroxidase and glutathione-S-transferase and the levels of non-enzymatic antioxidants such as vitamin C, vitamin E and reduced glutathione were decreased in diabetic rats. Oral treatment with AA (20 mg/kg b.w.) showed near normalized levels of plasma glucose, insulin, lipid peroxidation products, enzymatic and nonenzymatic markers in diabetic rats. The results demonstrate that AA possesses potent antioxidant effect comparable with glibenclamide in improving antihyperglycemia and attenuating antioxidant status in diabetic rats.     

Half tunnels along hill roads of Himalaya—an innovative approach

‘Half tunnels,’ which are excavated as overhangs within steep slopes of hard rocks, have an advantage over conventional full tunnels or open excavations in that they involve less cost and time. However, due to a lack of interest and their uncommon occurrence, the design and analysis of half tunnels have remained by and large unexplored. In the present paper, an effort has been made to study some of the half tunnels in the Middle and the Higher Himalaya in India. In addition to studying the geology of half tunnels, rock mass properties pertaining to Q and RMR for the rocks exposed around the half tunnel have been evaluated. The Markland test has been carried out to assess the probability of plane or wedge failures along the slopes in the half tunnel area. The results obtained have been again confirmed by analyzing the data with the help of a computer program . Both analyses suggest that the wedges are stable and that all the half tunnels analyzed are safe. Finite element analyses for different slopes and spans of half tunnels have been carried out to study the distribution of stresses around half tunnels. The range of maximum tensile stress concentration in the roof of half tunnels for different slopes is suggested.     

Inverted emulsion polymerization route to polyaniline‐3D nanofiber network using sulfonated‐p‐cresol as novel dopant

Sulfonated‐p‐cresol (SPC) was used as novel dopant for the first time in the synthesis of polyaniline in 3D nanofiber networks (PANI‐3D). Polyaniline in 3D nanofiber network was prepared using organic solvent soluble benzoyl peroxide as oxidizing agent in presence of SPC and sodium lauryl sulfate (SLS) surfactant via inverted emulsion polymerization pathway. The influence of synthesis conditions such as the concentration of the reactants, stirring/static condition, and temperature etc., on the properties and formation of polyaniline nanofiber network were investigated. Polyaniline in 3D nanofiber network with 40–160 nm (diameter), high yield (134 wt % with respect to aniline used), and reasonably good conductivity (0.1 S/cm) was obtained in 24 h time. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Performance and emission study in manifold hydrogen injection with diesel as an ignition source for different start of injection

Over the past two decades there has been a considerable effort to develop and introduce alternative transportation fuels to replace conventional fuels, gasoline and diesel. Environmental issues are the principal driving forces behind this effort. To date the bulk of research has focused on the carbon-based fuels such as reformulated gasoline, methanol and natural gas. One alternative fuel to carbon-based fuels is hydrogen which is considered to be low polluting fuel. In the present experimental investigation hydrogen was injected into the intake manifold by using an injector. Using an electronic control unit (ECU) the injection timing and the duration were controlled. From the results it is observed that the optimum injection timing is at gas exchange top dead center (GTDC). The efficiency improved by about 15% with an increase in NO_X emission by 3% compared to diesel. The smoke emission decreased by almost 100%. A net reduction in carbon emissions was also noticed due to the use of hydrogen. By adopting manifold injection technique the hydrogen–diesel dual fuel engine operates smoothly with a significant improvement in performance and reduction in emissions.     

Corrosion behavior of Cr electrodeposited from Cr(VI) and Cr(III)-baths using direct (DCD) and pulse electrodeposition (PED) techniques

A comparison was made between the electrochemical corrosion behaviors of chromium deposited from hexavalent [Cr(VI)] and trivalent [Cr(III)] chromium baths using direct current (DCD) and pulse electro deposited (PED) techniques. Chromium coatings were deposited on mild-steel (MS) substrate. The corrosion behavior of both DCD and PED chromium from Cr(VI) and Cr(III)-baths in 3.5%NaCl solution was studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results indicated that PED chromium from Cr(VI) and Cr(III)-baths have higher charge-transfer resistance R_ct and very low I_corr than that of DCD chromium on mild-steel substrate.     

Surface chemistry and adsorption mechanism of cadmium ion on activated carbon derived from Garcinia mangostana shell

A detailed surface characterizations and adsorption mechanism of Cd²⁺ on chemical activated carbon (CAC) prepared from Garnicia mangostana shell were investigated. The activation is accomplished in self-generating atmosphere using phosphoric acid as activating agent. The characterizations performed are elemental analysis, functional group identification, N₂ adsorption isotherm and surface charges. Adsorption mechanism of metal ion was tested using Cd²⁺ as model ion. CAC achieved BET surface area of 1,498 m²/g with a mixture of micro and mesopores. The point of zero charge is observed to be at pH 2.8 and the optimum pH for Cd²⁺ adsorption on CAC is 12. The adsorption isotherm followed the Freundlich model, and the adsorption kinetics was explained by pseudo-second order kinetic model. From thermodynamic studies, the adsorption was found to be physical adsorption. X-ray photoelectron spectroscopy (XPS) confirmed the adsorption of Cd²⁺ onto CAC as +2 oxidation state.     

Experimental investigation on a DI dual fuel engine with hydrogen injection

Over the past two decades considerable efforts have been undertaken to develop and introduce new alternative fuels for the conventional gasoline and diesel. Many alternative fuels, both liquid and gaseous, have been experimented and some have even been commercialized such as ethanol, natural gas, etc. Hydrogen has been considered as an excellent fuel to replace the petroleum‐based fuels due to its clean burning characteristics. In the present experimental investigation, hydrogen was injected in the intake manifold and diesel fuel was injected inside the engine cylinder in the conventional manner. Hydrogen injection parameters such as injection timing, injection duration and quantity of hydrogen injected were optimized based on the performance and emission characteristics. Exhaust gas recirculation (EGR) technique was adopted to reduce the oxides of nitrogen emission. From the results it was observed that for hydrogen diesel dual fuel (DF) engine, the optimal operating parameters for hydrogen injection were start of injection at gas exchange top dead centre with injection duration of 30° crank angle with the hydrogen flow rate of 7.5 litres per minute (lpm). With EGR the optimized condition was found to be 20% for the entire load. The brake thermal efficiency with 20% EGR increases by 16% at 75% load as compared with diesel, while at full load it reduces by 8% due to the recirculation of exhaust gases that results in a reduction of intake oxygen concentration compared with part load. NO_X emission decreases by five and half times, while other emissions increase by 1.4 times as compared with DF engine. Copyright © 2008 John Wiley & Sons, Ltd.     

Polynorbornene/fluorosilica hybrids for hydrophobic and oleophobic coatings

Polynorbornene dicarboxylic anhydride (PNA)/fluorosilica hybrid coating materials with good hydrophobicity, oleophobicity, transparency, thermal stability, and hardness were synthesised using a sol–gel method. The surface structure, transparency, hydrophobicity, oleophobicity, and surface free energy of the coating could be controlled by adjusting the fluorosilane ratio. The maximum static water and oil contact angles of films were 112° and 87°, respectively. The PNA/fluorosilica hybrid films exhibited good transparency and colourlessness. The marks written using water and oil-based pens on the films could be erased with a tissue even after eight times. In addition, the hardness of the hybrid films was enhanced to 4H with increasing fluorosilane content.     

Simple synthesis of ZnS nanoparticles in alkaline medium

ZnS nanoparticles were successfully synthesized by reflux under an alkaline medium. The nanoparticles were characterized by using X-Ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The optical properties of ZnS nanoparticles were examined by photoluminescence (PL) spectrum. The result shows that the as-synthesized ZnS nanoparticles had a cubic phase. SEM image shows that ZnS nanoparticles are basically in spherical shape and are homogeneous. The particle size was found to be in the range of 18 nm.     

Evaluation of connection flexibility in cold formed steel racks

Steel storage racks are three-dimensional framed structures fabricated from cold formed steel sections, wherein hook-in end connectors are used to make beam-column connections which are basically boltless and semi-rigid in nature. Different types of beam end connectors with different geometry of the connected members are available, making it impossible to develop a generalized analytical model. Only very few theoretical models are available to evaluate the performance of the joints for some typical connectors. More often experimental evaluation and numerical studies are needed to predict the behaviour of every different type of connectors. In the present study eighteen experiments were conducted on a commercially available pallet rack connection by varying the most influencing parameters such as thickness of the column, depth of the connector and the depth of the beam. The main objective of this work is to quantify the beam to column joint, flexibility of commonly used pallet rack frame and to develop a general Frye-Morris type/three parameter power model type moment versus relative rotation relationship. A companion finite element shell model that simulates the experimental behaviour closely is developed using ABAQUS finite element software, which is also used for further parametric studies. Using the three major variables as size parameters, a Frye-Morris type of equation has been proposed. Some calibration studies have also been carried out. Using the ultimate moment capacity, initial connection stiffness and the shape parameter obtained, a three parameter power model has also been proposed to represent the moment-rotation behaviour of the boltless connections.