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991.
M. Alejandra Mazo Cristina Palencia Andrés Nistal Fausto Rubio Juan Rubio José Luis Oteo 《Journal of the European Ceramic Society》2012,32(12):3369-3378
Dense silicon oxycarbide glasses (SiOC) have been produced by spark plasma sintering (SPS) of SiOC powders. Raw powders were obtained by pyrolysis under nitrogen at 1100 °C of tetraethylorthosilcate/polydimethylsiloxane (TEOS/PDMS) hybrids. SPS experiments were carried out at 1300 and 1500 °C at 10 and 80 MPa and then were studied by chemical analysis, 29Si and 13C MAS NMR, ATR, Raman, XRD, FE-SEM, density, porosity, microhardness (Hv) and thermal conductivity (K). The SiOC materials are formed by SixOC4?x units within a silica matrix where silicon carbide and graphite nanodomains are also present. After the SPS treatment the silicon carbide crystallite size is close to 2.5 nm. At 1300 °C and 1500 °C the carbon nanodomain size is close to 3 nm and 2 nm, respectively. Hv values vary from 3.4 to 9.15 GPa, for 30% and 1% of porosity, respectively. Finally, K is always close to 1.38 W m?1 K?1. 相似文献
992.
A high-yielding fluorination of (triphos)Pt-R(+) has been achieved using an array of F(+) sources, with XeF(2) yielding R-F in minutes. The C-F coupling proved to be a stereoretentive process that proceeds via a concerted reductive elimination from a putative dicationic Pt(IV) center. The larger the steric congestion of the (triphos)Pt-C(sp3) (+) complexes, the more efficient the fluorination, seemingly a result of sterically accelerated C-F reductive elimination along with simultaneous deceleration of its competing processes (β-H elimination). 相似文献
993.
Susanne Leuchs Dr. Lasse Greiner Dominique Dechambre Dr. Lasse Greiner Prof. André Bardow 《化学,工程师,技术》2012,84(4):427-431
The illustrated literature series Asterix (and Obelix) is commonly known as entertainment and distraction, but behind that mask, case studies for chemical production in small medium enterprises and the crucial role of research and development can be discovered. The series rightly puts chemistry and chemical engineering at the heart of success and prosperity. Overall, the motives exemplified are of high relevance today for chemical industry. 相似文献
994.
995.
INTRODUCTIONMultibladerowcalculationscanbeperformedusingsteady3DNScodesprovidedthatassumptionsaremadeforthecouplingofbladerows.Thesocalledmixing--planeapproachneedsthetangentialaveragesofflowquantitiesattheinterfaceplanebetweenadjacentbladerows.Butth... 相似文献
996.
Catalytic use of zeolites in the Prins reaction of arylalkenes 总被引:1,自引:0,他引:1
María A. Aramendía Victoriano Borau César Jiménez José M. Marinas Francisco J. Romero Francisco J. Urbano 《Catalysis Letters》2001,73(2-4):203-206
The Prins reaction of various arylalkenes with paraformaldehyde on different zeolites as solid acid catalysts was studied. The main product of the reaction under the experimental conditions used was found to be the corresponding 1,3-dioxane. Of the catalysts tested, beta (75) zeolite proved the most active and selective in the Prins reaction of styrene, with a selectivity of 41.4% and a conversion of 95%. Other zeolites such as USY and, especially, ZSM-5, provided much lower yields. The reactions of other arylalkenes were found to be strongly influenced by the substituents on the double bond. 相似文献
997.
Recent accounts of accidents draw attention to “automation surprises” that arise in safety critical systems. An automation surprise can occur when a system behaves differently from the expectations of the operator. Interface mode changes are one class of such surprises that have significant impact on the safety of a dynamic interactive system. They may take place implicitly as a result of other system action. Formal specifications of interactive systems provide an opportunity to analyse problems that arise in such systems. In this paper we consider the role that an interactor based specification has as a partial model of an interactive system so that mode consequences can be checked early in the design process. We show how interactor specifications can be translated into the SMV model checker input language and how we can use such specifications in conjunction with the model checker to analyse potential for mode confusion in a realistic case. Our final aim is to develop a general purpose methodology for the automated analysis of interactive systems. This verification process can be useful in raising questions that have to be addressed in a broader context of analysis. 相似文献
998.
The efficiency of the UV photolysis, ozonation and their combination were compared in the decomposition of phenol using a self-devised experimental apparatus running under identical power conditions. The light source was a low-pressure mercury vapor lamp emitting at 185 nm (responsible for the formation of ozone) and 254 nm (responsible for the direct photolysis of ozone and phenol). The effect of flowrate of oxygen or air on the concentration of formed ozone in the gas phase, the effect of dissolved oxygen and pH on the transformation of phenol and formation of intermediates in aqueous solution were also investigated. 相似文献
999.
Mariel Monrroy Regis Teixeira Mendonça José Ruiz Jaime Baeza Juanita Freer 《木材化学与工艺学杂志》2013,33(2):150-163
Abstract Fourier transform near infrared (FT-NIR) associated with multivariate analysis was used to estimate glucan, xylan, 4-O-Methyl-α -D-glucuronic acid (MeGlcA) content, and pulp yield in kraft pulps of Eucalyptus globulus Labill. Several models were applied to correlate chemical composition in samples with the NIR spectral data by means of principal components regression (PCR) or partial least square (PLS) algorithms. Calibration models were built and validated by using all the spectral data and cross-validation methodology. The rc 2 values for the best calibration models for quantification of glucan, xylan, MeGlcA contents and pulp yield were between 0.71–0.92. The model was validated using a set of external samples. The amount of glucan (64–77%), xylan (12–18%), and MeGlcA (204–363 mmol kg pulp–1) in pulps were predicted with a root mean square error of prediction (RMSEP) of 0.91%, 0.46%, and 15.21% for glucan, xylan, and MeGlcA, respectively. Pulp yield (in the range of 46–70%) was also predicted with good accuracy with a RMSEP of 1.63%. These results suggest that glucan, xylan, MeGlcA composition, and pulp yield in kraft pulps of E. globulus can be adequately estimated by NIR spectroscopy for laboratory or industrial applications. NIR predictions can also provide useful and cost-effective tools for the rapid screening of large numbers of samples. 相似文献
1000.
Impact of ciprofloxacin,carbamazepine and ibuprofen on a membrane bioreactor system: Kinetic study and biodegradation capacity
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