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991.
992.
Modeling of a Methanol Synthesis Reactor for Storage of Renewable Energy and Conversion of CO2 – Comparison of Two Kinetic Models
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Johannes J. Meyer Pepe Tan Andreas Apfelbacher Robert Daschner Andreas Hornung 《化学工程与技术》2016,39(2):233-245
The storage of renewable energy over a long time period, via methanol synthesis, will become very important to reach a greenhouse gas‐free energy supply. A steady‐state methanol synthesis flowsheet, containing a 2D pseudo‐homogeneous reactor, flash, and recycle, is modeled in MATLAB. With the kinetic models of Graaf and Bussche & Froment, two frequently used kinetic models for conventional methanol synthesis are compared and evaluated for applicability regarding methanol synthesis from CO2/H2. The results are presented for different cases of synthesis gas compositions. Both kinetic models produce similar results when the system is limited by thermodynamic equilibrium. However, differences in reaction rates are observable from the reactor axial molar component profiles of the reaction products. 相似文献
993.
Olga Sambalova Emanuel Billeter Oguz Yildirim Andrea Sterzi Davide Bleiner Andreas Borgschulte 《International Journal of Hydrogen Energy》2021,46(5):3346-3353
External magnetic fields affect various electrochemical processes and can be used to enhance the efficiency of the electrochemical water splitting reaction. However, the driving forces behind this effect are poorly understood due to the analytical challenges of the available interface-sensitive techniques. Here, we present a set-up based on magneto- and electro-optical probing, which allows to juxtapose the magnetic properties of the electrode with the electrochemical current densities in situ at various applied potentials and magnetic fields. On the example of an archetypal hydrogen evolution catalyst, Pt (in a form of Co/Pt superlattice), we provide evidence that a magnetic field acts on the electrochemical double layer affecting the local concentration gradient of hydroxide ions, which simultaneously affects the magneto-optical and magnetocurrent response. 相似文献
994.
Industrial facilities usually need multiple energy subsystems, e.g., for heat, cold, and electric power supply. Normally, these energy subsystems are controlled locally and independent of each other. Coupling of the different subsystems can open up additional potential. Fraunhofer IISB has developed a demonstration and research platform for investigating the benefits of such sector coupling. A major precondition is to understand the energy flows in the system and establish an overall and flexible system control to realize the required algorithms for setting up an intelligent decentralized energy system. Major components of the overall system are various storages, which extend the degree of freedom for sector coupling and increase the effectiveness of the different subsystems. 相似文献
995.
996.
Norman Kauss Andreas Heyn Oliver Michael Michael Schymura Paul Rosemann 《工业材料与腐蚀》2021,72(10):1656-1667
Nickel-free high-nitrogen-alloyed stainless steels like the P2000 (X13CrMnMoN18-14-3) were developed to enhance the strength and corrosion resistance of austenitic stainless steels like 304 and 316 while keeping the typical high ductility. The mechanical and corrosive properties of P2000 were investigated and compared with 304 and 316 to highlight the application opportunities of this new alloy. The microstructure of the solution-annealed condition was characterised by electron backscatter diffraction and the mechanical properties were studied by uniaxial tensile tests, Charpy impact tests and hardness measurements. The passivation behaviour was analysed using the electrochemical potentiodynamic reactivation, whereas the pitting corrosion resistance was compared by pitting potentials and pitting temperatures. However, secondary thermal influences or suboptimal heat treatment can impair the corrosion resistance due to the precipitation of secondary phases and the resulting sensitisation. Thermodynamic calculations and artificial ageing treatment in the range of 500–900°C for up to 100 h were used to determine critical time–temperature parameters for sensitisation. The microstructure of the various aged states was evaluated by scanning electron microscopy and compared with the degrading corrosion resistance characterised by the KorroPad method. 相似文献
997.
Results of a study devoted to provide the pure enantiomers of isoflurane and desflurane from racemic mixtures using gas chromatography are presented. For that purpose, a cyclodextrin‐based selector described in earlier work was immobilized on porous glass beads. The adsorption isotherms were determined and applied to predict operating parameters which provide the highest possible productivity of the separation. The analysis included evaluation of the performance of larger columns applying simplifying scale‐up considerations. Using repetitive batches, the method can provide per day with a laboratory scale column approximately 1 g pure enantiomer. Selected model predictions were validated experimentally. 相似文献
998.
Wireless Networks - In this paper we model a situation where several wireless body sensor networks (WBSN) compete for occupation of a number of frequency channels. Each channel can host at most one... 相似文献
999.
1000.
Andreas P. Kyriacou Leonel Muinelo-Gallo Oriol Roca-Sagalés 《Papers in Regional Science》2015,94(1):89-107
In this paper we consider how government quality mediates the relationship between fiscal decentralization and regional disparities. Previous work has argued that fiscal decentralization has the potential to reduce income differences across regions but that this potential may not be realized because of governance problems associated with sub-national authorities. Our empirical evidence based on a sample of 24 OECD countries over the period 1984 to 2006 lends a measure of support to this idea. We find that fiscal decentralization promotes regional convergence in high government quality settings but, worryingly, it leads to wider regional disparities in countries with poor governance. 相似文献