Invariant ellipsoid method for minimization of unmatched disturbances effects in sliding mode control

A new sliding mode control design algorithm for a linear and a class of nonlinear quasi-Lipschitz disturbed system is presented. It is based on the appropriate selection of the sliding surface via invariant ellipsoid method. The designed control guarantees minimization of unmatched disturbances effects to system motions in a sliding mode. The obtained theoretical results are approved by numerical simulations.     

Ion-cyclotron resonance study of elementary stages of the catalytic oxidation of CO by N2O in the presence of VIA-group metal ions

Gas phase reactions of Mo⁺ and W⁺ ions with the molecules of various oxidants (NO, O₂, N₂O, CH₂O, C₂H₄O) were studied using ion cyclotron resonance. In oxidation with N₂O the mono-, di- and trioxide metal cations are formed consecutively. The trioxide MO₃ ⁺ ions of both metals react with CO to form CO₂ and MO₂ ⁺ ions. In this way, catalytic reaction N₂O + CO N₂ + CO₂ occurs in the gas phase with MoO₃ ⁺ /MoO₂ ⁺ and WO₃ ⁺/WO₂ ⁺ couples as catalysts. The rate constants have been measured for both stages of the catalytic cycle as well as for the stages of the catalyst preparation. Metal-oxygen bond energies were estimated for MoO_x ⁺ and WO_x ⁺ species with various x. The mechanism of CO oxidation with MoO_x ⁺ and WO_x ⁺ cations as catalysts in the gas phase is discussed in comparison with that for the oxidation over classical solid oxide catalysts.     

Investigation of thermo-mechanical contact between slider and bit patterned media

Contact between a slider and bit patterned media (BPM) is investigated using finite element analysis. The effect of contact conditions and material properties at the interface between slider and disk on plastic deformation and temperature is studied. In addition, the planarization of bit pattern media on temperature and plastic deformation is investigated for different filler materials. It is found that filler material results in reduction of plastic deformation and temperature.     

Compression-after-Impact Strength of Sandwich Panels with Core Crushing Damage

Compression-after-impact (CAI) strength of foam-cored sandwich panels with composite face sheets is investigated experimentally. The low-velocity impact by a semi-spherical (blunt) projectile is considered, producing a damage mainly in a form of core crushing accompanied by a permanent indentation (residual dent) in the face sheet. Instrumentation of the panels by strain gauges and digital speckle photography analysis are used to study the effect of damage on failure mechanisms in the panel. Residual dent growth inwards toward the mid-plane of a sandwich panel followed by a complete separation of the face sheet is identified as the failure mode. CAI strength of sandwich panels is shown to decrease with increasing impact damage size. Destructive sectioning of sandwich panels is used to characterise damage parameters and morphology for implementation in a finite element model. The finite element model that accounts for relevant details of impact damage morphology is developed and proposed for failure analysis and CAI strength predictions of damaged panels demonstrating a good correlation with experimental results.     

Simultaneous H control of a finite collection of linear plants with a single nonlinear digital controller

This paper considers the problem of simultaneous H^∞ control of a finite collection of linear time-invariant systems via a nonlinear digital output feedback controller. The main result is given in terms of the existence of suitable solutions to Riccati algebraic equations and a dynamic programming equation. Our main result shows that if the simultaneous H^∞ control problem for k linear time-invariant plants of orders n₁,n₂,…,n_k can be solved, then this problem can be solved via a nonlinear time-invariant controller of order nn₁+n₂++n_k.     

Static indentation and unloading response of sandwich beams

This paper deals with analysis of foam core sandwich beams subject to static indentation and subsequent unloading (removal of load). Sandwich beams are assumed continuously supported by a rigid platen to eliminate global bending. An analytical model is presented assuming an elastic-perfectly plastic compressive behaviour of the foam core. An elastic part of indentation response is described using the Winkler foundation model. Upon removal of the load, an elastic unloading response of the foam core is assumed. Also, finite element (FE) analysis of static indentation and unloading of sandwich beams is performed using the FE code ABAQUS. The foam core is modelled using the crushable foam material model. To obtain input data for the analytical model and to calibrate the crushable foam model in FE analysis, the response of the foam core is experimentally characterized in uniaxial compression, up to densification, with subsequent unloading and tension until tensile fracture. Both models can predict load–displacement response of sandwich beams under static indentation and a residual dent magnitude in the face sheet after unloading along with residual strain levels in the foam core at the unloaded equilibrium state. The analytical and FE analyses are experimentally verified through static indentation tests of composite sandwich beams with two different foam cores. The load–displacement response, size of a crushed core zone and the depth of a residual dent are measured in the testing. A digital speckle photography technique is also used in the indentation tests in order to measure the strain levels in the crushed core zone. The experimental results are in good agreement with the analytical and FE analyses.     

Self-assembled silver nanoislands formed on glass surface via out-diffusion for multiple usages in SERS applications

We demonstrate that silver nanoisland film self-assembled on the surface of silver-containing glass in the course of thermal processing in hydrogen is capable to detect 10⁻⁷ M concentration of rhodamine 6G in water using surface enhanced Raman spectroscopy (SERS) technique. The film can be multiply restored on the same glass substrate via annealing of the glass in hydrogen. We showed that the film can be self-assembled after as much as ten circles of the substrate cleaning followed by annealing. The proposed technique of the silver nanoisland film formation enables multiple usage of the same glass substrate in SERS experiments.     

One-point-plus for 5-DOF localization of vehicle-mounted omnidirectional camera in long-range motion

This paper proposes a method for localization of vehicle using one point plus an edge matching region of monocular vision in wide urban environments. The five degree of freedom (5-DoF) localization estimated by monocular omnidirectional camera improves the planar motion assumption in most of conventional researches. In recent year, the car-like motion model with planar motion is often investigated to reduce the requirements of correspondence until one point. However, in the real application of long-range motion in outdoor scene, the motion may not satisfy this condition. This leads to the inaccurate vehicle localization. In this proposed method, the car-like model is also utilized for 5-DoF localization however the requirements of correspondence are reduced to only one point plus an edge matching region which is much simpler than the conventional 5-point RANSAC. The cumulative errors of visual odometry are excluded by using global positioning system (GPS) correction under equation of maximum likelihood estimation in Extended Kalman Filter (EKF) frame work. The real application in hills and mountainous regions demonstrates the accuracy of vehicle localization using this proposed method.     

GPR55 Receptor Activation by the N-Acyl Dopamine Family Lipids Induces Apoptosis in Cancer Cells via the Nitric Oxide Synthase (nNOS) Over-Stimulation

GPR55 is a GPCR of the non-CB1/CB2 cannabinoid receptor family, which is activated by lysophosphatidylinositol (LPI) and stimulates the proliferation of cancer cells. Anandamide, a bioactive lipid endocannabinoid, acts as a biased agonist of GPR55 and induces cancer cell death, but is unstable and psychoactive. We hypothesized that other endocannabinoids and structurally similar compounds, which are more hydrolytically stable, could also induce cancer cell death via GPR55 activation. We chemically synthesized and tested a set of fatty acid amides and esters for cell death induction via GPR55 activation. The most active compounds appeared to be N-acyl dopamines, especially N-docosahexaenoyl dopamine (DHA-DA). Using a panel of cancer cell lines and a set of receptor and intracellular signal transduction machinery inhibitors together with cell viability, Ca²⁺, NO, ROS (reactive oxygen species) and gene expression measurement, we showed for the first time that for these compounds, the mechanism of cell death induction differed from that published for anandamide and included neuronal nitric oxide synthase (nNOS) overstimulation with concomitant oxidative stress induction. The combination of DHA-DA with LPI, which normally stimulates cancer proliferation and is increased in cancer setting, had an increased cytotoxicity for the cancer cells indicating a therapeutic potential.