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61.
Anatolii Ustinov Yury Falchenko Tatyana Melnichenko Andrey Shishkin Gennady Kharchenko Lidia Petrushinets 《Journal of Materials Processing Technology》2013,213(4):543-552
In the diffusion welding (DW) of difficult-to-deform materials (such as composites and intermetallics), the application of intermediate multilayer foils (MF), which have alternating layers of elements that form intermetallics, allows for production of a permanent joint under milder conditions. In this paper, the processes occurring in the joint zone (JZ) during DW of Al–5 wt.%Mg+27 wt.%Al2O3 composite material through the Al/Cu interlayer were studied. It was shown that, while heating of such a foil, phase transformations that are due to the reaction diffusion of elements, run in it. At MF heating under a continuously applied external load, the materials are plastically deformed. It is established that the intensity of foil plastic deformation at a specified load non-monotonically depends on temperature. It is shown that welding temperature is determined by the temperature at which MF can undergo superplastic flow under the impact of applied pressure. A mechanism of formation for a solid-phase joint of high-strength materials through interlayers based on the MF of intermetallic-forming elements is proposed. 相似文献
62.
The results of activity made in the framework of preparation of the experiment SAFIR (Single fin condensAtion: FIlm local measuRements) of European Space Agency are presented. First prototype of the test cell has been developed and tested. Confocal technique has been adopted for condensate film thickness measurements. Experiments on condensation of the liquid FC-72 have been carried out. Average heat transfer coefficient has been measured in the range of 880–1440 W/m2 K and compared to the Nusselt theory. 相似文献
63.
The over-phase control method of inverter multiphase (i.e. having number of phases more than four) AC linear drives is developed by the authors of this paper. Its application allows to improve considerably a number of the drive technical-and-economic characteristics (speed of response, reliability, mass-and-overall dimensions, etc.). This control method can be used not only in the field of electrical AC drives, but also in the systems for electromagnetic stirring of molten metals. In these systems the application of one of versions of the over-phase-control for multiphase inverter-fed linear stators allows to increase the intensity of electromagnetic stirring of molten metals by providing with continuous change of the quantity, space location, and configuration of the vortex areas in the metal mass during the process of the above-mentioned stirring. 相似文献
64.
Yuri V. Batygin Sergey F. Golovashchenko Andrey V. Gnatov 《Journal of Materials Processing Technology》2013,213(3):444-452
The paper is dedicated to the study of pulsed electromagnetic attraction processes which can deform ferromagnetic sheet metal materials such as low carbon steels using low frequency discharges. The analytical model based upon the solution of Maxwell equations explains that magnetic forces are prevailing over the Lorentz forces for low frequency discharges. For electromagnetic forming (EMF) processes employing ferromagnetic sheet metal blanks of low electrical conductivity with relatively slow electric discharges, the magnetic forces should be taken into account in order to achieve a correct representation of electromagnetic forces applied to the blank. An engineering estimate on the size of magneto-static forces and Lorentz-forces is the outcome of the analytical work. In addition to analytical work and validation of the proposed engineering estimate of attracting forces, a single turn coil is introduced which is more robust than previous designs with multiple frequencies and interrupted discharges. The simplified setup only requires a rather slow single frequency low voltage electric discharge which allows for using cheaper and longer life capacitors, substantially reduces the safety implications and also extends the life of the coil insulation. 相似文献
65.
We demonstrate the use of the Integrated Volume Method (IVM) to estimate activity coefficients of semi-volatile organic compounds pertinent to ambient/atmospheric aerosols in binary mixtures. We generate binary solution aerosols with different mole fractions of individual components; for each mixture, we measure total change in aerosol volume upon heating from 25 ○ C to 35 ○ C, with the aerosols being at equilibrium in both states. The change in aerosol volume, or in other words, the partitioning between the particle phase and the gas phase, is used to determine activity coefficients of the compounds as a function of their mole fraction in the mixture. We demonstrate this method using the following four model systems. System 1: adipic acid–pimelic acid, which illustrates polar organic–polar organic interactions. Non-ideal behavior was observed with activity coefficients around three at infinite dilution. System 2: adipic acid–dioctyl sebacate, which illustrates polar organic–non-polar organic interactions. The compounds in this experiment did not form a solution. System 3: adipic acid–ammonium sulfate, which illustrates polar organic–inorganic interactions. The compounds in this experiment did not form a solution. System 4: adipic acid–ambient extracts, which illustrates the potential use of the method to study partitioning behavior of individual components in a complex matrix approximating that of real ambient aerosol. The measured activity coefficients of adipic acid were less than unity for the tested range of mixing ratios, indicating suppression of volatility of this compound in ambient organic matrix. 相似文献
66.
Adsorption of methyl mercaptan on activated carbons 总被引:1,自引:0,他引:1
Activated carbons of different origins were studied as methyl mercaptan adsorbents in wet, dry, and oxidizing conditions. The materials were characterized using adsorption of nitrogen, Boehm titration, and thermal analysis. Investigation was focused on the feasibility of the removal of methyl mercaptan on activated carbons and on the role of surface chemistry and porosity in the adsorption/oxidation processes. The results showed relatively high capacities of carbons for removal of CH3SH. The amount adsorbed depends on the surface features. Methyl mercaptan, in general, is oxidized to disulfides, which, depending on the chemistry of the carbon surface, can be converted to sulfonic acid due to the presence of water and active radicals. 相似文献
67.
M. A. Turchanin 《Powder Metallurgy and Metal Ceramics》2006,45(5-6):272-278
Thermodynamic assessment of the Cu-V system was carried out using the CALPHAD method. The excess heat capacity of the liquid
phase was taken into account in the model of its excess Gibbs free energy. Excess thermodynamic properties of limiting solid
solutions were represented by regular solution models. A self-consistent set of thermodynamic parameters was obtained using
data on the mixing enthalpy and information on the phase equilibria. The thermodynamic properties of the phases and the phase
diagram along with its metastable extension were calculated using this set of parameters. The thermodynamic model of the system
was used in order to predict the composition limits of formation of supersaturated solid solutions prepared by highly nonequilibrium
methods of synthesis.
__________
Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 71–79, May–June, 2006. 相似文献
68.
This article deals with the development of learning methods for an intelligent control system for an autonomous mobile robot.
On the basis of visual servoing, an approach to learning the skill of tracking colored guidelines is proposed. This approach
utilizes a robust and adaptive image processing method to acquire features of the colored guidelines and convert them into
the controller input. The supervised learning procedure and the neural network controller are discussed. The method of obtaining
the learning data and training the neural network are described. Experimental results are presented at the end of the article.
This work was presented, in part, at the Sixth International Symposium on Artificial Life and Robotics, Tokyo, Japan, January
15–17, 2001 相似文献
69.
Tapered fiber bundles are often used to combine the output power of several semiconductor lasers into a multimode optical fiber for the purpose of pumping fiber lasers and amplifiers. It is generally recognized that the brightness of such combiners does not exceed the brightness of the individual input fibers. We report that the brightness of the tapered fibers (and fiber bundles) depends on both the taper ratio and the mode-filling properties of the beams launched into the individual fibers. Brightness, therefore, can be increased by selection of sources that fill a small fraction of the input fiber's modal capacity. As proof of concept, we present the results of measurements on tapered fiber-bundle combiners having a low-output étendue. Under low mode-filling conditions per input multimode fiber (i.e., fraction of filled modes < or =0.29), we report brightness enhancements of 8.0 dB for 19 x 1 bundles, 6.7 dB for 7 x 1 bundles, and 4.0 dB for 3 x 1 combiners. Our measured coupling efficiency variations of approximately 1%-2% among the various fibers in a given bundle confirm the uniformity and quality of the fabricated devices. 相似文献
70.
Kudryashova Elena V.; Artemova Tatiana M.; Vinogradov Alexei A.; Gladilin Alexander K.; Mozhaev Vadim V.; Levashov Andrey V. 《Protein engineering, design & selection : PEDS》2003,16(4):303-309
Formation of enzymeoligoamine complexes was suggestedas an approach to obtain biocatalysts with enhanced resistancetowards inactivation in waterorganic media. Complex formationresults in broadening (by 2040% v/v ethanol) of the rangeof cosolvent concentrations where the enzyme retains its catalyticactivity (stabilization effect). At moderate cosolvent concentrations(2040% v/v) complex formation activates the enzyme (by36 times). The magnitude of activation and stabilizationeffects increases with the number of possible electrostaticcontacts between the protein surface and the molecules of oligoamines(OA). Circular dichroism spectra in the far-UV region show thatcomplex formation stabilizes protein conformation and preventsaggregation in waterorganic solvent mixtures. Two populationsof the complexes with different thermodynamic stabilities werefound in -chymotrypsin (CT)OA systems depending on theCT/OA ratio. The average dissociation constants and stoichiometriesof both low- and high-affinity populations of the complexeswere estimated. It appears that it is the low-affinity siteson the CT surface that are responsible for the activation effect. 相似文献