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471.
Graham MC Oliver IW MacKenzie AB Ellam RM Farmer JG 《The Science of the total environment》2011,409(10):1854-1866
Uranium associations with colloidal and truly dissolved soil porewater components from two Ministry of Defence Firing Ranges in the UK were investigated. Porewater samples from 2-cm depth intervals for three soil cores from each of the Dundrennan and Eskmeals ranges were fractionated using centrifugal ultrafiltration (UF) and gel electrophoresis (GE). Soil porewaters from a transect running downslope from the Dundrennan firing area towards a stream (Dunrod Burn) were examined similarly. Uranium concentrations and isotopic composition were determined using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) and Multi-Collector-Inductively Coupled Plasma-Mass Spectrometry (MC-ICP-MS), respectively.The soils at Dundrennan were Fe- and Al-rich clay-loam soils whilst at Eskmeals, they were Fe- and Al-poor sandy soils; both, however, had similar organic matter contents due to the presence of a near-surface peaty layer at Eskmeals. These compositional features influenced the porewater composition and indeed the associations of U (and DU). In general, at Dundrennan, U was split between large (100 kDa-0.2 μm) and small (3-30 kDa) organic colloids whilst at Eskmeals, U was mainly in the small colloidal and truly dissolved fractions. Especially below 10 cm depth, association with large Fe/Al/organic colloids was considered to be a precursor to the removal of U from the Dundrennan porewaters to the solid phase. In contrast, the association of U with small organic colloids was largely responsible for inhibiting attenuation in the Eskmeals soils.Lateral migration of U (and DU) through near-surface Dundrennan soils will involve both large and small colloids but, at depth, transport of the smaller amounts of U remaining in the porewaters may involve large colloids only. For one of the Dundrennan cores the importance of redox-related processes for the re-mobilisation of DU was also indicated as MnIV reduction resulted in the release of both MnII and UVI into the truly dissolved phase. 相似文献
472.
When building fires occur in large, open compartments they rarely burn uniformly across an entire floor plate of a structure. Instead, they tend to travel, igniting fuel in their path and burning it out as they move to the next fuel package. Current structural fire design methods do not account for these types of fires. This paper applies a novel methodology for defining a family of possible heating regimes to a framed concrete structure using the concept of travelling fires. A finite-element model of a generic concrete structure is used to study the impact of the family of fires; both relative to one another and in comparison to the conventional codified temperature-time curves. It is found that travelling fires have a significant impact on the performance of the structure and that the current design approaches cannot be assumed to be conservative. Further, it is found that a travelling fire of approximately 25% of the floor plate in size is the most severe in terms of structural response. It is concluded that the new approach is simple to implement, provides more realistic fire scenarios, and is more conservative than current design methods. 相似文献
473.
Christopher Massimo Magazzeni Rory Rose Chris Gearhart Jicheng Gong Angus J. Wilkinson 《Fatigue & Fracture of Engineering Materials & Structures》2023,46(1):228-243
A statistical framework is presented enabling optimal sampling and analysis of constant life fatigue data. Protocols using Bayesian maximum entropy sampling are built based on conventional staircase and stress step methods, reducing the requirement of prior knowledge for data collection. The Bayesian Staircase method shows improved parameter estimation efficiency, and the Bayesian Stress Step method shows equal accuracy to the standard method at larger step size allowing experimentalists to lessen concerns of loading history. Statistical methods for determining model suitability are shown, highlighting the influence of protocol. Experimental validation is performed, showing the applicability of the methods in laboratory testing. 相似文献
474.
Angus Gaudry Ryan Li Vicky Mak-Hau 《International Journal of Satellite Communications and Networking》2023,41(6):515-538
Modern satellite communication systems are required to serve heterogeneous and geographically dispersed user demands with limited resources. In this paper, we investigate methodologies for dynamic resource allocation in Geosynchronous Earth Orbit (GEO) High-throughput Satellite (HTS) systems. We designed three solution approaches FlexBeamOpt v1 , FlexBeamOpt v2 , and FlexBeamOpt v3 , each as a hybridization of custom heuristics, integer linear programming, and/or constraint programming. We test the performance of the three approaches on 12 test instances that vary in user distribution (realistic, random, and clustered), user numbers (500 vs. 5000 users), and demand distribution (uniform vs. random). We observed that FlexBeamOpt v1 consistently outperformed FlexBeamOpt v2 and FlexBeamOpt v3 in terms of demand coverage and number of users covered for realistic and random user distribution test instances but at the cost of computation time. FlexBeamOpt v3 is the fastest in these instances. For clustered user distribution instances, FlexBeamOpt v3 performed better in terms of demand coverage and number of users covered, at the cost of using more beams. For these test instances, FlexBeamOpt v2 is the fastest in terms of computation time while providing a comparable solution quality. 相似文献