Integrated sampling and analytical approach for common groundwater dissolved gases

A novel passive gas diffusion sampler (PGDS) combines sampling, storage and direct injection into a single gas chromatograph (GC). The sampler has a 4.5 mL internal volume when deployed, is easy to operate, and eliminates sample-partitioning. The associated GC method analyzes for a large, dynamic sampling range from a single, small volume injection. Dissolved gases were separated on parallel Rt-Molsieve 5A and Rt-Q-PLOT columns and eluted solutes were quantified using a pulse discharge helium ionization detector (PD-HID). The combined sampling and analytical method appears to be less prone to systematic bias than conventional sampling and headspace partitioning and analysis. Total dissolved gas pressure used in tandem with the PGDS improved the accuracy of dissolved gas concentrations. The incorporation of routine measurements of dissolved biogeochemical and permanent gases into groundwater investigations will provide increased insight into chemical and biological processes in groundwater and improve chemical mass balance accuracy.     

Subirrigation Systems to Minimize Nitrate Leaching

Nitrate leaching from corn production systems and the subsequent contamination of ground and surface waters is a major environmental problem. In field plots 75 m long by 15 m wide, the writers tested the hypothesis that subirrigation and intercropping will reduce leaching losses from cultivated corn and minimize water pollution. Nitrate leaching under subirrigation at a depth of either 0.7 m or 0.8 m below the soil surface was compared with leaching under free drainage. The cropping systems investigated were corn (Zea mays L.) monoculture and corn intercropped with annual Italian ryegrass (Lolium multiflorum Lam. cv. Barmultra). The effects of three fertilizer application rates (0, 180, and 270 kg N ha?1) on leaching were investigated in the freely drained plots. The greatest annual loss of NO3?-N in tile drainage water (21.9 kg N ha?1) occurred in freely draining, monocropped plots fertilized with 270 kg N ha?1. Monocropped plots fertilized with 270 kg N ha?1, with subirrigation at 0.7 m depth, resulted in annual nitrate losses into tile drainage of 6.6 kg N ha?1, 70% less than under free drainage. Annual soil denitrification rates (60 kg N ha?1) with subirrigation at 0.7 m were about three-fold greater than under free drainage. Intercropping under free drainage resulted in a 50% reduction in tile drainage loss of NO3?-N compared with monocropping. Off-season (November 1, 1993, to May 31, 1994) tile drainage losses of NO3?-N (7.8 kg N ha?1) from freely draining monocropped plots accounted for 30% of the annual tile drainage losses.     

Creep of CaO/SiO2-containing MgO refractories

Compressive creep of five commercially-available brands of CaO/SiO2-containing MgO refractories was measured over a temperature range of 1400-1550°C and compressive stresses of 0.10–0.30 MPa. All brands had a MgO content greater than 96 wt%, a CaO/SiO2 wt% ratio equal to or greater than 1.9, and a firing temperature greater than 1535°C. The more creep resistant brands were observed to have a combination of: (1) a larger average grain size and wider grain size distribution, (2) a low iron content, and (3) an absence of CaO-MgO-SiO2 compounds. Creep-stress exponents for three of the five brands indicated their creep was rate-controlled by diffusion, and their activation energy values indicated that creep was accommodated by grain boundary sliding through viscous flow of the calcium silicate grain-boundary phase. Two brands exhibited dramatic time-hardening behavior which resulted in their creep not being well-represented by the power-law creep formulation. The observed attributes among the brands were combined and a hypothetical CaO/SiO2-containing MgO refractory is proposed.     

Baseline layout and design of a 0.8 GW reference wind farm in the North Sea

The paper presents a model of a reference wind farm. The model considers the wind and wave climatologies for a specific site from which two different wind farm layouts are derived. These layouts are examined through the effective wake‐enhanced turbulence intensity at the hub height for a given climatology, and a simple model for the influence on capital expenditures is proposed. An electrical design is presented, the cable losses are calculated and the energy yield is determined. An operation and maintenance model is established, and the associated operating expenditure is obtained. All of the models are then summarized in terms of a levelized cost of energy using a numerical simulation tool, which allows the layouts to be compared. The data and models are freely available online for others to use and may serve as a baseline for benchmarking and allow researchers to compare and discuss their results. Copyright © 2017 John Wiley & Sons, Ltd.     

Discrepancies between knowledge and practice of childhood motor vehicle occupant safety in Nova Scotia—A population-based study

Objectives

To determine discrepancies between knowledge and practice of childhood motor vehicle restraints (CMVRs) and vehicle seating position amongst parents within the province of Nova Scotia.

Design

Random telephone survey.

Setting

The Canadian province of Nova Scotia.

Subjects

Four hundred and twenty-six households with at least one child under the age of 12 years, totaling 723 children.

Main outcome measures

The proportion of parents whose children who should be in a specific stage of CMVR and sitting in the rear seat of the vehicle, and who demonstrate correct knowledge of that restraint system and seating position, yet do not use that restraint system/seating position for their child (demonstrate practice discrepant from their knowledge).

Results

Awareness of what restraint system to use is good (>80%). However, knowledge of when it is safe to graduate to the next stage is low (30–55%), most marked for when to use a seatbelt alone. Awareness of the importance of sitting in the rear seat of a vehicle was universal. Discrepancies between knowledge and practice were most marked with booster seats and rear-seating of older children. Factors influencing incorrect practice (prematurely graduated to a higher-level restraint system than what is appropriate for age and weight) included lower household income, caregiver education level, and knowledge of when to graduate from forward-facing car seats and booster seats. Incorrect practice was also more commonly observed amongst children of weight and/or age approaching (but not yet reaching) recommended graduation parameters of the appropriate CMVR.

Conclusions

Discrepancies between knowledge and practice are evident through all stages of CMVRs, but most marked with booster seats. The roles of lower socioeconomic status and gaps in CMVR legislation, in influencing discrepant practice, must be acknowledged and suggest the need for targeted education concurrent with development of comprehensive all-stages CMVR policies.     

XPS investigation of a CdS-based photoresistor under working conditions: operando-XPS

A noncontact chemical and electrical measurement X-ray photoelectron spectroscopy (XPS) technique is performed to investigate a CdS-based photoresistor during its operation. The main objective of the technique is to trace chemical- and location-specified surface potential variations as shifts of the XPS Cd 3d(5/2) peak position without and under photoillumination with four different lasers. The system is also modeled to extract electrical information. By analyzing the measured potential variations with this model, location-dependent resistance values are represented (i) two dimensionally for line scans and (ii) three dimensionally for areal measurements. In both cases, one of the dimensions is the binding energy. The main advantage of the technique is its ability to assess an element-specific surface electrical potential of a device under operation based on the energy deviation of core level peaks in surface domains. Detection of the variations in electrical potentials and especially their responses to the energy of the illuminating source in operando, is also shown to be capable of detecting, locating, and identifying the chemical nature of structural and other types of defects.     

How does target duration affect object substitution masking?

Object substitution masking (OSM) is typically studied using a brief search display. The target item may be indicated by a cue/mask surrounding but not overlapping it. Report of the target is reduced when mask offset trails target offset rather than being simultaneous with it. We report 5 experiments investigating whether OSM can be obtained if the search display is on view for a period of up to 830 ms but cueing of the target location is delayed. The question of interest is whether OSM must reflect the initial response of the visual system to target onset or whether it can arise in other ways, possibly during the transition from a pre-attentive representation of the target item to an attentional representation of it. Our results show that OSM decreases in strength as target duration increases. An explanation is suggested in terms of the object individuation hypothesis (Lleras & Moore, 2003). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Assessing the utility of environmental factors and objectives in environmental impact assessment practice: Western Australian insights

Environmental factors and objectives are formally identified during the scoping stage of environmental impact assessment (EIA) to structure and focus individual assessments. Environmental factors are broad components of the environment, while objectives set the desired outcome for a specific factor. This research assesses the utility of environmental factors and objectives in EIA practice based upon a combination of literature review and interviews with 21 EIA practitioners from Western Australia. Further to providing focus and structure for EIA, practitioners also use environmental factors and objectives for decision-making throughout the process. The majority of practitioners also note that factors and objectives are value adding and useful to their EIA practice. Due to their inherent subjective natures, interviewees noted a lack of consistency regarding how to meet the objectives and challenges in determining the significance of impacts on a factor. Identified opportunities to enhance use of objectives and factors in EIA included provision of more guidance, especially criteria or standards to apply and improve knowledge sharing between EIA stakeholders.     

Power plant maintenance scheduling using ant colony optimization: an improved formulation

It is common practice in the hydropower industry to either shorten the maintenance duration or to postpone maintenance tasks in a hydropower system when there is expected unserved energy based on current water storage levels and forecast storage inflows. It is therefore essential that a maintenance scheduling optimizer can incorporate the options of shortening the maintenance duration and/or deferring maintenance tasks in the search for practical maintenance schedules. In this article, an improved ant colony optimization-power plant maintenance scheduling optimization (ACO-PPMSO) formulation that considers such options in the optimization process is introduced. As a result, both the optimum commencement time and the optimum outage duration are determined for each of the maintenance tasks that need to be scheduled. In addition, a local search strategy is presented in this article to boost the robustness of the algorithm. When tested on a five-station hydropower system problem, the improved formulation is shown to be capable of allowing shortening of maintenance duration in the event of expected demand shortfalls. In addition, the new local search strategy is also shown to have significantly improved the optimization ability of the ACO-PPMSO algorithm.