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991.
The extraction of Te(IV) from aqueous solutions containing various ligands was studied using various inert organic diluents
and other solvents. The extraction was carried out from solutions of various mineral (HCl, HBr, HI, HNO3) and organic (citric, oxalic) acids of various concentrations. The organic phase was an inert diluent (cyclohexane, CCl4, chloroform, benzene, p-xylene, toluene, nitrobenzene) or a solution of 20 vol % Aliquat-336, 20 vol % trioctylamine, or 30 vol % TBP in p-xylene. A correlation between the distribution of Te(IV) and some physicochemical properties of the diluents and the possibility
of extraction separation radioactive Te isotopes and their daughters, i.e., radioactive I isotopes, were examined. In most
cases, the Te(IV) distribution ratio decreases in the order nitrobenzene > CHCl3 > CCl4 > p-xylene > benzene > toluene > cyclohexane.
Published in Russian in Radiokhimiya, 2007, Vol. 49, No. 4, pp. 353–358.
The text was submitted by the authors in English.
An erratum to this article is available at . 相似文献
992.
In this paper, we present a general method to calculate the inverse and direct dynamic models of parallel robots. The models
are expressed in a closed form by a single equation in which all the elements needed are expressed. The solution is given
in terms of the dynamic models of the legs, the dynamics of the platform and some Jacobian matrices. The proposed method is
applied in this paper on two parallel robots with different structures.
Categories (2), (3). 相似文献
993.
A new chromosome encoding method, named fuzzy coding, is proposed for representing real number parameters in a genetic algorithm. Fuzzy coding provides the value of a parameter on the basis of the optimum number of selected fuzzy sets and their effectiveness in terms of degree of membership. Thus, it represents the knowledge associated with each parameter and is an indirect method of encoding compared with alternatives, where the parameters are directly represented in the encoding. Fuzzy coding is described and compared with conventional binary coding, gray coding, and floating-point coding. Two test examples, along with neural identification of a nonlinear pH process from experimental data, are studied. It is shown that fuzzy coding is better than the conventional methods and is effective for parameter optimization in problems where the search space is complicated. 相似文献
994.
Finite sample properties of estimators of spatial autoregressive models with autoregressive disturbances 总被引:1,自引:0,他引:1
The article investigates the finite sample properties of estimators for spatial autoregressive models where the disturbance
terms may follow a spatial autoregressive process. In particular we investigate the finite sample behavior of the feasible
generalized spatial two-stage least squares (FGS2SLS) estimator introduced by Kelejian and Prucha (1998), the maximum likelihood
(ML) estimator, as well as that of several other estimators. We find that the FGS2SLS estimator is virtually as efficient
as the ML estimator. This is important because the ML estimator is computationally burdensome, and may even be forbidding
in large samples, while the FGS2SLS estimator remains computationally feasible in large samples.
Received: 20 January 2001 / Accepted: 31 August 2001 相似文献
995.
996.
997.
998.
The basic physicochemical principles of preparation of emulsion fuel compositions based on heavy and extra-heavy crude cuts
were analyzed with consideration of the nature and content of the phases constituting the emulsion, type of chemical additives
— emulsifiers and stabilizers, and type of equipment for production of emulsion fuels.
__________
Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 51–56, September–October, 2007. 相似文献
999.
Martín A. Rodríguez Ricardo M. Carranza Raúl B. Rebak 《Metallurgical and Materials Transactions A》2005,36(5):1179-1185
Alloy 22 (N06022) is the current candidate alloy used to fabricate the external wall of the high-level nuclear waste containers
for the Yucca Mountain repository. It was of interest to study and compare the general and localized corrosion susceptibility
of Alloy 22 in fluoride and chloride solutions at 90 °C. Standard electrochemical tests such as cyclic potentiodynamic polarization,
amperometry, and electrochemical impedance spectroscopy were used. Studied variables included the solution pH and the alloy
microstructure (thermal aging). Results show that Alloy 22 is highly resistant to general corrosion in all the solutions tested.
Thermal aging is not detrimental and even seems to be slightly beneficial for general corrosion at the higher solution pHs.
Pitting corrosion was never observed. Crevice corrosion was found only for high chloride-containing solutions after anodic
polarization. The presence of fluoride ions together with chloride ions seems to increase the susceptibility of Alloy 22 to
crevice corrosion compared to pure chloride solutions.
This article is based on a presentation made in the symposium “Effect of Processing on Materials Properties for Nuclear Waste
Disposition,” November 10–11, 2003, at the TMS Fall meeting in Chicago, Illinois, under the joint auspices of the TMS Corrosion
and Environmental Effects and Nuclear Materials Committees. 相似文献
1000.
Total simulation model of the thermo-mechanical process in shape rolling of steel rods 总被引:2,自引:0,他引:2
The production of steel reinforcing bars for civil engineering is investigated by means of FEM-simulation. An integrated system for computing appropriate thermo-mechanical parameters of the rolling process is proposed. Generalized plane strain approach and coupled thermal-mechanical solution are applied. The microstructural model combines both the effect of the recrystallization mechanisms (static, dynamic and metadynamic) upon the austenite grain forming in hot rolling and that of phase transformation upon the final microstructure. The phases are created during interrupted below the temperature of martensite transition cooling. Thus a typical industrial process for thermo-mechanical strengthening of reinforcing bars, known as Tempcor-process is considered. Computational results are validated to experimental measured mechanical properties of the steel. By means of computer simulation the system can perform different solutions, giving the possibility to obtain a reasonable choice of different thermo-mechanical rolling conditions. 相似文献