Improvement of anode oxidation reaction of a fuel cell using ammonium formate with Pt‐Ir catalysis

We have attempted to develop high‐performance and safe fuel cells by using ammonium formate as a solid (powder) fuel. This solid fuel has the potential of safer transportability than liquid fuels such as methanol from the viewpoint of toxicity and flammability. In order to make use of some of the advantages of ammonium formate, we investigated the oxidation characteristics of ammonium formate with respect to a Pt electrode. Cyclic voltammograms indicate that ammonium formate has high oxidation activity with respect to a Pt electrode. We have also found that the oxidation of ammonium formate can be improved by the addition of Ir to Pt catalysts. It is highly likely that ammonium formate will be useful as a solid (powder) fuel for polymer electrolyte membrane (PEM) fuel cells. This new fuel will promote the development of safe fuel cells for PEM. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 174(4): 45–50, 2011; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.21043     

Simulation on contact between the droplet and the slider at head-disk interface based on water-hammer pressure model

To understand the cause of read/write error due to lube accumulation, a model to simulate the slider’s response to the contact impact, which can occur between a lubricant droplet on the disk and a slider, was developed. The contact impact model is based on the water-hammer pressure model with an additional damping force, where the wave-shock pressure is assumed to function as the contact pressure, and the damping force defines the damping characteristics of the impact which are due to the lubricant’s high viscosity and squeeze between the droplet and slider contact area along the slider local velocity direction. The transient contact impact is dependent on lube droplet density, disk velocity, pitch angle of the slider, and contact area between the droplet and the slider. The measured read/write signal jump due to lube pickup can be explained by the simulation results. This modeling and simulation are helpful to us in understanding the read/write signal loss due to a lube droplet at head disk interface.     

Electrooptic planar deflector switches with thin-film PLZT active elements

First prototypes of electrooptic (EO) planar deflector switches (PDSs) are fabricated with hybrid integration on Si substrates. Planar optical modules, made in silica-on-silicon technology, consist of input and output (I/O) waveguide microlenses facing each other and slab waveguides in between. The modules interconnect the I/O fibers with laterally collimated light beams less than 400 /spl mu/m in width at distances up to 100 mm with losses lower than 3 dB. Thin lead lanthanum zirconium titanate (PLZT) films with prism-shaped electrodes grown on SrTiO/sub 3/ substrates form the deflector elements. The PLZT films are more than 10 /spl mu/m thick with EO coefficients about 40 pm/V. The deflector assembly technology provides chip vertical positioning accuracy better than 1 /spl mu/m. The deflector chips are attached to the optical substrates with thermo-compression flip-chip bonding. The optical power losses of the modules with test silica chips can be as low as 3.6 dB. However, the lowest module losses achieved with PLZT are about 10 dB. The channel-to-channel switching operations are demonstrated at about 40 V and switching times less than 500 ns.     

Resonance phenomena of a single water droplet located on a hydrophobic sheet under AC electric field

Resonance vibration of a water droplet located on the surface of a hydrophobic sheet under an AC electric field was investigated experimentally. In order to confirm the effect of the surface property of hydrophobic materials on the resonance phenomena of a water droplet, three kinds of hydrophobic materials, silicone rubber (SR), polytetrafluoroethylene (PTFE), and polydimethylsiloxane-grafted fluoropolymer (PGF) sheet were used. A single water droplet with a volume ranging from 3 to 30 /spl mu/L was placed between parallel electrodes, where a tangential electric field was formed along the surface of the hydrophobic sheet. A water droplet under the AC field vibrates strongly only at a particular frequency range. The resonance frequency, when the water droplet vibrates, decreases with increasing the volume of the water droplet. The resonance frequency on the SR sheet is lower than that on the PTFE and the PGF sheet. The resonance frequency and the magnitude of the deformation of the water droplet depend on the surface properties of the hydrophobic material.     

Novel episomal vectors and a highly efficient transformation procedure for the fission yeast Schizosaccharomyces japonicus

Schizosaccharomyces japonicus is a fission yeast for which new genetic tools have recently been developed. Here, we report novel plasmid vectors with high transformation efficiency and an electroporation method for Sz. japonicus. We isolated 44 replicating segments from 12 166 transformants of Sz. japonicus genomic fragments and found a chromosomal fragment, RS1, as a new replicating sequence that conferred high transformation activity to Sz. japonicus cells. This sequence was cloned into a pUC19 vector with ura4⁺ of Sz. pombe (pSJU11) or the kan gene on the kanMX6 module (pSJK11) as selection markers. These plasmids transformed Sz. japonicus cells in the early‐log phase by electroporation at a frequency of 123 cfu/µg for pSJK11 and 301 cfu/µg for pSJU11, which were higher than previously reported autonomously replicating sequences. Although a portion of plasmids remained in host cells by integration into the chromosome via RS1 segment, the plasmids could be recovered from transformants. The plasmid copy number was estimated to be 1.88 copies per cell by Southern blot analysis using a Sz. pombe ura4⁺ probe. The plasmid containing ade6⁺ suppressed the auxotrophic growth of the ade6‐domE mutant, indicating that the plasmid would be useful for suppressor screening and complementation assays in Sz. japonicus. Furthermore, pSJU11 transformed Sz. pombe cells with the same frequency as the pREP2 plasmid. This study is a report to demonstrate practical use of episomal plasmid vectors for genetic research in Sz. japonicus. RS1 has been submitted to the DDBJ/EMBL/GenBank database (Accession No. AB547343). Copyright © 2010 John Wiley & Sons, Ltd.     

Recent advances in phosphorylation of food proteins: A review

Phosphorylation is a useful method for improving the functional properties of food proteins. In this article, various methods of phosphorylation are reviewed. Dry-heating phosphorylation, a method developed recently, is also introduced. Some characteristics of phosphate groups are involved, and the effects of phosphorylation on the structural changes, the functional properties, and the physiological functions in vitro of food proteins, are discussed. The types of phosphate linkages and the phosphopeptides from phosphorylated proteins are identified. The molten (partially unfolded) conformations of food proteins formed by phosphorylation are discussed. The phosphorylation of food proteins improved a number of functional properties, including heat stability, emulsifying properties, foaming properties, gelling properties, water absorption capacity, oil absorption capacity, and calcium phosphate-solubilizing ability. In vitro physiological function studies of protein (α-lactoalbumin) indicated that the digestibility (ovalbumin) was improved and the inflammatory response (α-lactoalbumin) was suppressed by phosphorylation. Experiments with animals are necessary to evaluate the toxicity and physiological functions of phosphorylated proteins.     

Effects of Winding Attachment Positions on Output Characteristics of Flux‐Modulating Synchronous Machines

The flux‐modulating synchronous machine (FMSM) is a new type of multipole SM with nonoverlapping concentrated armature and field windings on the stator. This paper compares the output characteristics of two FMSMs through finite element analysis (FEA) and experiments. In both of the FMSMs, the attachment positions of the armature and field windings are swapped. To determine the reason for the discrepancies in their output characteristics, unsaturated inductances were calculated using a d‐‐q equivalent circuit. In addition, the calculated results of the inductances were confirmed through a visualization of the leakage fluxes using FEA. The results of the study show that the synchronous inductance can be reduced by attaching the armature winding to the air‐gap side of the stator teeth and that the reduction leads to an increase in output power.     

取代聚苯乙炔环状三聚体的合成

以对溴苯酚为原料,经四步反应合成一种取代苯乙炔单体4-乙炔基-(2,6)二羟甲基-1-十二烷基酚醚。利用手性的铑催化剂引发聚合,得到高分子量的螺旋聚合物,通过GPC和CD对分子量和螺旋结构进行表征。最后通过光环化反应高效合成了环状三聚体,并通过1HNMR和GPC确认其化合物结构。     

Evaluation of Lysophospholipid Measurement in Cerebrospinal Fluid Samples using Liquid Chromatography–Tandem Mass Spectrometry

A quantification system for lysophospholipids (lysoPL) was developed, especially for blood samples, using liquid chromatography–tandem mass spectrometry (LC–MS/MS). However, the lysoPL measurement in cerebrospinal fluid (CSF) has not been validated. Therefore, the present study aimed to validate the lysoPL measurement using CSF samples and to elucidate the possible clinical significance of the lysoPL measurement in CSF. For the validation, we observed a good precision and linearity in a sample with high lysoPL levels. The concentrations of lysoPL changed after incubation but the changes were smaller than those observed for serum samples. Moreover, we observed that the CSF levels of 16:0, 18:0 lysophosphatidylcholine, and 18:0, 18:1, and 20:4 lysophosphatidic acid were significantly higher in subjects with central nervous system invasion caused by hematological malignancies or carcinoma than in subjects with no abnormal CSF test results. In conclusion, an LC–MS/MS quantification system for lysoPL in CSF might be useful and could be applied to clinical laboratory testing.     

Oxidation mechanisms of SiC-fiber–reinforced Si eutectic alloy matrix composites at elevated temperatures

SiC-fiber–reinforced binary Si eutectic alloy composites have been developed for aerospace applications using the melt infiltration method. In this study, the oxidation mechanisms of various binary Si eutectic alloys were evaluated at elevated temperatures. We suggest that the oxidation resistance of eutectic alloys could be predicted using the Gibbs energy change for the oxidation reaction. Based on these calculations, eutectic alloys of Si-16at%Ti, Si-17at%Cr, Si-22at%Co, Si-38at%Co, and Si-27at%Fe were prepared. These alloys produced uniform SiO₂ layers and showed the same oxidation resistance as Si at 1000°C under humid conditions. Therefore, SiC composites using Si alloys with excellent oxidation resistance can be predicted using thermodynamic calculations.