Superconductivity and Unusual Magnetic Features in Amorphous Carbon and in Other Unrelated Materials

Traces of superconductivity (SC) were observed in three different inhomogeneous sulfur-doped amorphous carbon (a-C) systems: (i) in old commercial powder, (ii) in fabricated (by pyrolytic decomposition of sucrose) powder, and (iii) in a-C thin films. (i) The commercial a-C powder contains 0.21 at% sulfur and reveals traces of two superconducting phases around T _C ?34 and T _C～65 K. (ii) The fabricated a-C powder is diamagnetic but not superconducting. However, mixtures of this powder with sulfur (a-CS) which were heated to 250 °C also show traces of SC up to T _C～42 K. (iii) Non-superconducting a-C thin films were grown by electron-beam induced deposition. SC at T _C～34 K emerged only after heat treatment with sulfur. It is proposed that the high SC states in a-CS (T _C～65 K at ambient pressure) and in H₃S materials (T _C = 203 K under >200 GPa) has the same origin. In both sulfur-containing systems, SC is induced by the interaction between electrons and the high frequencies of low mass atom (H or C) vibrations a-CS products obtained by heating commercial and fabricated a-C powders at 400 °C show unusual magnetic features: (a) pronounced irreversible peaks around 55–80 K which appear in the first zero-field-cooled (ZFC) runs only. This temperature range is close to the highest T _C observed. (b) These peaks are totally suppressed in the second ZFC sweeps measured a few minutes later. (c) The peaks reappear after 18 months. (d) Around the peak position, the field-cooled (FC) curves cross the ZFC plots (ZFC > FC). All these phenomena are intrinsic properties of the amorphous carbon materials and were not observed in crystalline graphite. The ZFC > FC state was also observed in chiral-based magnetic memory device and unexpectedly in the liver taken from a patient with mantle cell lymphoma. This peculiarity will be discussed.     

Analysis of Reflectance Properties in 1D Photonic Crystal Containing Metamaterial and High-Temperature Superconductor

In the present work, reflectance properties of one-dimensional photonic crystal (1D PC) containing a metamaterial and high-temperature superconductor have been investigated theoretically and analyzed. The reflectance/transmittance spectrum of the proposed structure is obtained by using the characteristic or transfer-matrix method (TMM). The results show that by increasing the thickness of the metamaterial layer, the width of the second reflection band decreases while the width of the first reflection band remains almost the same though it shifts towards the higher frequency side. In addition to this, a new band gap arises in the lower side of frequency. But, when the thickness of the superconductor layer is increased, the width of both the bands increases and no additional band arises in this case. Moreover, the reflection band is also affected by varying the operating temperature of the superconducting layer and the results show that bands get narrower by increasing the operating temperature. Finally, the effect of incident angle on the reflection band has been discussed for both transverse electric (TE) and transverse magnetic (TM) polarizations.     

LDA + U Study of Induced Half Metallicity in Cr-Doped GaN

Half-metallic ferromagnetism in the Ga_{1 ? x}Cr _x N compound at different concentrations, x = 25, 12.5 and 6.25 %, have been investigated using density functional theory as implemented in code Spanish Initiative for Electronic Simulations with Thousands of Atoms (SIESTA) using LDA + U as exchange-correlation (XC) potential, to find out the possibility of new diluted DMSs. The outcomes reveal that transition metal atom (Cr) doping in GaN induces ferromagnetism. The 3d levels of the TM ion originate a half-metallic gap at the Fermi level in the majority spin channel for all concentrations. Moreover, diluted magnetic semiconductor compounds retain the half-metallic nature at all concentrations, i.e., x = 0.25, 0.125 and 0.0625, with 100 % spin polarization at the Fermi level (E _F). The total magnetic moment of these compounds is due to Cr-3d states, and the existence of a small magnetic moment on Ga and N, non-magnetic atoms, for all doping concentrations is a consequence of p-d hybridization of Cr-d and N-p states. The calculated values of s-d exchange constant N α and p-d exchange constant N βconfirm the ferromagnetic character of the Cr-doped GaN compound.     

Effects of Ti and Mn Co-substitution on P4mm BiFeO3: An Ab Initio Calculation

Tetragonal BiFeO₃ (BFO), which has a giant spontaneous polarization, has attracted a great deal of attention recently. In this paper, we systematically study the structural, magnetic, electronic and optic properties of BFO, BiFe_0.75Mn_0.25 O ₃ (BFMM), and BiFe_0.75Ti_0.125Mn_0.125 O ₃ (BFMT). Results show that doping Ti and Mn into the Fe sites increases the c/a ratio and enhances the magnetization of BiFeO₃ from 0 to 5 μ_B. The crystal symmetry changes from orthogonality to tetragonality with half of the Mn atoms being replaced by Ti in BiFe_0.75Mn_0.25 O ₃, which suppresses the energy splitting of the Mn 3d orbitals and thus enlarge the band gap to 1.21 eV for BiFe_0.75Ti_0.125Mn_0.125 O ₃. Our calculated Bader charge and charge density difference show that the smallest volume of BiFe_0.75Mn_0.25 O ₃ arises from the strong Mn–O bonds in BiFe_0.75Mn_0.25 O ₃. Further investigations indicate similar optical behaviors for BiFeO₃ and BiFe_0.75Ti_0.125Mn_0.125 O ₃. However, BiFe_0.75Mn_0.25 O ₃ exhibits strong absorption in the infrared region for the transition from O 2p to Mn \({e_{g}^{2}}\) and \(t_{2g}^{3}\).     

A Comparative Investigation of Optical and Structural Properties of Cu-Doped CdO-Derived Nanostructures

In this report, we studied various structural and optical properties of pure and copper-doped cadmium oxide (CdO) thin films. Nanostructured Cu-doped CdO films were deposited using sol–gel spin-coating technique. The structural and morphological changes have been observed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and atomic force microscopy (AFM) studies. The optical and electrical properties of the pure and Cu-doped CdO thin films were studied by UV–vis spectroscopy and four-point probe method, respectively. The XRD peaks show the formation of nanocrystalline CdO with cubic face-centered crystal structure. The band gaps of the as deposited films were found in the range of 2.32–2.73 eV, while after doping, it decreases due to structural deformation. The electrical resitivity was found to decrease approximately ～10 in Cu-doped CdO thin films.     

Effect of Sintering Temperature on Magnetic and Electrical Properties of GdBaCo<Subscript>2</Subscript><Emphasis Type="Italic">O</Emphasis><Subscript>5 + <Emphasis Type="Italic">δ</Emphasis></Subscript>

In this study, we report the results of an investigation into the sintering temperature dependence of magnetic and transport properties for GdBaCo₂ O _{5 + δ} synthesized through a sol-gel method. The lowering of sintering temperature leads to the increase of oxygen content and the reduction of grain size. The increase of oxygen content results in the enhancement of magnetic interactions and the weakening of Coulomb repulsion effect, while the reduction of grain size improves the magnetoresistance effect. Metal-insulator transition accompanied with spin-state transition is observed in all samples.     

Effect of Ni Doping at Pd Site in Nb<Subscript>2</Subscript>PdS<Subscript>5</Subscript> Superconductor

The superconducting properties of Nb₂PdS₅ superconductor have been investigated with Ni doping at Pd site All the bulk polycrystalline Nb₂Pd_1?xNi_x S ₅ (0 = x ≤ 0.10) samples are crystallized in singlephase monoclinic structure. The electrical resistivity and magnetic measurements of Nb₂Pd_1?xNi_x S ₅ (0 = x ≤ 0.15) were carried out to study the variation of superconducting critical parameters with Ni doping. Superconductivity in Nb₂PdS₅ sample completely disappears for x ≥ 0.15. We observed that the ratio of upper critical field to transition temperature decreases with increasing Ni concentration. Also, the magnetization study of Nb₂Pd_1?xNi_x S ₅ (0 = x ≤ 0.15) samples shows similar superconducting behaviour. In summary, the superconductivity in Nb₂PdS₅ sample is slightly varying with partial doping of Ni at Pd site in Nb₂PdS₅ superconductor.     

Filamentary Superconductivity in Semiconducting Policrystalline ZrSe<Subscript>2</Subscript> Compound with Zr Vacancies

Z r S e ₂ is a band semiconductor studied long time ago. It has interesting electronic properties, and because its layer structure can be intercalated with different atoms to change some of the physical properties. In this investigation, we found that Zr deficiencies alter the semiconducting behavior and the compound can be turned into a superconductor. In this paper, we report our studies related to this discovery. The decreasing of the number of Zr atoms in small proportion according to the formula Zr _x Se₂, where x is varied from about 8.1 to 8.6 K, changing the semiconducting behavior to a superconductor with transition temperatures ranging between 7.8 and 8.5 K, is depending on the deficiencies. Outside of those ranges, the compound behaves as semiconducting with the properties already known. In our experiments, we found that this new superconductor has only a very small fraction of superconducting material determined by magnetic measurements with applied magnetic field of 10 Oe. Our conclusions is that superconductivity is filamentary. However, in one studied sample, the fraction was about 10.2 %, whereas in others is only about 1% or less. We determined the superconducting characteristics; the critical fieldsthat indicate a type 2 superonductor with Ginzburg-Landau κ parameter of the order about 2.7. The synthesis procedure is quite normal following the conventional solid state reaction. In this paper, included are the electronic characteristics, transition temperature, and evolution with temperature of the critical fields.     

Optimizing spatiotemporal sensors placement for nutrient monitoring: a stochastic optimization framework

Nutrient monitoring is very important for the area of food–energy–water nexus. The sensor network for nutrient monitoring requires dynamic sensing where the positions of the sensors change with time. In this work, we have proposed a methodology to optimize a dynamic sensor network which can address the spatiotemporal aspect of nutrient movement in a watershed. This is a first paper in the series where an algorithmic and methodological framework for spatiotemporal sensor placement problem is proposed. Dynamic sensing is widely used in wireless sensors, and the current approaches to solving this problem are data intensive. This is the first time we are introducing a stochastic optimization approach to dynamic sensing which is efficient. This framework is based on a novel stochastic optimization algorithm called Better Optimization of Nonlinear Uncertain Systems (BONUS). A small case study of the dynamic sensor placement problem is presented to illustrate the approach. In the second paper of this series, we will present a detailed case study of nutrient monitoring in a watershed.     

On the simulation,economic analysis,and life cycle assessment of batch-mode organic solvent recovery alternatives for the pharmaceutical industry

This study explores design alternatives for the purification and possible reuse of low-volume organic solvents waste streams in pharmaceutical manufacturing. Solvent use has a large impact on the life cycle of pharmaceutical processes, as typically 80–90% of the total mass used in the production of an active pharmaceutical ingredient is attributed to solvent use. Solvents are not consumed in pharmaceutical processes so they exit the process as waste. These waste streams are usually disposed of using incineration; therefore, generating significant life cycle emissions from disposal and replacement of virgin solvent. Solvent recovery efforts are generally limited to large-volume waste streams. However, results show that solvents in low-volume streams can also be economically recovered using a versatile multi-campaign solvent recovery skid. Three different solvent waste streams were evaluated, and 85.3% reduction in total emissions and 86.3% reduction in operating costs were achieved. Investment in the solvent recovery system was determined to have a payback period of 4.5 years and a 28% IRR over 10 years. A life cycle impact assessment shows impacts on the human health, ecosystems, and resources categories have been reduced by 82.4, 85.1, and 87.1%, respectively.