Analysis of photocurrents at the semiconductor—eletrolyte junction

The photocurrent vs potential characateristics for three different electrolyte—semiconductor junctions, representative of those generally found in semiconductor photoelectrochemistry, are analyzed in detail using parameters which define both the semiconductor and the electrolyte. It is shown that, in general, the behaviour of junctions including semiconductors with sufficiently wide energy pags and large free carriers densities, may be accurately described using the Gärtner model in the potential region which does not include the onset of the photocurrent. In this case, it is the characteristics of the semiconductor which control the photoresponse and the electrolyte does not induce limiting steps in the charge transfer across the interface. If certain restrictive conditions are fulfilled concerning the relative orders of magnitude of the semiconductor space charge region, diffusion length of minority carriers and penetration depth of light into the semiconductor, the value of the flat band potential may be easily determined by ploting i²_phvs V and extrapolating to i²_ph = 0. In the other cases, the relation established by Gärtner between i_ph and V has been verified provided that the free carriers density be sufficiently large.     

Laser sintering of coated polyamide 12: a new way to improve flammability

Journal of Materials Science - In this study coatings of kaolin and talc particles were successfully applied on the surface of polyamide 12 powder intended for laser sintering (LS). Microscopic...     

Radial dispersion in trickle-bed reactors: Comparison between sock and dense loadings

A 0.3 m diameter trickle-bed reactor filled with porous alumina cylinders is used to study the influence of the catalyst loading method on liquid distribution. The study compares the performances of the dense and the sock loading methods in terms of radial liquid spreading. Measurements were performed using two wire mesh tomography devices, placed, respectively, 0.33 and 0.96 m below the liquid distributor. The obtained results show that, in opposition to general agreement, sock packed beds seem to distribute liquid better than dense packed beds. This surprising result may be tentatively explained by a larger anisotropy of the dense loading.     

An improved Wigner Monte-Carlo technique for the self-consistent simulation of RTDs

We present an original approach to including quantum transport into classical Ensemble Monte Carlo (EMC) simulations. The method, based on the Wigner transport equation, is fully self-consistent, and includes impurity and phonon scattering according to the Fermi Golden rule. It is inspired by an approach suggested by Shifren et al. [IEEE Trans. Electron Dev. 50, 769 (2003)], with some major improvements that make possible successful comparison with other simulation techniques and experiments.     

Topography of brain sodium accumulation in progressive multiple sclerosis

Object

Sodium accumulation is involved in neuronal injury occurring in multiple sclerosis (MS). We aimed to assess sodium accumulation in progressive MS, known to suffer from severe neuronal injury.

Materials and methods

3D-²³Na-MRI was obtained on a 3T-MR-scanner in 20 progressive MS patients [11 primary-progressive (PPMS) and nine secondary-progressive (SPMS)] and 15 controls. Total sodium concentrations (TSC) within grey matter (GM), normal-appearing white matter (WM) and lesions were extracted. Statistical mapping analyses of TSC abnormalities were also performed.

Results

Progressive MS patients presented higher GM–TSC values (48.8 ± 3.1 mmol/l wet tissue vol, p < 0.001) and T₂lesions-TSC values (50.9 ± 2.2 mmol/l wet tissue vol, p = 0.01) compared to GM and WM of controls. Statistical mapping analysis showed TSC increases in PPMS patients confined to motor and somatosensory cortices, prefrontal cortices, pons and cerebellum. In SPMS, TSC increases were associated with areas involving: primary motor, premotor and somatosensory cortices; prefrontal, cingulate and visual cortices; the corpus callosum, thalami, brainstem and cerebellum. Anterior prefrontal and premotor cortices TSC were correlated with disability.

Conclusion

Sodium accumulation is present in progressive MS patients, more restricted to the motor system in PPMS and more widespread in SPMS. Local brain sodium accumulation appears as a promising marker to monitor patients with progressive MS.     

On the relationship between snow grain morphology and in-situ near infrared calibrated reflectance photographs

Seasonal and permanent snow cover a significant portion of our planet, and its impact on climate is significant. Through specific thermophysical properties, snow controls radiative and turbulent fluxes between the ground and the atmosphere, but many aspects of the energy balance are poorly understood due to lingering uncertainties regarding snow properties, such as grain size in particular. Rapid and accurate measurement method has yet to be developed given the reality of field and laboratory logistical constraints, and the sensitivity of snow to any sort of manipulation.In this paper, we investigate the relationship between snow grain morphology parameters measured from visible (traditional) snow grain photography and optical diameter estimated from Near-InfraRed (NIR) reflectance photographs of snow walls. A total of 51 snowpits were analyzed during our International Polar Year field campaign across a 1000 km South-to-North transect over Eastern Canada. We compared the NIR measurements with the theoretical snow albedo model of Kokhanovsky and Zege (2004). Results show the large difference between the snow specific surface area (SSA) of snow grains derived from snow albedo model and the geometrical (visual) diameter. From three different snow grain classes which can be distinguished from traditional photography, linkages can be made with shape factors required in the optical model in order to retrieve optical grain size from NIR photography.     

Quantitative biodistribution and pharmacokinetics of multimodal gadolinium-based nanoparticles for lungs using ultrashort TE MRI

Objective

To study the biodistribution and lung pharmacokinetics of tracheally administered gadolinium-based contrast agents [gadoteric acid and multimodal ultra-small rigid platforms (USRPs)], to validate their pharmacokinetics against optical imaging of fluorescent USRPs, and to test their short-term toxicity.

Materials and methods

Ultrashort echo-time (UTE) lung proton magnetic resonance imaging (MRI) was performed at 4.7-Tesla (T) after the intratracheal instillation of different concentrations of contrast agent solutions in mice. Pharmacokinetic models were implemented on the absolute concentration calculated from the MRI signal enhancement measurements. Fluorescent USRPs were used to obtain optical images with the same protocol. Bronchoalveolar lavage inflammatory cell count and serum creatinine measurement were performed on four groups of instilled mice (sham, saline, USRPs, lipopolysaccharide).

Results

MR and optical imaging showed similar kinetics of the USRPs, passing from the airways to the lung tissue and to the kidneys, with negligible hepatic clearance. No significant increase of lung and renal inflammation markers were observed in USRP-instilled animals.

Conclusion

A T ₁-weighted radial UTE sequence was found to be valuable in quantitatively monitoring the biodistribution and pharmacokinetics of nanoparticles in the lungs of mice. The observed favorable pharmacokinetics, which was validated by fluorescence imaging, ensures the negligible toxicity of the nanoprobes, making the USRPs and the developed protocol good candidates for applications on selected lung diseases.     

A (Triphenylphosphine)Silver (I) Complex as a New Performance Additive in Free‐Radical Photopolymerization under Air

Unusual photochemical properties of an Ag(I)‐derived complex, i.e., bis[(µ‐chloro)bis(triphenylphosphine)silver (I)] ([Ag](PPh₃)) are demonstrated when used in free‐radical photopolymerization reactions: i) [Ag](PPh₃) can act as an innovative photoinitiating system when associated with a commercial type I photoinitiator 2,2‐dimethoxy‐2‐phenylacetophenone to overcome the oxygen inhibition effect during the free‐radical photopolymerization of acrylate monomers, thus accelerating the kinetics of polymerization under air; ii) silver‐based nanoparticles can be in situ generated under air, thus leading to new antibacterial coatings which prevent the growth of Escherichia coli and Staphylococcus aureus after few hours of incubation.