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51.
Macrophage apoptosis, a key process in atherogenesis, is regulated by oxidation products, including hydroxyoctadecadienoic acids (HODEs). These stable oxidation products of linoleic acid (LA) are abundant in atherosclerotic plaque and activate PPARγ and GPR132. We investigated the mechanisms through which HODEs regulate apoptosis. The effect of HODEs on THP‐1 monocytes and adherent THP‐1 cells were compared with other C18 fatty acids, LA and α‐linolenic acid (ALA). The number of cells was reduced within 24 hours following treatment with 9‐HODE (p < 0.01, 30 μM) and 13 HODE (p < 0.01, 30 μM), and the equivalent cell viability was also decreased (p < 0.001). Both 9‐HODE and 13‐HODE (but not LA or ALA) markedly increased caspase‐3/7 activity (p < 0.001) in both monocytes and adherent THP‐1 cells, with 9‐HODE the more potent. In addition, 9‐HODE and 13‐HODE both increased Annexin‐V labelling of cells (p < 0.001). There was no effect of LA, ALA, or the PPARγ agonist rosiglitazone (1μM), but the effect of HODEs was replicated with apoptosis‐inducer camptothecin (10μM). Only 9‐HODE increased DNA fragmentation. The pro‐apoptotic effect of HODEs was blocked by the caspase inhibitor DEVD‐CHO. The PPARγ antagonist T0070907 further increased apoptosis, suggestive of the PPARγ‐regulated apoptotic effects induced by 9‐HODE. The use of siRNA for GPR132 showed no evidence that the effect of HODEs was mediated through this receptor. 9‐HODE and 13‐HODE are potent—and specific—regulators of apoptosis in THP‐1 cells. Their action is PPARγ‐dependent and independent of GPR132. Further studies to identify the signalling pathways through which HODEs increase apoptosis in macrophages may reveal novel therapeutic targets for atherosclerosis.  相似文献   
52.
New π‐conjugated polymers containing dithieno(3,2‐b:2′,3′‐d)pyrrole (DTP) were successfully synthesized via electropolymerization. The effect of structural differences on the electrochemical and optoelectronic properties of the 4‐[4H‐dithieno(3,2‐b:2′,3′‐d)pyrrol‐4‐yl]aniline (DTP–aryl–NH2), 10‐[4H‐dithiyeno(3,2‐b:2′,3′‐d)pirol‐4‐il]dekan‐1‐amine (DTP–alkyl–NH2), and 1,10‐bis[4H‐dithieno(3,2‐b:2′,3′‐d)pyrrol‐4‐yl] decane (DTP–alkyl–DTP) were investigated. The corresponding polymers were characterized by cyclic voltammetry, NMR (1H‐NMR and 13C‐NMR), and ultraviolet–visible spectroscopy. Changes in the electronic nature of the functional groups led to variations in the electrochemical properties of the π‐conjugated systems. The electroactive polymer films revealed redox couples and exhibited electrochromic behavior. The replacement of the DTP–alkyl–DTP unit with DTP–aryl–NH2 and DTP–alkyl–NH2 resulted in a lower oxidation potential. Both the poly(10‐(4H‐Dithiyeno[3,2‐b:2′,3′‐d]pirol‐4‐il)dekan‐1‐amin) (poly(DTP–alkyl–NH2)) and poly(1,10‐bis(4H‐dithieno[3,2‐b:2′,3′‐d]pyrrol‐4‐yl) decane) (poly(DTP–alkyl–DTP)) films showed multicolor electrochromism and also fast switching times (<1 s) in the visible and near infrared regions. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40701.  相似文献   
53.
牛奶蛋白纤维(第Ⅰ部分)   总被引:1,自引:0,他引:1  
牛奶蛋白纤维是一种新颖的工业生产纤维,中国已拥有2项发明专利.2004年它就已经通过了国际生态纺织品Oeko-Tex标准100认证.牛奶蛋白纤维是利用新型生物工程技术将牛奶去水脱脂,加工成适用于湿法纺丝工艺的蛋白浆后制得的纤维.它对皮肤友好,手感舒适,色彩鲜艳,具有很好的可染性.牛奶蛋白纤维可以纯纺或与羊绒、蚕丝、棉、毛、麻及其他纤维混纺.  相似文献   
54.
ABSTRACT

Current health situations have instigated increased frequency of taking antibiotics for cure of infections but this amplified use is posing threats to environment. This research is focused to remove Tetracycline (TC), an antibiotic from water, using an advanced nanohybrid that compact the properties of adsorbent and photocatalyst. Compared to conventional methods for remediation of TC, large surface area (452 m2g?1) adsorbent photocatalyst hybrid (APH) g-C3N4/α-MoO3/ZIF-67 (CMZ) have found much effective as 97% degradation of TC is observed in 110 min with 0.1 g of APH. Increasing g-C3N4 in the hybrids has improved percent degradation of TC molecules. CMZ-3 is found as a potential candidate for water treatment.  相似文献   
55.
Turkish lignite can be used as a new adsorption material for removing some toxic metals from aqueous solution. The adsorption of lignite (brown young coals) to remove copper (Cu2+), lead (Pb2+), and nickel (Ni2+) from aqueous solutions was studied as a function of pH, contact time, metal concentration and temperature. Adsorption equilibrium was achieved between 40 and 70 min for all studied cations except Pb2+, which is between 10 and 30 min. The adsorption capacities are 17.8 mg/g for Cu2+, 56.7 mg/g for Pb2+, 13.0 mg/g for Ni2+ for BC1 (Ilg?n lignite) and 18.9 mg/g for Cu2+, 68.5 mg/g for Pb2+, 12.0 mg/g for Ni2+ for BC2 (Beysehir lignite) and 7.2 mg/g for Cu2+, 62.3 mg/g for Pb2+, 5.4 mg/g for Ni2+ for AC (activated carbon). More than 67% of studied cations were removed by BC1 and 60% BC2, respectively from aqueous solution in single step. Whereas about 30% of studied cations except Pb2+, which is 90%, were removed by activated carbon. Effective removal of metal ions was demonstrated at pH values of 3.8–5.5. The adsorption isotherms were measured at 20 °C, using adsorptive solutions at the optimum pH value to determine the adsorption capacity. The Langmuir adsorption isotherm was used to describe observed sorption phenomena. The rise in temperature caused a slight decrease in the value of the equilibrium constant (Kc) for the sorption of metal ions. The mechanism for cations removal by the lignite includes ion exchange, complexation and sorption. The process is very efficient especially in the case of low concentrations of pollutants in aqueous solution, where common methods are either economically unfavorable or technically complicated.  相似文献   
56.
The effect of citric acid (CA) addition was studied on the HDS of thiophene over Co–Mo/(B)/Al2O3 catalysts. The catalysts were characterized by means of LRS, Mo K-edge EXAFS, NO adsorption capacity measurements, and UV–vis spectra. The catalysts were subjected to a chemical vapor deposition (CVD) technique using Co(CO)3NO as a precursor of Co in order to get deeper insights into the effect of citric acid addition. It was shown that the HDS activity was enhanced by the citric acid addition up to the CA/Mo mole ratio of around 1 and leveled off with further addition. The amount of Co anchored by the CVD was increased by the addition of citric acid, suggesting an increase in the dispersion of MoS2 particles on the catalyst by the simultaneous presence of Co, Mo and citric acid, in conformity with the increase in the NO adsorption capacity. In contrast to Co–Mo catalysts, the edge dispersion of MoS2 particles in Mo/B/Al2O3 was not affected by the addition of citric acid. The LRS, UV–vis spectra and Mo K-edge EXAFS showed that Co–CA and Mo–CA surface complexes are formed by the addition of citric acid. The Co–CA surface complex is more preferentially formed on CoMo/Al than on CoMo/B/Al, in agreement with a greater promoting effect of citric acid at a lower CA/Mo mole ratio for CoMo/Al than for CoMo/B/Al.  相似文献   
57.
58.
Poly(vinylidenefluoride‐co‐trifluoroethylene) (P(VDF‐TrFE)), as a ferroelectric polymer, offers great promise for energy harvesting for flexible and wearable applications. Here, this paper shows that the choice of solvent used to dissolve the polymer significantly influences its properties in terms of energy harvesting. Indeed, the P(VDF‐TrFE) prepared using a high dipole moment solvent has higher piezoelectric and pyroelectric coefficients and triboelectric property. Such improvements are the result of higher crystallinity and better dipole alignment of the polymer prepared using a higher dipole moment solvent. Finite element method simulations confirm that the higher dipole moment results in higher piezoelectric, pyroelectric, and triboelectric potential distributions. Furthermore, P(VDF‐TrFE)‐based piezoelectric, pyroelectric, and triboelectric nanogenerators (NGs) experimentally validate that the higher dipole moment solvent significantly enhances the power output performance of the NGs; the improvement is about 24% and 82% in output voltage and current, respectively, for piezoelectric NG; about 40% and 35% in output voltage and current, respectively, for pyroelectric NG; and about 65% and 75% in output voltage and current for triboelectric NG. In brief, the approach of using a high dipole moment solvent is very promising for high output P(VDF‐TrFE)‐based wearable NGs.  相似文献   
59.
The present paper is focused on visible light initiated cationic polymerizations. Photoinitiated polymerization of representative vinyl ether and oxirane monomers using two quinoxaline derivatives; namely (2-(2,3-dihydrobenzo [b][1,4]dioxin-6-yl)-3-(2,3-dihydrobenzo[b]-[1,4]dioxin-7-yl)-5-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-8-(2,3-dihydrothieno[3,4-b][1,4]dioxin-7yl) quinoxaline) (DBQEd) and 2,3,5,8-tetra(thiophen-2-yl)quinoxaline (TTQ) are studied. Novel dyes based on the quinoxaline skeleton are employed as efficient photosensitizers in cationic photopolymerizations. Polymerizations were initiated at room temperature upon irradiation with long-wavelength UV and visible lights in the presence of diphenyliodonium hexafluorophosphate (Ph2I+PF6?). The progress of the polymerizations was monitored by optical pyrometry (OP). Solar irradiation is also employed to carry out the cationic polymerization of a diepoxide monomer in the presence of air.  相似文献   
60.
A rule-based expert system for earthquake prediction   总被引:2,自引:0,他引:2  
Earthquake is a natural disaster which causes extensive damage as well as the death of thousands of people. Earthquake professionals for many decades have recognized the benefits to society from reliable earthquake predictions. Techniques like: mathematical modelling, hydrology analysis, ionosphere analysis and even animal responses have been used to forecast a quake. Most of these techniques rely on certain precursors like, stress or seismic activity. Data mining techniques can also be used for prediction of this natural hazard. Data mining consists of evolving set of techniques such as association rule mining that can be used to extract valuable information and knowledge from massive volumes of data. The aim of this study is to predict a subsequent earthquake from the data of the previous earthquake. This is achieved by applying association rule mining on earthquake data from 1979 to 2012. These associations are polished using predicate-logic techniques to draw stimulating production-rules to be used with a rule-based expert system. Prediction process is done by an expert system, which takes only current earthquake attributes to predict a subsequent earthquake. The rules generated for predicting the earthquake are mathematically validated as well as tested on real life earthquake data. Results from our study show that the proposed rule-based expert system is able to detect 100 % of earthquakes which actually occurred within 15 hours at-most within a defined range, depth and location. This work solely relies on previous earthquake data for predicting the next.  相似文献   
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