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21.
Responsive Macroscopic Materials From Self‐Assembled Cross‐Linked SiO2‐PNIPAAm Core/Shell Structures
Christian W. Pester Artjom Konradi Birte Varnholt Patrick van Rijn Alexander Böker 《Advanced functional materials》2012,22(8):1724-1731
A way to obtain macroscopic responsive materials from silicon‐oxide polymer core/shell microstructures is presented. The microparticles are composed of a 60 nm SiO2‐core with a random copolymer corona of the temperature responsive poly‐N‐isopropylacrylamide (PNIPAAm) and the UV‐cross‐linkable 2‐(dimethyl maleinimido)‐N‐ethyl‐acrylamide. The particles shrink upon heating and form a stable gel in both water and tetrahydrofuran (THF) at 3–5 wt% particle content. Cross‐linking the aqueous gel results in shrinkage when the temperature is increased above the lower critical solution temperature and it regains its original size upon cooling. By freeze drying with subsequent UV irradiation, thin stable layers are prepared. Stable fibers are produced by extruding a THF gel into water and subsequent UV irradiation, harnessing the cononsolvency effect of PNIPAAm in water/THF mixtures. The temperature responsiveness translates to the macroscopic materials as both films and fibers show the same collapsing behavior as the microcore/shell particle. The collapse and re‐swelling of the materials is related to the expelling and re‐uptake of water, which is used to incorporate gold nanoparticles into the materials by a simple heating/cooling cycle. This allows for future applications, as various functional particles (antibacterial, fluorescence, catalysis, etc.) can easily be incorporated in these systems. 相似文献
22.
Niklas Sommer André Bauer Martin Kahlmeyer Thomas Wegener Sebastian Degener Alexander Liehr Artjom Bolender Malte Vollmer Hendrik Holz Stefan Zeiler Benoit Merle Thomas Niendorf Stefan Böhm 《Advanced Engineering Materials》2023,25(15):2300030
In laser-based direct energy deposition (DED-LB) additive manufacturing (AM), wire or powder materials are melted by a high-power laser beam. Process-specific characteristics enable robust in situ fabrication of compositionally graded materials, e.g., through an adaption of powder mass flow from independent hoppers. Based on the high flexibility of this approach, pathways toward multimaterial AM have been unlocked. Obviously, such characteristics enable high-throughput alloy development. However, rapid alloy development demands substantial characterization efforts to assess phase and microstructural evolution. So far, property analysis is considered as the limiting factor for these high-throughput approaches. Herein, the use of high-brilliance X-Ray analysis and subsequent micropillar compression testing are introduced to tackle these challenges. As a proof of concept, their application to a compositionally graded material made from AISI 316L stainless steel and a CoCrMo alloy is presented. The results obtained reveal that X-Ray analysis can be exploited to evaluate process robustness, chemical characteristics, and phase composition within the gradient regions. Moreover, the use of micropillar compression testing provides spatially resolved insights into the mechanical properties of the gradient regions. The combination of both characterization techniques eventually opens pathways toward a robust and time-efficient alloy development using powder-fed DED-LB (DED-LB/P). 相似文献
23.
Alexander Liehr Thomas Wegener Sebastian Degener Artjom Bolender Nico Möller Thomas Niendorf 《Advanced Engineering Materials》2023,25(17):2300380
Quenching and partitioning (Q&P) steels are characterized by an excellent combination of strength and ductility, opening up great potentials for advanced lightweight components. The Q&P treatment results in microstructures with a martensitic matrix being responsible for increased strength whereas interstitially enriched metastable retained austenite (RA) contributes to excellent ductility. Herein, a comprehensive experimental characterization of microstructure evolution and austenite stability is carried out on a 42CrSi steel being subjected to different Q&P treatments. The microstructure of both conditions is characterized by scanning electron microscopy as well as X-ray diffraction (XRD) phase analysis. Besides macroscopic standard tensile tests, RA evolution under tensile loading is investigated by in situ XRD using synchrotron and laboratory methods. As a result of different quenching temperatures, the two conditions considered are characterized by different RA contents and morphologies, resulting in different strain hardening behaviors as well as strength and ductility values under tensile loading. In situ synchrotron measurements show differences in the transformation kinetics being rationalized by the different morphologies of the RA. Eventually, the evolution of the phase specific stresses can be explained by the well-known Masing model. 相似文献