The iron compounds (iron(III) oxide‐hydroxide monohydrate FeO(OH) × H2O, iron(III) oxide Fe2O3, and ascorbic acid) were used as oxygen scavengers modifiers in laminating of polymer films. This oxygen‐scavenging system was coated on preselected films (low density polyethylene [LDPE] and polyethylene terephthalate [PET]) from which the laminates were formed. It presents the new form of composite material packaging that has the function of oxygen scavenging, which could be suitable for food packaging. The scope of the research included studies of morphology of oxygen scavengers by scanning electron microscope and their average particle size distribution measure by particle size analyzer, the effect of type, and concentration of these substances on viscosity of adhesive and seal strength of laminates. The Fourier‐transform infrared spectroscopy (FTIR) of laminates was also performed to observe the potential interaction of functional groups of polyurethane adhesives with oxygen scavenger components. The most important ability of the developed system for oxygen scavenging was confirmed by measuring oxygen concentration (% vol) in a headspace with the prepared laminates. The concentrations of selected oxygen scavengers (4‐6 wt%) and their combinations were studied. The most effective oxygen scavenger system integrated within the PE/PET composite film consists of 6 wt% ascorbic acid and 1 wt% FeO(OH) × H2O, where the oxygen concentration of 1.0 vol% (±0.20 vol%) was obtained after 15 days of storage. It was found that in this system the oxygen scavenging reaction occurs through ascorbate oxidation to dehydroascorbic acid, which is catalyzed by reduction of Fe3+ to Fe2+ ions. 相似文献
Nanostructured erbium oxides (Er2O3) with coherent scattering length 26, 31, 62 and 65 nm were obtained using as a precursor of erbium chloride and erbium oleate. The influences of Er203 on the immune system and some animal tissues were carried out. The experiments have been made on white mouse's and outbred rats. Complex pharmaco-toxicological research presented erbium oxide nanostructure size of coherent scattering regions 26, 31, 56 and 65 nm showed that when administered orally no acute toxicity, no effect on the immune system of the body, has no effect on blood cells. But, long-term (30 day) intragastric administration shows toxicities on the internal organs of experimental animals, which lead to structural changes and functional impairment due to tissue accumulation of nanoparticles. 相似文献
Commonly used orthotropic Hill’s criterion of plastic flow initiation (Hill in Proc R Soc Lond A 193:281–297, 1948) suffers from some constraints and inconsistencies, which are of two different origins. Firstly, in case of high orthotropy degree, the quadratic form corresponding to Hill’s criterion may change type from convex and closed elliptic to concave and open hyperbolic in the deviatoric stress space (Ottosen and Ristinmaa in the mechanics of constitutive modeling, Elsevier, Amsterdam, 2005). Secondly, application of classical Hill’s criterion to transversely isotropic materials shows a discrepancy between Hill’s limit curves in the transverse isotropy plane and the Huber-von Mises prediction for isotropic materials (Huber 1904; von Mises 1913). The basic result of the present paper is to propose the new transversely isotropic von Mises–Hu–Marin’s-type criterion of hexagonal symmetry that is free from both constraints. The new enhanced Hu–Marin’s-type limit surface represents an elliptic cylinder, the axis of which is proportional to stress/strength, in contrast to Hill’s-type limit surface possessing the hydrostatic axis. Hence, this condition does not exhibit the deviatoricity property, which is a price for coincidence with the Huber–von Mises condition in the transverse isotropy plane, but with cylindricity ensured for an arbitrarily high orthotropy degree. The hybrid-type transversely isotropic Hu–Marin’s criterion of mixed symmetry based on additional biaxial bulge test, capable of fitting experimental findings for some complex composites, is also proposed. Application of this criterion has been verified for a unidirectional SiC/Ti composite examined by Herakovich (Thermal stresses V, Lastran Corp. Publ. Division, pp 1–142, 1999). 相似文献
A new efficient multicatalytic process involving a single catalyst to promote tandem hydroformylation/arylation reactions is disclosed. The effect of the rhodium ligand was evaluated and the rhodium/triphenylphosphine catalytic system was selected to apply the methodology to different olefins and boronic acids. High yields (up to 89%) and good to excellent isomer ratios (up to 98:2) were achieved using aryl olefins as starting materials. This new methodology allows the preparation of secondary alcohols, from simple olefins, and paves the way for the synthesis of high‐value products, namely vinylindole and anethole derivatives.
High temperature stress leads to complex changes to plant functionality, which affects, i.a., the cell wall structure and the cell wall protein composition. In this study, the qualitative and quantitative changes in the cell wall proteome of Brachypodium distachyon leaves in response to high (40 °C) temperature stress were characterised. Using a proteomic analysis, 1533 non-redundant proteins were identified from which 338 cell wall proteins were distinguished. At a high temperature, we identified 46 differentially abundant proteins, and of these, 4 were over-accumulated and 42 were under-accumulated. The most significant changes were observed in the proteins acting on the cell wall polysaccharides, specifically, 2 over- and 12 under-accumulated proteins. Based on the qualitative analysis, one cell wall protein was identified that was uniquely present at 40 °C but was absent in the control and 24 proteins that were present in the control but were absent at 40 °C. Overall, the changes in the cell wall proteome at 40 °C suggest a lower protease activity, lignification and an expansion of the cell wall. These results offer a new insight into the changes in the cell wall proteome in response to high temperature. 相似文献
The effect on the wine protein haze potential of five organic acids commonly encountered in wines (l(+)-tartaric, l(−)-malic, citric, succinic and gluconic acids) was assessed. All five acids, tested at 20 mM, reduced dramatically the haze potential of proteins, either in wine or dissolved in water, throughout the range of pH values typical of wines (i.e., from 2.8 through 3.8). Subtle differences among the acid effects did not correlate with the number of their carboxyl groups, but were attributed to electrostatic interactions that depend upon the acid pKa values, the protein pI values and the medium pH. These results invalidate or question the validity of all experiments on wine proteins involving wine model solutions containing organic acids. Overall, the results obtained in the present work clearly indicate that organic acids with a common occurrence in wines exhibit a stabilising effect upon the haze potential of the wine proteins. 相似文献
Artificial plant cell walls were produced from bacterial cellulose and cell wall constituents. The artificial cell walls were stored at low, medium and high relative humidity, and then subjected to micro-mechanical tests. From chemical composition and microstructure analysis it was found that, among all artificial cell wall materials produced, the most representative analogue of natural apple cell wall was based on bacterial cellulose supplemented with xyloglucan and pectin. Uniaxial tensile tests revealed that the different cell wall materials differed in their mechanical properties; increasing the humidity during storage resulted in a decrease in the value of the secant modulus. The cell wall model material obtained may be used for the simulation of the effect of external factors on the physical and chemical properties of cell walls. 相似文献
A new contact acoustic emission detector (CAED) was developed for the instrumental texture evaluation of apples. The goal of this work was to determine the relations between instrumental parameters and sensory texture attributes, and to develop calibration models for prediction of the sensory texture of apples with CAED. Seven apple cultivars were used for the construction and validation of the models. CAED is particularly useful for evaluation of sensory crispness, crunchiness and hardness. There is also a significant correlation of acoustic emission counts with juiciness, mealiness and overall texture. Validation of the models indicates better prediction of these sensory attributes by total acoustic emission counts than prediction by puncture firmness in terms of variance explained, root-mean-square of a model prediction, and bias.相似文献