Comparative evaluation of extraction of tetra- and hexa-valent neptunium ions by CMPO in a room temperature ionic liquid

ABSTRACT

Solvent extraction studies were performed to understand the extraction behavior of Np⁴⁺ and NpO₂ ²⁺ from acidic feeds with CMPO (octyl (phenyl)-N,N-diisobutyl carbamoyl methyl phosphine oxide) dissolved in 1-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide, a water immiscible ionic liquid. Slope analyses on the distribution data revealed the extraction of ML₂ type species, where M = Np⁴⁺ or NpO₂ ²⁺, and L = CMPO. Studies were also carried out with Pu⁴⁺ and UO₂ ²⁺ under identical conditions. The nature of the extracted species was found to vary with the nature of the ionic species.     

Two dimensional transport characteristics of surface stabilized zero-valent iron nanoparticles in porous media

Zero-valent iron nanoparticles (INP) were synthesized and stabilized using poly acrylic acid (PAA) to yield stabilized INP (S-INP). A two-dimensional physical model was used to study the fate and transport of the INP and S-INP in porous media under saturated, steady-state flow conditions. Transport data for a nonreactive tracer, INP, and S-INP were collected under similar flow conditions. The results show that unstabilized INP cannot be transported into groundwater systems. On the other hand, the S-INP can be transported like a tracer without significant retardation. However, the S-INP plume migrated downward as it moved horizontally in the physical model, indicating that small density gradients have significant influence on two-dimensional transport. The variable-density groundwater flow model SEAWAT was used to model the observed density-driven transport patterns. This is the first time a two-dimensional transport data set is reported for demonstrating the multidimensional transport characteristics of nanoparticles. The data shows the importance of density effects, which cannot be fully discerned using one-dimensional, column experiments. Finally, we also demonstrate that the numerical model SEAWAT can be used to predict the density-driven transport characteristics of S-INP in groundwater aquifers.     

Application of molecular identification tools for Lactobacillus, with a focus on discrimination between closely related species: A review

Lactobacillus is among the most important GRAS food lactic acid bacteria, with nearly 140 species at present, mostly of industrial importance. Being part of the natural flora of a range of food products like raw milk, fermented dairy products, fruits, vegetables, meat products they also serve as starters for a number of fermented food products either to enhance the quality or to add health benefits. These groups of economically important species are often alike in phenotypic and physiological characteristics, probably due to their co-evolution in the same ecological niches; hence they are difficult to be differentiated. This demands advanced methods for their proper identification and characterization. With the advancement of molecular biology, a range of DNA-based molecular techniques has replaced the largely cumbersome phenotypic methods. This review summarizes the various molecular techniques available for detection and identification within the genus Lactobacillus, with special emphasis on the four groups of closely resembling species: L. casei group, L. acidophilus group, L. delbrueckii subspecies, and L. plantarum group. This review also provides insights into current trends for alternative molecular markers other than 16S rRNA to resolve the ambiguity within phylogenetically close species in the genus Lactobacillus.     

A joint economic-lot-size model for purchaser and vendor in fuzzy sense

This paper investigates a group of computing schemas for joint economic lot size as fuzzy values of the economic lot size model for purchaser and vendor. We express the fuzzy order quantity/production lot size for the purchaser/vendor as the normal triangular fuzzy number (q₁, q₀, q₂) and then we solve the aforementioned optimization problem under the condition 0 < q₁ < q₀ < q₂. We find that, after defuzzification, the joint total relevant cost is slightly higher than in the crisp model.     

Growth, optical transmission and X-ray photoemission studies of BaB2O4 single crystals

Beta barium borate (-BBO) crystals have been grown by the top seeded solution growth technique (TSSG) using Na₂O as a flux. The crystals exhibited high transparency and the absence of inclusions and found to have sodium contamination in the range 150 to 230 p.p.m. The effect of this contamination on some crystal properties of interest has been investigated. The presence of impurities causes optical absorption below 550 nm in BBO crystals of both and -phases. X-ray photo emission spectroscopy (XPS) measurements performed on these crystals show that sodium gives rise to a measurable shift in the binding energies of the constituent ions. Further, the results show that Na⁺ ions enter into the lattice substitutionally and provide charge trapping sites close to the band edge.     

Interleukin-6-mediated autocrine growth promotion in human glioblastoma multiforme cell line U87MG

Human glioblastoma multiforme cell lines, brain tumor biopsy tissue, and normal human fetal brain synthesize interleukin (IL)-6 and IL-6 receptor (IL-6R). Neither of these is expressed in human neurons or neuroblastoma cell lines in culture. Astrocytes from fetal brain grown in culture retain the ability to synthesize IL-6 but do not express IL-6R as inferred from RT-PCR and Southern blot studies. Coexpression of IL-6 and IL-6R in the glioblastoma cell line U87MG is confirmed by immunofluorescence staining. Both specific monoclonal antibodies against IL-6 and IL-6R and antisense oligonucleotide to IL-6 mRNA inhibit the growth of U87MG cells in culture, suggesting the existence of a functional autocrine growth loop. Anti-IL-6 antibodies also inhibit the growth of glioblastoma cell lines U373 and U118. The expression of IL-6 by human fetal astrocytes in culture is highly suggestive of its role as an oncofetal protein responsible for rapid proliferation of fetal and tumor cells but not cells of adult brain.     

Responses of American readers to visual aspects of a mid-sizedJapanese company's annual report: a case study

American document design process models reflect the assumption that comprehension and usability are the most important characteristics of effective documents, but it is increasingly evident that other cultures value other communicative features of documents and that purposes and intentions vary across cultures. This case study examines the responses of four sets of American readers (three sets familiar with American document design research and practice and one set of content specialists-engineers by training) to the visual aspects of an annual report. The original document was prepared for a mid-sized Japanese corporation and published and distributed in Japan; the American version is an almost literal translation of the original document from Japanese to English, with no changes in visuals, graphic design or format. Protocol analyses of readers' responses revealed distinct patterns of expectations and preferences based on (1) cultural biases, (2) degree of familiarity with the American document design model, and (3) ignorance of Japanese culture and corporate communicative practices. This study raises questions about the effectiveness in terms of cultural sensitivity of what we have called the “American” document design process model and usability testing procedures, and calls for extensive collaborative research designed to describe and analyze current practice in international settings     

Isobaric vapour-liquid equilibria of the ternary system hexane-benzene-sulpholane

Isobaric vapour-liquid equilibria for the ternary system hexane-benezene-sulpholane have been determined at 760 mmHg pressure. The data have been compared with those calculated using the NRTL equation. The NRTL constants obtained from the literature were evaluated from ternary liquid-liquid equilibrium data for this system. The agreement between experimental and calculated values is reasonable.     

Role of Direct Reduced Iron Fines in Nitrogen Removal from Electric Arc Furnace Steel

Electric arc furnace steel contains about 70‐120 ppm nitrogen. There is no suitable method for nitrogen removal from electric arc furnace steel up to the level desired for good quality bars and flat rolled products (30 ppm max). The existing process based on vacuum degassing can remove only up to 20% of nitrogen in steel. In the present study DRI fines have been injected into a steel bath which can drift out nitrogen in steel through production of fine CO bubbles in‐situ on reaction with residual FeO in DRI fines and C in bath. For high and medium carbon steel, nitrogen got reduced to 30 ppm and 60 ppm respectively where initial nitrogen was 150 – 200 ppm in steel. Nitrogen removal also depends upon bath depth and addition level of DRI.     

Fuzzy Reliability Assessment of Distribution System with Wind Farms and Plug-in Electric Vehicles

Abstract

The equipment failures are highly uncertain in nature and simple average failure rate will not reflect this uncertainty. The uncertainty level further increases in reliability evaluation due to the integration of wind farm (WF) because of the intermittent nature of wind speed and random charging patterns of plug-in electric vehicles (PEVs). In this work, the uncertain variables in the distribution system (failure rate, repair time, WF output, PEVs charging and system load factor) are represented as fuzzy numbers to handle the uncertainty. The available uncertain data are used to find the probability distribution function (PDF) of that parameter and is converted into fuzzy membership function using transformation techniques. Failure rate of equipment is converted into failure probability using Monte Carlo simulation (MCS) method. Sampling method is applied to create the PDF of a variable which has average value. Fuzzy severity index (FSI) is proposed to find the importance of an equipment on reliability and is evaluated by measuring the fuzzy distance between the fuzzy reliability indices. The proposed assessment method is validated on modified RBTS bus 2 by comparing with analytical and MCS methods. The proposed method has been tested with integration of WFs and PEVs.