Kinetics of Catalytic Ozonation of Methyl tert‐Butyl Ether in the Presence of Perfluorooctyl Alumina

In this work, the kinetics of heterogeneous ozonation of methyl tert‐butyl ether (MTBE) in the presence of perfluorooctyl alumina (PFOAL) catalysts is presented. Activity of the PFOAL catalysts in ozonation reactions of MTBE was studied in a batch reactor over the temperature range of 25 to 40 °C. The results show that PFOAL is an effective catalyst for enhancing the molecular mechanism of ozone reactions. For a catalyst concentration of 5 g/L, the contribution of the rate of heterogeneous catalytic reaction in the total reaction rate is about 50 %, 75 %, and 85 % at the reaction temperatures of 25 °C, 30 °C, and 40 °C, respectively. Kinetic studies showed that the chemical reaction of ozone and MTBE is the controlling step in this catalytic system. The quasi‐homogeneous kinetic model proved to be an appropriate approach in modeling the heterogeneous reaction of ozone with MTBE on PFOAL catalysts.     

Bidding strategies in dynamic electricity markets

In this paper the problem of developing bidding strategies for the participants of dynamic oligopolistic electricity markets is studied. Attention is given to strategic bidding of load serving entities (LSE) in these markets. We model oligopolistic electricity markets as non-linear dynamical systems and use discrete-time Nash bidding strategies. We assume a Cournot model for our game, where the LSEs decide on demand quantities and the market price is the marginal cost of producing electricity.Attention is given to a problem, where the objective functions are quadratic in the deviations of trajectories from desired trajectories and quadratic in the control deviations from the nominal controls. It is assumed that each power marketer can estimate his/her competitors' benefit function coefficients.The optimal bidding strategies are developed mathematically using dynamic game theory. We deal with games that are non-linear in the state equations. We linearize these equations for complex non-linear oligopolistic electricity multi-markets and use discrete-time Nash strategies. We show that the actual dynamic excursions from the operating point where we linearize are small so that the linearization is valid. The developed algorithm is applied to an IEEE 14-bus power system. We show that the LSEs' expected profits are higher for our method than those for other methods in the literature (F. Wen, A.K. David, Optimal bidding strategies and modeling of imperfect information among competitive generators. IEEE Transactions on Power Systems, Vol. 16, No. 1, pp.15–21, Feb. 2001.     

Improved Two-Dimensional Millimeter-Wave Imaging for Concealed Weapon Detection Through Partial Fourier Sampling

Active millimeter-wave imaging based on synthetic aperture focusing offers certain unique and practical advantages in nondestructive testing applications. Traditionally, the imaging for this purpose is performed through a long procedure of raster scanning with a single antenna across a two-dimensional grid, leading to a slow, bulky, and expensive scanning platform. In this paper, an improved bistatic structure based on radial compressive sensing is proposed, where one fixed transmitter antenna and a linear array of receiving antennas are used. The main contributions of this paper are (a) reducing the scanning time, (b) improving the output quality, and (c) designing an inexpensive setup. These improvements are the result of the underlying proposed simpler scanning structure and faster reconstruction process.     

Numerical Investigation of the Behavior of MERO Joint System Under Combined Loading Regarding Helical Threads of Elements

International Journal of Steel Structures - A comprehensive finite element (FE) model of bolt-ball joint, as called MERO joint, is presented in this paper for a double layer grid structure. In...     

Displacement measurement of the soil nail walls by using close range photogrammetry and introduction of CPDA method

Displacement measurement of the soil nail walls is a very important task in monitoring tiny movements in excavations to prevent disastrous accidents like wall collapsing. In building construction projects, this is usually done by either micro-geodesy or accurate instrumentation methods. In this research, for the first time, the use of close range photogrammetry in displacement measurement of the soil nail walls has been proposed and experienced. For this, a photogrammetric system was designed, implemented and evaluated. Proposed system with three separate methods for displacement measurement, which one of them was submitted for the first time (CPDA), was implemented. The evaluation results the accuracy of 3 mm is achievable in determining the point coordinates with a precision of 8 mm in displacement measurement of soil nail walls. Due to the efficiency, low cost, high accuracy, high speed of observations along with the simplicity of implementation of close range photogrammetry, it is suggested as a proper alternative to the traditional methods.     

An attempt to cast light into starch nanocrystals preparation and cross-linking

Potato starch was hydrolyzed with 2.2 or 3.7 M hydrochloric acid in order to obtain the nanocrystals which afterwards were chemically cross-linked with sodium hexametaphosphate. The stronger acidity resulted in smaller nanocrystals with mean size of 48 nm in a shorter time. X-ray diffraction confirmed the dominant crystalline nature of particles and Fourier transform infrared spectroscopy suggested the presence of lower number of free hydroxyl groups in nanocrystals after cross-linking. Starch nanocrystals showed two distinctive differential scaning colorimetry endotherms at 26 and 125 °C, attributed to destruction of nanocrystals lattice and moblizing of each nanocrystal’s structure, respectively. Cross-linking resulted in a tenacious spatial arrangement of nanocrystals, strengthening the crystals lattice against phase transitions induced by heating. Scanning electron microscopy images confirmed the particle size measured for nanocrystals by light scattering. Atomic force microscopy topographic images suggested that starch nanocrystals were originated from small amylopectin blocklets in granular assembly of starch.     

An artificial neural network for predicting the physiochemical properties of fish oil microcapsules obtained by spray drying

The aim of this work was to develop an artificial neural network (ANN) to predict the physiochemical properties of fish oil microcapsules obtained by spray drying method. The relation amongst inlet-drying air temperature, outlet-drying air temperature, aspirator rate, peristaltic pump rate, and spraying air flow rate with 5 performance indices, namely capsules’ residual moisture content, particle size, bulk density, encapsulation efficiency, and peroxide value was bridged by using ANN. A multilayer perceptron ANN was developed to predict the performance indices based on the input variables. The optimal ANN model was found to be a 5-10-5 structure with tangent sigmoid transfer function, Levenberg-Marquardt error minimization algorithm, and 1,000 training epochs. This optimal network was capable to predict the outputs with R² values higher than 0.87. It was concluded that ANN is a useful tool to investigate, approximate, and predict the encapsulation characteristics of fish oil.     

Structural parameters improvement of an integrated HBT in a cascode configuration opto-electronic mixer

We analyze an integrated electrically pumped opto-electronic mixer, which consists of two InP/GaInAs hetero junction bipolar transistors(HBT), in a cascode configuration. A new HBT with modified physical structure is proposed and simulated to improve the frequency characteristics of a cascode mixer. For the verification and calibrating software simulator, we compare the simulation results of a typical HBT, before modifying it and comparing it with empirical reported experiments. Then we examine the simulator on our modified proposed HBT to prove its wider frequency characteristics with better flatness and acceptable down conversion gain. Although the idea is examined in several GHz modulation, it may easily be extended to state of the art HBT cascode mixers in much higher frequency range.     

An innovative fabrication of nano-HA coatings on Ti-CaP nanocomposite layer using a combination of friction stir processing and electrophoretic deposition

In the present study, a combination of friction stir processing and electrophoretic deposition was used to fabricate nano-hydroxyapatite coatings on the Ti-CaP nanocomposite surface layer. A constant tool rotation rate of 250 rpm, travel speed of 16 mm/min and plunge depth of 1.2 mm with a tool tilt angle of 3° were used to incorporate nano-hydroxyapatite particles into Ti–6Al–4V substrates. Microstructure of the stir zone was analyzed using optical and scanning electron microscopy. Microhardness profile and AFM analysis of substrates were then studied. The electrophoretic deposition of nano-HA particles was carried out at constant voltage of 30 V after 60 s. The as-deposited nano-HA coating was characterized employing scanning electron microscope and X-ray diffraction. The results of adhesion test and potentiodynamic polarization measurements showed that Ti-CaP nanocomposite layer could effectively increase the bonding strength between coating and substrate as well as corrosion resistance.