Some properties of bacterial cellulose produced by new native strain Gluconacetobacter sp. A06O2 obtained from Turkish vinegar

The aim of the study was to isolate and identify an acetic acid bacterial strain having high cellulose yield and to investigate some physicochemical properties of bacterial cellulose (BC). Acetic acid bacteria were isolated by using 62 samples (vinegar, fruit, vegetable, and soil) from different region of Turkey. The cellulose production ability of 153 isolates was determined. A strain (A06O2) having high and stable cellulose yield was identified by biochemical tests and 16S rRNA gene sequencing and compared with type strain Gluconacetobacter xylinus NRRL B‐759. Based on the results, strain A06O2 was named at the genus level as Gluconacetobacter, however, species level identification could not be made. Celluloses from both strains were purified to investigate the physicochemical properties such as thermal properties, solubility in various solvents, elemental composition, tensile properties, and surface properties by FTIR and SEM. The results showed that the cellulose samples of two bacterial strains differed in the physicochemical properties. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Maghemite, γ-Fe2O3, nanoparticles preparation via carbon-templated solution combustion synthesis

High surface area maghemite, γ-Fe₂O₃, nanoparticles were prepared via carbon-templated solution combustion synthesis, which is a two-step approach. Step one involves the combustion synthesis of maghemite nanoparticles embedded in an amorphous carbon matrix, by using a fuel rich reaction mixture of triethylenetetramine and iron nitrate. Step two consists of residual carbon removal by treating the previously-obtained composite precursor with hydrogen peroxide, which releases the maghemite nanopowder. This approach avoids carbon removal by thermal treatment, thus preserving the nanometric size of maghemite nanoparticles (8–12?nm), yielding a high specific surface area of 191.9?m²/g. At the same time, the final maghemite nanoparticles presented a superparamagnetic behavior and a saturation magnetization of 26.2?emu/g, in relation to the small particle size.     

Nanomaterial interfaces designed with different biorecognition elements for biosensing of key foodborne pathogens

Foodborne diseases caused by pathogen bacteria are a serious problem toward the safety of human life in a worldwide. Conventional methods for pathogen bacteria detection have several handicaps, including trained personnel requirement, low sensitivity, laborious enrichment steps, low selectivity, and long-term experiments. There is a need for precise and rapid identification and detection of foodborne pathogens. Biosensors are a remarkable alternative for the detection of foodborne bacteria compared to conventional methods. In recent years, there are different strategies for the designing of specific and sensitive biosensors. Researchers activated to develop enhanced biosensors with different transducer and recognition elements. Thus, the aim of this study was to provide a topical and detailed review on aptamer, nanofiber, and metal organic framework–based biosensors for the detection of food pathogens. First, the conventional methods, type of biosensors, common transducer, and recognition element were systematically explained. Then, novel signal amplification materials and nanomaterials were introduced. Last, current shortcomings were emphasized, and future alternatives were discussed.     

On-demand diversity wireless relay networks

There has been much recent attention on using wireless relay networks to forward data from mobile nodes to a base station. This network architecture is motivated by performance improvements obtained by leveraging the highest quality links to a base station for data transfer. With the advent of agile radios it is possible to improve the performance of relay networks through intelligent frequency assignments. First, it is beneficial if the links of the relay network are orthogonal with respect to each other so that simultaneous transmission on all links is possible. Second, diversity can be added to hops in the relay network to reduce error rates. In this paper we present algorithms for forming such relay networks dynamically. The formation algorithms support intelligent frequency assignments and diversity setup. Our results show that algorithms that order the sequence in which nodes join a relay network carefully, achieve the highest amount of diversity and hence best performance. This research is supported in part by NSF grant CNS-0508114. JaeSheung Shin received the B.S. and M.S. degree in Computer Science and Engineering from DongGuk University, Korea, in 1991 and 1993, respectively. He is currently working toward the Ph.D. degree in Computer Science and Engineering at the Pennsylvania State University, University Park. He is a research assistant at the Networking and Security Research Center (NSRC). Prior to joining Pennsylvania State University, he was with Electronics and Telecommunications Research Institute (ETRI), Korea, since 1993. He worked on development of 2G and 3G wireless cellular core network elements. His research interests include mobility management and signaling for wireless cellular and routing and resource allocation for multi-radio multi-hop wireless cellular networks. Kyounghwan Lee received the B.S. degree in Electrical and Electronics Engineering from University of Seoul, Seoul, Korea, in 2000, and the M.S. degree in Information and Communication Engineering from Gwangju Institute of Science and Technology, Gwangju, Korea, in 2002. He is currently a Ph.D candidate at the Electrical Engineering department at the Pennsylvania State University and a research assistant at the Wireless Communications and Networking Laboratory (WCAN@PSU). His research interests include wireless communication theory and relay networks. E-mail: kxl251@psu.edu Aylin Yener received the B.S. degrees in Electrical and Electronics Engineering, and in Physics, from Bogazici University, Istanbul, Turkey, in 1991, and the M.S. and Ph.D. degrees in Electrical and Computer Engineering from Rutgers University, NJ, in 1994 and 2000, respectively. During her Ph.D. studies, she was with Wireless Information Network Laboratory (WINLAB) in the Department of Electrical and Computer Engineering at Rutgers University, NJ. Between fall 2000 and fall 2001, she was with the Electrical Engineering and Computer Science Department at Lehigh University, PA, where she was a P.C. Rossin assistant professor. Currently, she is with the Electrical Engineering department at the Pennsylvania State University, University Park, PA, as an assistant professor. Dr. Yener is a recipient of the NSF CAREER award in 2003. She is an associate editor of the IEEE Transactions on Wireless Communications. Dr. Yener’s research interests include performance enhancement of multiuser systems, wireless communication theory and wireless networking. Thomas F. La Porta received his B.S.E.E. and M.S.E.E. degrees from The Cooper Union, New York, NY, and his Ph.D. degree in Electrical Engineering from Columbia University, New York, NY. He joined the Computer Science and Engineering Department at Penn State in 2002 as a Full Professor. He is the Director of the Networking Research Center at Penn State. Prior to joining Penn State, Dr. La Porta was with Bell Laboratories since 1986. He was the Director of the Mobile Networking Research Department in Bell Laboratories, Lucent Technologies. He is an IEEE Fellow and Bell Labs Fellow. Dr. La Porta was the founding Editor-in-Chief of the IEEE Transactions on Mobile Computing. He has published over 50 technical papers and holds 25 patents.     

Qualitative analysis of tackifier resins in pressure sensitive adhesives using direct analysis in real time time-of-flight mass spectrometry

Tackifier resins play an important role as additives in pressure sensitive adhesives (PSAs) to modulate their desired properties. With dependence on their origin and processing, tackifier resins can be multicomponent mixtures. Once they have been incorporated in a polymer matrix, conventional chemical analysis of tackifiers usually tends to be challenging because a suitable sample pretreatment and/or separation is necessary and all characteristic components have to be detected for an unequivocal identification of the resin additive. Nevertheless, a reliable analysis of tackifiers is essential for product quality and safety reasons. A promising approach for the examination of tackifier resins in PSAs is the novel direct analysis in real time mass spectrometry (DART-MS) technique, which enables screening analysis without time-consuming sample preparation. In the present work, four key classes of tackifier resins were studied (rosin, terpene phenolic, polyterpene, and hydrocarbon resins). Their corresponding complex mass spectra were interpreted and used as reference spectra for subsequent analyses. These data were used to analyze tackifier additives in synthetic rubber and acrylic adhesive matrixes. To prove the efficiency of the developed method, complete PSA products containing two or three different tackifiers were analyzed. The tackifier resins were successfully identified, while measurement time and interpretation took less than 10 mins per sample. Determination of resin additives in PSAs can be performed down to 0.1% (w/w, limit of detection) using the three most abundant signals for each tackifier. In summary, DART-MS is a rapid and efficient screening method for the analysis of various tackifiers in PSAs.     

Enhanced Anti-Tumoral Activity of Methotrexate-Human Serum Albumin Conjugated Nanoparticles by Targeting with Luteinizing Hormone-Releasing Hormone (LHRH) Peptide

Active targeting could increase the efficacy of anticancer drugs. Methotrexate-human serum albumin (MTX-HSA) conjugates, functionalized by luteinizing hormone-releasing hormone (LHRH) as targeting moieties, with the aim of specifically targeting the cancer cells, were prepared. Owing to the high expression of LHRH receptors in many cancer cells as compared to normal cells, LHRH was used as the targeting ligand in this study. LHRH was conjugated to MTX-HSA nanoparticles via a cross-linker. Three types of LHRH targeted nanoparticles with a mean particle size between 120-138 nm were prepared. The cytotoxicity of LHRH targeted and non-targeted nanoparticles were determined on the LHRH positive and negative cell lines. The internalization of the targeted and non-targeted nanoparticles in LHRH receptor positive and negative cells was investigated using flow cytometry analysis and fluorescence microscopy. The cytotoxicity of the LHRH targeted nanoparticles on the LHRH receptor positive cells were significantly more than non-targeted nanoparticles. LHRH targeted nanoparticles were also internalized by LHRH receptor positive cells significantly more than non-targeted nanoparticles. There were no significant differences between the uptake of targeted and non-targeted nanoparticles to the LHRH receptor negative cells. The active targeting procedure using LHRH targeted MTX-HSA nanoparticles could increase the anti-tumoral activity of MTX.     

Synthesis,characterization, and enzymatic degradation of chitosan/PEG hydrogel films

Poly(ethyleneglycol) (PEG)/tartaric acid (TA)‐crosslinked chitosan hydrogel (CPT) films were prepared, and the formation of the PEG/TA‐crosslinked structure was confirmed by Fourier transformed infrared (FTIR), nuclear magnetic resonance (NMR), and scanning electron microscope (SEM) measurements. The thermal properties of the crosslinked films were also determined with thermogravimetric analysis (TGA) and differential scanning calorimeter (DSC) analysis. The swelling properties of the films were investigated at different temperature and pH values. It was found that the swelling ratio increased with the decrease of pH value of the surrounding buffer solutions, amount of PEG, and with the increase of temperature. Swelling behavior of the PEG/TA‐crosslinked chitosan hydrogel films depended on pH and reversible with the temperature. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Impact of visual performance management systems on the performance management practices of organisations

The purpose of this paper was to explore how visual strategy and performance management techniques impact performance measurement and management practices of organisations. A novel visual performance management approach is developed and implemented in qualitative case studies with seven manufacturing SMEs across Europe. The implementation cases demonstrate that visual management systems serve to support ongoing strategy development and implementation, facilitate performance measurement and review, enable people engagement, improve internal and external communication, enhance collaboration and integration, support the development of a continuous improvement culture and foster innovation. Additional explorative and longitudinal research is required to understand the long-term impact of such approaches in both small and larger organisations.     

Comparison of chitosan apatite composites synthesized by different methods

This article presents some results concerning chitosan apatite composites obtained by two different methods. First method is based on phosphorylation, calcification and soaking in different calcium phosphate growth media (1.5 × SBF (simulated body fluid), Ca‐PTris (calcium phosphorous tris) and the second method is based on mixing of calcium deficient apatite powder with a chitosan solution. This research is focused on studying and understanding the effect of using different methods on Ca:P ratio of composites. The Ca:P ratio of composites formed in 1.5 × SBF are closer to that of bone when compared with the Ca:P ratio of composites formed in Ca‐PTris solution and Ca:P ratio of composites formed by mixing of calcium deficient apatite powder with a chitosan solution. The Ca:P ratio of the composite (1.75) immersed in 1.5 × SBF for 35 day is similar to the theoretical value of hydroxyapatite (1.67) and equal to the theoretical value of human bone (1.75). POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers     

Structure of zirconium alloy oxides formed in pure water studied with synchrotron radiation and optical microscopy: relation to corrosion rate

A detailed study was undertaken of oxides formed in 360 °C water on four Zr-based alloys (Zircaloy-4, ZIRLO™,¹ Zr-2.5%Nb and Zr-2.5%Nb-0.5%Cu) in an effort to relate oxide structure to corrosion performance. Micro-beam X-ray diffraction was used along with transmitted light optical microscopy to obtain information about the structure of these oxides as a function of distance from the oxide-metal interface. Optical microscopy revealed a layered oxide structure in which the average layer thickness was inversely proportional to the post-transition corrosion rate. The detailed diffraction studies showed an oxide that contained both tetragonal and monoclinic ZrO₂, with a higher fraction of tetragonal oxide near the oxide-metal interface, in a region roughly corresponding to one oxide layer. Evidence was seen also of a cyclic variation of the tetragonal and monoclinic oxide across the oxide thickness with a period of the layer thickness. The results also indicate that the final grain size of the tetragonal phase is smaller than that of the monoclinic phase and the monoclinic grain size is smaller in Zircaloy-4 and ZIRLO than in the other two alloys. These results are discussed in terms of a model of oxide growth based on the periodic breakdown and reconstitution of a protective layer.