The Fe-Ni (iron-nickel) system

The online version of the original article can be found at     

The assessment of thermal history in pressure vessel steel

A component of the present work involves attempts to simulate the microstructures of 1Cr-0.5Mo steel sample removed from service after extended exposure to elevated temperatures (10⁵ h at 535°C). The aim is to establish a basis for assessing the thermal history of service components and service weldments. Previous work has established that it is not possible to adequately simulate service microstructures using accelerated isothermal heat treatments alone. A selective mechanical testing program at elevated temperature has thus been investigated to superimpose the effect of stress on heat treatment. Qualitative comparison within each of these sets of micrographs suggests that the intraferritic precipitation in the creep samples is in each case refined and of a higher density compared to the sample subjected to isothermal heat treatments. It has been suggested that a comparison of the composition of the pearlitic M₃C in creep test samples with the empirical relationship may provide a means of assessing the average thermal history of the ex-service sample.     

The distribution of grain boundary planes in polycrystals

During the last ten years, techniques have been developed to measure the distribution of grain boundaries in polycrystals as a function of both lattice misorientation and grain boundary plane orientation. This paper presents a brief overview of the techniques used for these measurements and the principle findings of studies implementing these techniques. The most significant findings are that grain boundary plane distributions are anisotropic, that they are scale invariant during normal grain growth, that the most common grain boundary planes are those with low surface energies, that the grain boundary populations are inversely correlated with the grain boundary energy, and that the coincident site lattice number is a poor predictor of the grain boundary energy and population.     

Corrosion and wear properties of multipurpose coatings deposited by ion-beam-assisted deposition

Electrochemical measurements and wear tests were performed on aluminium and aluminium alloy coatings containing magnesium for uniform and local pitting corrosion protection of low carbon steel substrates. Final hard chromium nitride and aluminium nitride layers were deposited at the surface of the protective films in order to lower friction and wear. The results show that wear and corrosion protection can be improved by use of bifunctional multilayers. The coatings for multipurpose application were generated by ion-beam-assisted deposition. The defined intrinsic film stress controlled by the ion-to-atom arrival ratio influences the corrosion properties. Increasing the ion-to-atom ratios usually improves the corrosion resistance.     

Removal of trace amounts of strontium from aqueous solutions by ion flotation. II Continuous scale operation

A flotation circuit operating on a continuous basis has been designed and constructed for removal of Sr ions from simple aqueous solutions. Under steady-state conditions, a continuous extraction rate of 97.3% has so far been achieved. The effects of changing the gas rate and flow rates of both the Sr and collector solutions were also examined. Finally a discussion is included where the results of these experiments are compared with those from similar continuous-scale experiments where Sr ions are removed by the technique of foam separation.     

Growth of part-through thickness fatigue cracks in sheet polymethylmethacrylate

Fatigue growth data has been obtained for part-through thickness cracks in sheet specimens of polymethylmethacrylate subjected to cyclic tension. Statistical techniques are used to examine the usefulness of linear elastic fracture mechanics for correlating this part-through thickness crack growth data with throughthickness data published previously.     

Crack Healing in UO2

Isothermal annealing of thermally shocked UO₂ bars (O/M= 2.00 ±0.01) at 1600°, 1800°, and 2000°C caused crack healing, which was determined from recovery of room-temperature fracture strength. The activation energy for crack healing was ∼0.5 of that for volume diffusion, and healing occurred at the same rate as grain growth. This result has important implications with respect to crack healing in oxide fuels during in-reactor restructuring.     

A farm level approach to define successful mitigation strategies for GHG emissions from ruminant livestock systems

Ruminant livestock systems are a significant source of greenhouse gases (GHGs). Thus far, mitigation options for GHG emissions mainly focused on a single gas, and are treated as isolated activities. The present paper proposes a framework for a farm level approach for the full accounting of GHG emissions. The methodology accounts for the relevant direct and indirect emissions of methane, nitrous oxide and carbon dioxide, including carbon sequestration. Furthermore, the potential trade-off with ammonia volatilisation and nitrate leaching are taken into account. A ruminant livestock farm is represented with a conceptual model consisting of five pools: animal, manure, soil, crop and feed. The carbon and nitrogen inputs, throughputs and outputs are described, and the direct emissions are related to the carbon and nitrogen flows. The indirect emissions included in the methodology are mainly carbon dioxide emissions from energy use and nitrous oxide emissions related to imported resources and nitrogen losses. The whole farm approach is illustrated with a case of two dairy farms with contrasting livestock density and grassland management. It is shown that the inclusion of carbon sequestration and all indirect emissions have a major impact on the GHG budget of the farm. For one farm, the effect of four mitigation options on the GHG emissions was quantified. It was concluded that a whole farm approach of full accounting contributes to a better insight in the interactions between the carbon and nitrogen flows and the resulting emissions, within and outside the farm boundaries. Consequently, the methodology can be used to develop efficient and effective mitigation strategies.