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It is well-known that the conventional reproducing kernel particle method (RKPM) is unfavorable when dealing with the derivative type essential boundary conditions [1], [2], [3]. To remedy this issue a group of meshless methods in which the derivatives of a function can be incorporated in the formulation of the corresponding interpolation operator will be discussed. Formulation of generalized moving least squares (GMLS) on a domain and GMLS on a finite set of points will be presented. The generalized RKPM will be introduced as the discretized form of GMLS on a domain. Another method that helps to deal with derivative type essential boundary conditions is the gradient RKPM which incorporates the first gradients of the function in the reproducing equation. In present work the formulation of gradient RKPM will be derived in a more general framework. Some important properties of the shape functions for the group of methods under consideration are discussed. Moreover error estimates for the corresponding interpolants are derived. By generalizing the concept of corrected collocation method, it will be seen that in the case of employing each of the proposed methods to a BVP, not only the essential boundary conditions involving the function, but also the essential boundary conditions which involve the derivatives could be satisfied exactly at particles which are located on the boundary.  相似文献   
73.
Screening alternatives for producing paraffinic phase change materials (PCMs) from natural gas‐based products was investigated. Based on the quality and cost of these PCMs, two sources were identified: (i) hydrogenated gas‐to‐liquid (GTL) products such as heavy detergent feedstocks; and (ii) linear alpha olefins. Fractionation of a typical hydrogenated GTL mixture, containing C14 – C18 alkene and alkane hydrocarbons, has been experimentally conducted to produce five paraffinic PCMs with melting points between 3 and 28 °C. ChemCAD simulation has been proved to be a valid tool for predicting the behaviour of the GTL fractionation, including optimum experimental conditions and compositions of products. Also, hydrogenation of technical 1‐octadecene was experimentally carried out in order to evaluate the quality of PCM produced from one of the available technical alpha‐olefins. All PCMs produced in this work were analysed by gas chromatography equipped with flame ionization detector to determine their compositions and by differential scanning calorimetry to determine their latent heats. The results showed that the PCM with a melting temperature in the range 22 to 25 °C can be technically produced through hydrogenation of commercial 1‐octadecene showing a higher latent heat compared to the PCM produced from fractionation of hydrogenated GTL mixture. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
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Wireless Personal Communications - Wireless networks on chip (WiNoC) are considered to be a novel approach for designing efficient and scalable systems. The rationale behind this new approach is to...  相似文献   
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This article proposes a compact multiple‐input multiple‐output (MIMO) antenna with the electromagnetic band gap (EBG) structures for mobile terminals. The proposed MIMO antenna is composed of two radiation patches in which diagonal and folded microstrip lines are utilized to control the frequency bands. The radiation patch, one EBG structure and a rectangular‐shaped ground plane are etched on both sides of the antenna. The EBG structures have been employed for reducing the mutual coupling between the antenna elements. As a result of the effect of these structures, the mutual coupling between the two elements is reduced by less than ?30 dB. The proposed antenna is implemented on an FR4 substrate with dimensions 20 × 10 × 1 mm3. According to measured results, frequency ranges of 2.2 to 3.6 GHz and 5.1 to 5.9 GHz with S11 < ?10 dB and also 3.7 to 5 GHz and 8 to 12 GHz with S22 < ?10 dB have been obtained. Moreover, measured S12 and S21 with values of less than ?30 dB for both Ports have been realized. Additionally, the envelope correlation and radiation efficiency of the purposed antenna are less than 0.09 and more than 82%, respectively.  相似文献   
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We present the preparation of polypropylene (PP)/fumed silica (FS) nanocomposites via in situ polymerization in this article. The approach includes preparation and utilization of a bisupported Ziegler–Natta catalytic system in which magnesium ethoxide and FS are used as conjugate supports of the catalyst. Catalyst preparation and polymerization processes are carried out in the slurry phase and under argon atmosphere. Scanning electron microscopy images show a good dispersion of the FS throughout the PP matrix. Results from differential scanning calorimetry reveal that the crystallization temperature of prepared nanocomposites increases by increasing FS loading. Also, crystal content of nanocomposites increases as the FS concentration increases up to 3.48 wt%. Nanocomposites containing <3.14 wt% of nanoparticles do not show considerable change in their melting point where with more increment in filler concentration, melting temperature slightly increases. Thermogravimetric analysis shows a considerable improvement in the thermal stability of PP/FS nanocomposites compared to pure PP. Rheological studies indicate that the incorporation of FS into PP matrix results in increment in storage modulus, loss modulus, and complex viscosity of polymeric matrix, particularly in low frequency region. By increasing FS loading, the PP/FS nanocomposites show a transition from liquid‐like to solid‐like viscoelasticity behavior depicting microstructural changes in their structures. POLYM. COMPOS., 35:37–44, 2014. © 2013 Society of Plastics Engineers  相似文献   
78.
In preparation of polymer nanocomposites, achieving good mixing and uniform distribution of nanofillers is highly desired for property enhancement. Polyethylene (PE) and its nanocomposite with halloysite nanotubes (HNTs) possesses a myriad of potentials for advanced engineering properties. A high nanoparticle loading is preferred to capitalize the nano-reinforcement, thermal, and barrier properties. The capability of a two-roll calendaring machine to disperse HNT particles into a linear low-density polyethylene (LLDPE) matrix at elevated processing temperatures was assessed. Morphological, thermal, mechanical, and rheological behavior of prepared nanocomposites were characterized. A homogeneous distribution of HNTs in concentrations up to 5 wt.% was evidenced by SEM analysis. TGA showed the 10 wt.% composite exhibited an overall outstanding thermal stability. DSC analysis revealed the 30 wt.% sample has the highest Tm and Tc, and the %crystallinity did not change much due to HNT incorporation for all samples. DMA showed the storage and loss moduli increased with increase in HNT loadings. The effect of loading HNTs into the LLDPE matrix on Tg was minimal, implying that LLDPE and HNTs are quite compatible. The results demonstrated that the two-roll mill fabrication method can efficiently keep HNT particles unagglomerated and disperse them evenly into the LLDPE matrix.  相似文献   
79.
Melt spinning of graphene nanoplatelets (GnPs)‐polypropylene (PP) nanocomposite fibers are reported for the first time. PP/GnPs fibers were spun with a pilot‐plant spinning machine with varying concentration of GnPs by mixing PP/GnPs masterbatch with PP. The effect of inclusion of GnPs on the morphology and crystalline structure of PP fibers was investigated. The thermal stability of the fibers was also evaluated by thermogravimetric analysis. The light microscopy images showed that the GnPs are uniformly distributed over the PP matrix. The differential scanning calorimetry (DSC) results revealed that presence of GnPs affects both the melting and crystallization behaviors. The melting peaks of PP/GnPs nanocomposite fibers were broader than that of neat PP fibers, indicating a broader crystal size distribution in PP/GnPs nanocomposite fibers as compared to the neat PP fibers. Besides, an obvious increment in the crystallization peak temperature was observed in GnPs‐PP nanocomposite fibers. The wide‐angle X‐ray diffraction spectra (WAXD) results showed that the crystal type of nanocomposite fibers did not change and was still the α‐monoclinic crystal form. Moreover, the morphology of spherulites demonstrated that GnPs increased the nucleation sites in the nanocomposite fibers which in turn restricted the crystal growth of PP chains. This finding supported the DSC and WAXD results. Activation energies were calculated by Horowitz and Metzger's method as 77.87 and 105.41 kJ/mol for neat PP and PP/0.2 wt% GnPs fibers, respectively, suggesting an increase in the thermal stability of GnPs‐PP nanocomposite fibers. POLYM. COMPOS., 36:367–375, 2015. © 2014 Society of Plastics Engineers  相似文献   
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